2,6-DICHLORO-1,4-BENZOQUINONE

Names

[ CAS No. ]:
697-91-6

[ Name ]:
2,6-DICHLORO-1,4-BENZOQUINONE

[Synonym ]:
MFCD00037159
2,6-dichlorocyclohexa-2,5-diene-1,4-dione
EINECS 211-810-0

Chemical & Physical Properties

[ Density]:
1.56g/cm3

[ Boiling Point ]:
241.5ºC at 760 mmHg

[ Melting Point ]:
122-124 °C(lit.)

[ Molecular Formula ]:
C₆H₂Cl₂O₂

[ Molecular Weight ]:
176.98500

[ Flash Point ]:
98.5ºC

[ Exact Mass ]:
175.94300

[ PSA ]:
34.14000

[ LogP ]:
1.38360

[ Index of Refraction ]:
1.568

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: DK4000000

CHEMICAL NAME :: p-Benzoquinone, 2,6-dichloro-

CAS REGISTRY NUMBER :: 697-91-6

LAST UPDATED :: 199701

DATA ITEMS CITED :: 2

MOLECULAR FORMULA :: C6-H2-Cl2-O2

MOLECULAR WEIGHT :: 176.98

WISWESSER LINE NOTATION :: L6V DVJ BG FG

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LDLo - Lowest published lethal dose

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: NCNSA6 National Academy of Sciences, National Research Council, Chemical-Biological Coordination Center, Review. (Washington, DC) Volume(issue)/page/year: 5,20,1953

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
DK4000000

[ HS Code ]:
2914700090

Customs

[ HS Code ]: 2914700090

[ Summary ]:
HS: 2914700090 halogenated, sulphonated, nitrated or nitrosated derivatives of ketones and quinones, whether or not with other oxygen function Tax rebate rate:9.0% Supervision conditions:none VAT:17.0% MFN tariff:5.5% General tariff:30.0%

Articles

Metal-independent decomposition of hydroperoxides by halogenated quinones: detection and identification of a quinone ketoxy radical.

Proc. Natl. Acad. Sci. U. S. A. 106(28) , 11466-71, (2009)

We have shown recently that halogenated quinones could enhance the decomposition of hydroperoxides and formation of alkoxyl/hydroxyl radicals through a metal-independent mechanism. However, neither th...

Removal of halo-benzoquinone (emerging disinfection by-product) precursor material from three surface waters using coagulation.

Water Res. 47(5) , 1773-82, (2013)

Halo-benzoquinones (HBQs) have been previously detected as disinfection by-products in chlorinated drinking water. The current work investigates the link between natural organic matter (NOM) character...

Microbial anaerobic demethylation and dechlorination of chlorinated hydroquinone metabolites synthesized by basidiomycete fungi.

Appl. Environ. Microbiol. 70(1) , 385-92, (2004)

The synthesis and degradation of anthropogenic and natural organohalides are the basis of a global halogen cycle. Chlorinated hydroquinone metabolites (CHMs) synthesized by basidiomycete fungi and pre...

N-phenylsulfonyl-2,6-dichloro-1,4-benzoquinone imine
N-[(4-nitrophenyl)thio]-2,6-dichloro-1,4-benzoquinone imine
N-p-methylbenzenesulfonyl-2,6-dichloro-1,4-benzoquinone imine
2,6-dichloro-[1,4]benzoquinone-4-(2,4-dinitro-phenylimine)
2,6-DICHLORO-1,4-HYDROQUINONE
((2,6-dichloro-1,4-phenylene)bis(oxy))bis(trimethylstannane)