Boc-L- Prolinal

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Names

[ CAS No. ]:
69610-41-9

[ Name ]:
Boc-L- Prolinal

[Synonym ]:
1-Pyrrolidinecarboxylic acid, 2-formyl-, 1,1-dimethylethyl ester, (2S)-
tert-butyl (2S)-2-formylpyrrolidine-1-carboxylate
(S)-1-Boc-2-Formylpyrrolidine
MFCD00274186
(S)-(-)-1-Boc-pyrrolidine-2-carboxaldehyde
Boc-L- Prolinal
(S)-N-(TERT-BUTOXYCARBONYL)PROLINAL
2-Methyl-2-propanyl (2S)-2-formyl-1-pyrrolidinecarboxylate
N-BOC-L-Prolinal

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
276.3±33.0 °C at 760 mmHg

[ Molecular Formula ]:
C10H17NO3

[ Molecular Weight ]:
199.247

[ Flash Point ]:
120.9±25.4 °C

[ Exact Mass ]:
199.120850

[ PSA ]:
46.61000

[ LogP ]:
0.69

[ Vapour Pressure ]:
0.0±0.6 mmHg at 25°C

[ Index of Refraction ]:
1.528

[ Storage condition ]:
-20°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
UN 1989C 3 / PGIII

[ WGK Germany ]:
3

[ HS Code ]:
2933990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • n-(tert-butoxycarbonyl)-l-proline n'-methoxy-n'-methylamide
  • N-Boc-L-Prolinol
  • Boc-Pro-OMe
  • 1,2-Pyrrolidinedicarboxylic acid, 1-(1,1-dimethylethyl) 2-ethyl ester, (2S)-
  • carbon monoxide
  • 1-N-Boc-2,3-dihydropyrrole
  • Boc-L-Proline
  • Di-tert-butyl dicarbonate
  • Proline

DownStream

  • Boc-Pro-OMe
  • tert-butyl 2-(1-hydroxy-2-nitroethyl)pyrrolidine-1-carboxylate
  • 1-Boc-2-piperidone
  • N-Boc-L-Prolinol
  • (S)-TERT-BUTYL 2-(1H-IMIDAZOL-2-YL)PYRROLIDINE-1-CARBOXYLATE
  • tert-Butyl (S)-2-(4-bromo-1H-imidazol-2-yl)pyrrolidine-1-carboxylate
  • N-(tert-Butoxycarbonyl)-DL-phenylalaninol
  • Boc-L-Proline
  • (2R,3R)-BOC-dolaproine
  • (R)-1-BOC-2-ETHYNYLPYRROLIDINE

Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

A new general access to either type of Securinega alkaloids: synthesis of securinine and (-)-allonorsecurinine.

Org. Lett. 6 , 1813, (2004)

The syntheses of securinine and (-)-allonorsecurinine have been achieved starting from easily available alpha-amino acid derivatives and using as key steps a RCM and a Heck reaction for the formation ...

Tetrahedron Lett. 45 , 2985, (2004)


More Articles

Related Compounds

  • Boc-L-aspartic acid 4-benzyl ester
  • Boc-L-Thr(Bzl)-D-Leu-OMe
  • Boc-L-Glutamine
  • Boc-L-Trp-ONp
  • Boc-L-Pro-Sar-OH
  • Boc-L-Cys(SBzl)-OPfp
  • 3,5-Dichloro-4-[(piperidin-3-yl)methyl]pyridine
  • 3-Amino-2-(5-bromofuran-2-yl)propanoic acid
  • [4-(tert-Butylsulfamoyl)-3-methylphenyl]boronic acid
  • N,N-Dimethyl-3-(propan-2-yl)pyrrolidin-3-amine
  • MEthyl 4-(1,2,3-triazol-2-yl)butanoate
  • 4-Ethyl-2-iodo-5-methylaniline
  • 4-Chloro-6-(dimethylamino)pyridine-3-carbaldehyde
  • 3-Pyridinecarbonitrile, 4-chloro-5-formyl-
  • 2-(3-Bromo-5-chloro-4-methylphenyl)acetonitrile
  • 2-(4-Bromo-2-chloro-5-methylphenyl)acetonitrile
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