Boc-L- Prolinal

Suppliers

Names

[ Name ]:
Boc-L- Prolinal

[Synonym ]:
1-Pyrrolidinecarboxylic acid, 2-formyl-, 1,1-dimethylethyl ester, (2S)-
tert-butyl (2S)-2-formylpyrrolidine-1-carboxylate
(S)-1-Boc-2-Formylpyrrolidine
MFCD00274186
(S)-(-)-1-Boc-pyrrolidine-2-carboxaldehyde
Boc-L- Prolinal
(S)-N-(TERT-BUTOXYCARBONYL)PROLINAL
2-Methyl-2-propanyl (2S)-2-formyl-1-pyrrolidinecarboxylate
N-BOC-L-Prolinal

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
276.3±33.0 °C at 760 mmHg

[ Molecular Formula ]:
C₁₀H₁₇NO₃

[ Molecular Weight ]:
199.247

[ Flash Point ]:
120.9±25.4 °C

[ Exact Mass ]:
199.120850

[ PSA ]:
46.61000

[ LogP ]:
0.69

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.528

[ Storage condition ]:
-20°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
UN 1989C 3 / PGIII

[ WGK Germany ]:
3

[ HS Code ]:
2933990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

n-(tert-butoxycarbonyl)-l-proline n'-methoxy-n'-methylamide
N-Boc-L-Prolinol
Boc-Pro-OMe
1,2-Pyrrolidinedicarboxylic acid, 1-(1,1-dimethylethyl) 2-ethyl ester, (2S)-
carbon monoxide
1-N-Boc-2,3-dihydropyrrole
Boc-L-Proline
Di-tert-butyl dicarbonate
Proline

DownStream

Boc-Pro-OMe
tert-butyl 2-(1-hydroxy-2-nitroethyl)pyrrolidine-1-carboxylate
1-Boc-2-piperidone
N-Boc-L-Prolinol
(S)-TERT-BUTYL 2-(1H-IMIDAZOL-2-YL)PYRROLIDINE-1-CARBOXYLATE
tert-Butyl (S)-2-(4-bromo-1H-imidazol-2-yl)pyrrolidine-1-carboxylate
N-(tert-Butoxycarbonyl)-DL-phenylalaninol
Boc-L-Proline
(2R,3R)-BOC-dolaproine
(R)-1-BOC-2-ETHYNYLPYRROLIDINE

Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

A new general access to either type of Securinega alkaloids: synthesis of securinine and (-)-allonorsecurinine.

Org. Lett. 6 , 1813, (2004)

The syntheses of securinine and (-)-allonorsecurinine have been achieved starting from easily available alpha-amino acid derivatives and using as key steps a RCM and a Heck reaction for the formation ...

Tetrahedron Lett. 45 , 2985, (2004)

Boc-L-aspartic acid 4-benzyl ester
Boc-L-Thr(Bzl)-D-Leu-OMe
Boc-L-Glutamine
Boc-L-Trp-ONp
Boc-L-Pro-Sar-OH
Boc-L-Cys(SBzl)-OPfp
7-benzyl-1,3-dimethyl-8-octylsulfanyl-5H-purin-7-ium-2,6-dione
9-benzyl-3-butyl-1-methyl-6,7,8,9a,10,10a-hexahydro-4aH-purino[7,8-a]pyrimidine-2,4-dione
3-heptyl-9-(4-methoxyphenyl)-1,7-dimethyl-6,7,8,9a,10,10a-hexahydro-4aH-purino[7,8-a]pyrimidine-2,4-dione
8-[benzyl(methyl)amino]-3-methyl-7-octyl-2,3,6,7-tetrahydro-1H-purine-2,6-dione
BE5U52Snx7
9-(Furan-2-ylmethyl)-1-methyl-3-(naphthalen-1-ylmethyl)-4a,6,7,8-tetrahydropurino[7,8-a]pyrimidin-9-ium-2,4-dione
9-benzyl-3-[(2-chloro-6-fluorophenyl)methyl]-1-methyl-6,7,8,9a,10,10a-hexahydro-4aH-purino[7,8-a]pyrimidine-2,4-dione
(R)-3-Biphenyl-2-YL-3-(9H-fluoren-9-ylmethoxycarbonylamino)-propionic acid
(R)-3-((((9H-Fluoren-9-yl)methoxy)carbonyl)amino)-3-([1,1'-biphenyl]-2-yl)propanoic acid
(R)-3-([1,1'-Biphenyl]-3-yl)-3-((tert-butoxycarbonyl)amino)propanoic acid

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