dibromo(phenyl)arsane

Names

[ CAS No. ]:
696-24-2

[ Name ]:
dibromo(phenyl)arsane

[Synonym ]:
ARSINE,DIBROMOPHENYL
Phenylarsendibromid
Phenyldibromoarsine
Phenylarsonous dibromide
As.As-Dibrom-phenylarsin
Arsonous dibromide,phenyl
dibromo-phenyl-arsine
Dibromphenylarsin

Chemical & Physical Properties

[ Boiling Point ]:
264.6ºC at 760 mmHg

[ Molecular Formula ]:
C6H5AsBr2

[ Molecular Weight ]:
311.83400

[ Flash Point ]:
112.8ºC

[ Exact Mass ]:
309.79700

[ LogP ]:
2.17160

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
CH2700000
CHEMICAL NAME :
Arsine, dibromophenyl-
CAS REGISTRY NUMBER :
696-24-2
BEILSTEIN REFERENCE NO. :
2935647
LAST UPDATED :
199612
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C6-H5-As-Br2
MOLECULAR WEIGHT :
311.85
WISWESSER LINE NOTATION :
E-AS-ER

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
15 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JPBAA7 Journal of Pathology and Bacteriology. (London, UK) V.1-96, 1892-1968. For publisher information, see JPTLAS. Volume(issue)/page/year: 58,411,1946
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
4 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JPBAA7 Journal of Pathology and Bacteriology. (London, UK) V.1-96, 1892-1968. For publisher information, see JPTLAS. Volume(issue)/page/year: 58,411,1946
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
500 ug/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JPBAA7 Journal of Pathology and Bacteriology. (London, UK) V.1-96, 1892-1968. For publisher information, see JPTLAS. Volume(issue)/page/year: 58,411,1946
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - guinea pig
DOSE/DURATION :
6 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
JPBAA7 Journal of Pathology and Bacteriology. (London, UK) V.1-96, 1892-1968. For publisher information, see JPTLAS. Volume(issue)/page/year: 58,411,1946 *** U.S. STANDARDS AND REGULATIONS *** OSHA PEL (Gen Indu):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.5 mg(As)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994

Synthetic Route

Precursor & DownStream

Precursor

  • 1-phenyl-3,4-dimethyl-3-arsolene
  • Arsonic acid,As-phenyl-
  • phenylarsonodithious acid bis-(2-hydroxy-ethyl) ester
  • tellurium,triethylgermanium
  • Arsine, oxophenyl-
  • bromo(phenyl)mercury
  • phenyl dichloroarsine
  • Diphenylmercury
  • Hydrogen bromide

DownStream

  • Bromobenzene

Related Compounds

  • dibromo(phenyl)(tetradecyl)-l4-tellane
  • dibromo(phenyl)(3-phenylpropyl)-l4-tellane
  • [dibromo(phenyl)-λ4-selanyl]benzene
  • [dibromo(phenyl)methyl]benzene
  • [dibromo(phenyl)stannyl]methyl-trimethylsilane
  • dibromo(phenyl)borane
  • 2-(2-{[(Benzyloxy)carbonyl]amino}-3-bromophenyl)acetic acid
  • Ethyl 5-(2,2-dimethyl-1,3-oxazolidin-4-yl)pent-4-enoate
  • 5-{3-[(Benzyloxy)carbonyl]-2,2-dimethyl-1,3-oxazolidin-4-yl}pent-4-enoic acid
  • Tert-butyl 2,6-diaminohex-4-ynoate
  • 4-{[(Benzyloxy)carbonyl]amino}-4-(trifluoromethyl)cyclohexane-1-carboxylic acid
  • tert-butyl N-[2-hydroxy-3-(4-nitrophenoxy)propyl]-N-methylcarbamate
  • tert-butyl N-[3-(1,3-dioxaindan-5-yloxy)-2-hydroxypropyl]-N-methylcarbamate
  • Tert-butyl 4-[1-(4-chlorophenyl)-2-hydroxyethyl]piperazine-1-carboxylate
  • Tert-butyl 9-hydroxy-9-(trifluoromethyl)-3-azabicyclo[3.3.1]nonane-3-carboxylate
  • tert-butyl N-[1-(hydroxymethyl)cyclopentyl]-N-(2-phenylethyl)carbamate
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