1-(Cyclopenta-2,4-dien-1-ylidene)-N,N-dimethylmethanamine

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Names

[ CAS No. ]:
696-68-4

[ Name ]:
1-(Cyclopenta-2,4-dien-1-ylidene)-N,N-dimethylmethanamine

[Synonym ]:
1-(Cyclopenta-2,4-dien-1-yliden)-N,N-dimethylmethanamin
1-cyclopenta-2,4-dien-1-ylidene-N,N-dimethylmethanamine
Methanamine, 1-(2,4-cyclopentadien-1-ylidene)-N,N-dimethyl-
1-(Cyclopenta-2,4-dien-1-ylidene)-N,N-dimethylmethanamine
MFCD00013275
1-(2,4-Cyclopentadien-1-ylidene)-N,N-dimethylmethanamine
Methanamine, 1- (2,4-cyclopentadien-1-ylidene)-N,N-dimethyl-

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
205.3±9.0 °C at 760 mmHg

[ Melting Point ]:
64-66ºC(lit.)

[ Molecular Formula ]:
C8H11N

[ Molecular Weight ]:
121.180

[ Flash Point ]:
70.3±15.6 °C

[ Exact Mass ]:
121.089149

[ PSA ]:
3.24000

[ LogP ]:
1.61

[ Vapour Pressure ]:
0.3±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.633

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
26-37/39

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2921300090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2,4-Cyclopentadien-1-ylthallium
  • Cyclopentadiene
  • N,N-Dimethylformamide dimethyl acetal
  • Fulvene, 6,6-bis(dimethylamino)-
  • Dimethyl Carbonate
  • Dimethyl sulfate
  • 1,1-Diethoxy-N,N-dimethylmethanamine
  • N,N-Dimethylformamide
  • SODIUM CYCLOPENTADIENIDE

DownStream

  • Azulene, 5,6-dimethyl-
  • 4-(hydroxymethylidene)cyclopenta-2,5-diene-1,2-dicarbaldehyde
  • 4,6-dimethylazulene
  • cyclopenta-2,4-diene-1-carbaldehyde
  • (6-N,N-dimethylaminofulvene)tricarbonylmolybdenum

Customs

[ HS Code ]: 2921300090

[ Summary ]:
2921300090 other cyclanic, cyclenic or cyclotherpenic mono- or polyamines, and their derivatives; salts thereof。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Asymmetric synthesis of metallocenes through enantioselective addition of organolithium reagents to 6-(dimethylamino)fulvene.

J. Org. Chem. 67(10) , 3355-9, (2002)

Enantioselective addition of aryllithiums 2a-d (Ar = Ph (a), 2-MeC(6)H(4) (b), 2-MeOC(6)H(4) (c), 1-naphthyl (d)) to 6-(dimethylamino)fulvene (1) in the presence of (-)-sparteine in toluene at -78 deg...


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Related Compounds

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  • 4-fluoro-3-methyl-N-(1-methyl-2-oxoindolin-5-yl)benzenesulfonamide
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
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  • 8-[2-(dimethylamino)ethyl]-1,7-dimethyl-3-[(naphthalen-1-yl)methyl]-1H,2H,3H,4H,8H-imidazo[1,2-g]purine-2,4-dione
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