3-chloropropyl iodide

Names

[ CAS No. ]:
6940-76-7

[ Name ]:
3-chloropropyl iodide

[Synonym ]:
MFCD00001096
3-chloropropyl iodide
Propane, 1-chloro-3-iodo-
1-Chloro-3-iodopropane
EINECS 230-088-8

Chemical & Physical Properties

[ Density]:
1.9±0.1 g/cm3

[ Boiling Point ]:
166.9±8.0 °C at 760 mmHg

[ Molecular Formula ]:
C₃H₆ClI

[ Molecular Weight ]:
204.437

[ Flash Point ]:
54.7±18.4 °C

[ Exact Mass ]:
203.920258

[ LogP ]:
2.41

[ Vapour density ]:
6.8 (vs air)

[ Vapour Pressure ]:
2.3±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.536

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2903799090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

4-(3-Chloropropyl)morpholine hydrochloride
methyl 7-chloro-3-oxoheptanoate
3-(Dimethylphenylsilyl)propyl chloride
Benzeneacetonitrile, a-(3-chloropropyl)-3,4-dimethoxy-a-(1-methylethyl)-
5-CHLORO-1-(4-CYANOPHENYL)-1-OXOPENTANE
3-Chloropropyl acetate
1-Chloro-5-trimethylsilyl-4-pentyne
Butanenitrile, 4-iodo-
N-(2-chloroethyl)aniline
N,N-bis-(2-Chloroethyl)aniline

Customs

[ HS Code ]: 2903799090

[ Summary ]:
2903799090 halogenated derivatives of acyclic hydrocarbons containing two or more different halogens。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:5.5%。General tariff:30.0%

Articles

Asymmetric synthesis of chiral N-sulfinyl 3-alkyl- and 3-arylpiperidines by α-alkylation of N-sulfinyl imidates with 1-chloro-3-iodopropane.

J. Org. Chem. 76(1) , 234-44, (2011)

α-Alkylation of N-sulfinyl imidates with 1-chloro-3-iodopropane successfully led to 2-substituted N-tert-butanesulfinyl-5-chloropentanimidates in acceptable diastereomeric ratios (dr 67/33 to 72/28) a...

Synthesis of 1, 2, 3, 4-tetrahydroquinolines and 1, 2, 3, 4-tetrahydro-1, 6-naphthyridines by a directed lithiation reaction. Reed JN, et al.

Tetrahedron Lett. 29(45) , 5725-28, (1988)

Electrochemical Reduction of 1, 3-Dihalopropanes at Carbon Cathodes in Dimethylformamide. Pritts WA and Peters DG.

J. Electrochem. Soc. 141(4) , 990-95, (1994)