Ethyl 2-((diphenylmethylene)amino)acetate

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Names

[ CAS No. ]:
69555-14-2

[ Name ]:
Ethyl 2-((diphenylmethylene)amino)acetate

[Synonym ]:
Ethyl N-(diphenylmethylene)glycinate
Ethyl [(diphenylmethylene)amino]acetate
Glycine, N-(diphenylmethylene)-, ethyl ester
MFCD00010590
Diphenylmethyleneglycine ethyl ester
Ethyl N-(diphenylmethylidene)glycinate
2OV1NUYR&R
Ethyl N-benzhydrylideneglycinate
ethyl 2-(benzhydrylideneamino)acetate

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
357.9±34.0 °C at 760 mmHg

[ Melting Point ]:
51-53 °C(lit.)

[ Molecular Formula ]:
C17H17NO2

[ Molecular Weight ]:
267.322

[ Flash Point ]:
138.0±20.1 °C

[ Exact Mass ]:
267.125916

[ PSA ]:
38.66000

[ LogP ]:
3.18

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.542

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S22-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2925290090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Benzophenone
  • Glycine ethyl ester hydrochloride
  • Benzophenoneimine
  • ethyl 2-acetyloxy-2-(benzhydrylideneamino)acetate
  • Ethyl glycinate
  • (SS,2S,3S)-(+)-ethyl 2-N-(diphenylmethylideneamino)-3-N-(p-toluenesulfinyl)amino-3-phenylpropanoate
  • EDA
  • PHENYLMAGNESIUM CHLORIDE
  • Benzonitrile

DownStream

  • Ethyl 4-chlorophenylalaninate hydrochloride (1:1)
  • Ethyl 3-cyclobutylalaninate
  • 4-nitrophenylalanine
  • ethyl 2-(2,2-dichloro-3,3-diphenylaziridin-1-yl)acetate
  • Benzophenone
  • Glycine,N-(4-nitrobenzoyl)-, ethyl ester
  • H-DL-Nle-OH
  • Benzophenoneimine
  • Glycine, N-benzoyl-,ethyl ester
  • ethyl 2-(benzhydrylideneamino)pent-4-ynoate

Customs

[ HS Code ]: 2925290090

[ Summary ]:
2925290090 other imines and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

J. Org. Chem. 57 , 5469, (1992)

Tetrahedron Lett. 34 , 677, (1993)

Tetrahedron Lett. 34 , 8535, (1993)


More Articles

Related Compounds

  • ethyl 2-((diphenylmethylene)amino)-2-(thiophen-2-yl)acetate
  • ethyl 2-((diphenylmethylene)amino)-2-(tetrahydro-2H-pyran-4-yl)acetate
  • ethyl 2-((diphenylmethylene)amino)-4-methylpentanoate
  • ethyl 2-((diphenylmethylene)amino)-3-phenylpropanoate
  • ethyl 2-((diphenylmethylene)amino)-4-fluoro-4-phenylbutanoate
  • ethyl 2-[(diphenylmethylene)amino]-2-ethylbutanoate