(Bromomethyl)cyclopropane

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Names

[ CAS No. ]:
7051-34-5

[ Name ]:
(Bromomethyl)cyclopropane

[Synonym ]:
Cyclopropane, (bromomethyl)-
bromomethylcyclopropane
EINECS 230-331-8
MFCD00001306
(Bromomethyl)cyclopropane
1-Cyclopropylmethylbromide

Chemical & Physical Properties

[ Density]:
1.5±0.1 g/cm3

[ Boiling Point ]:
106.0±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C4H7Br

[ Molecular Weight ]:
135.00

[ Flash Point ]:
41.7±0.0 °C

[ Exact Mass ]:
133.973099

[ LogP ]:
2.05

[ Vapour Pressure ]:
33.6±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.512

[ Storage condition ]:
0-6°C

[ Stability ]:
Stable. Flammable. Incompatible with strong bases, strong oxidizing agents.

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R10;R22;R36/37/38

[ Safety Phrases ]:
S23-S24/25-S37/39-S26-S16-S36/37/39

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
29035990

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Cyclopropyl carbinol
  • Benzamide,N-(cyclopropylmethyl)-
  • (Chloromethyl)cyclopropane
  • cyclobutane carboxylic acid silver salt
  • Phosphorus tribromide
  • cyclopropylmethyl(trimethyl)silane
  • diazomethane
  • allyl bromide
  • Dichloromethane

DownStream

  • (Cyclopropylmethyl)hydrazine
  • (HYDROXYMETHYL)-2-PYRROLIDINONE
  • 1,7-Octadiene
  • 1-but-3-enyl-2-methylbenzene
  • DIMETHYLBIPHENYL
  • 1-(cyclopropylmethyl)-2-methylbenzene
  • 5-[1-(cyclopropylmethyl)pyridin-1-ium-4-yl]-3-methyl-1,2-oxazole,bromide
  • Benzyl 2-Hydroxy-2-Methylpropionate
  • octene
  • 1-cyclopropylpentane

Customs

[ HS Code ]: 2903890090

[ Summary ]:
2903890090. halogenated derivatives of cyclanic, cyclenic or cyclotherpenic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Iron-catalyzed cross-coupling of alkyl halides with alkenyl grignard reagents.

Angew. Chem. Int. Ed. Engl. 46 , 6521, (2007)

Simple iron-amine catalysts for the cross-coupling of aryl Grignards with alkyl halides bearing beta-hydrogens.

Chem. Commun. (Camb.) (33) , 4161-3, (2005)

Mixtures of iron(III) chloride and appropriate amine ligands are active catalysts for the coupling of aryl Grignard reagents with primary and secondary alkyl halide substrates bearing beta-hydrogens, ...

Identification of opioid ligands possessing mixed micro agonist/delta antagonist activity among pyridomorphinans derived from naloxone, oxymorphone, and hydromorphone [correction of hydropmorphone].

J. Med. Chem. 47 , 1400, (2004)

A series of pyridomorphinans derived from naloxone, oxymorphone, and hydromorphone (7a-k) were synthesized and evaluated for binding affinity at the opioid delta, micro, and kappa receptors in brain m...


More Articles

Related Compounds

  • (Bromomethyl)cyclopropane
  • (Bromomethyl)cyclopropane
  • 1,1-Bis(bromomethyl)cyclopropane
  • 1-bromo-1-(bromomethyl)cyclopropane
  • 1-(bromomethyl)cyclopropaneacetonitrile
  • 1,1-dibromo-2-(bromomethyl)cyclopropane
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1-(6-(1H-imidazol-1-yl)pyrimidin-4-yl)-N-(furan-2-ylmethyl)azetidine-3-carboxamide
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde
  • tert-Butyl-DL-alanine
  • 1-(2-methoxyethyl)-1H-1,2,3-benzotriazole-7-carboxylic acid