Trimethyl orthobenzoate

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Names

[ CAS No. ]:
707-07-3

[ Name ]:
Trimethyl orthobenzoate

[Synonym ]:
EINECS 211-897-5
(Trimethoxymethyl)benzene
trimethoxymethylbenzene
MFCD00008474
Benzene, (trimethoxymethyl)-

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
223.9±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C10H14O3

[ Molecular Weight ]:
182.216

[ Flash Point ]:
82.2±0.0 °C

[ Exact Mass ]:
182.094299

[ PSA ]:
27.69000

[ LogP ]:
3.70

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.481

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36/37/39-S37/39

[ WGK Germany ]:
3

[ HS Code ]:
2909309090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methanol
  • Benzaldehyde dimethyl acetal
  • Methyl benzoate
  • Toluene
  • Sodium Methylate
  • Benzotrichloride
  • Benzenecarboximidic Acid Methyl Ester
  • Benzonitrile
  • BENZINIDIC ACID METHYL ESTER HYDROCHLORIDE
  • Bromobenzene

DownStream

  • 1-[dimethoxy(phenyl)methyl]imidazole
  • 2-[amino(phenyl)methylidene]propanedinitrile
  • 2,5-Diphenyloxazole
  • [Ethoxy(methoxy)methyl]benzene
  • 2-Phenylbenzoxazole
  • o-Phenylenediamine
  • 2-Phenyl-1H-benzo[d]imidazole
  • 5-bromo-a-phenyl benzimidazole
  • 5-iodo-2-phenyl-1H-benzimidazole
  • 2-Methoxybenzylidenemalononitrile

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

Spin distributions, ring conformations, and spiroconjugation in "phosphaverdazyl" radicals.

Inorg. Chem. 40(8) , 1865-70, (2001)

Reaction of P-dimethylaminophosphonic acid bis(1-methylhydrazide) (6) with trimethyl orthobenzoate gave 1,2,5,6-tetrahydro-1,5-dimethyl-6-(N,N-dimethylamino)-6-phenyl-1,2,4,5,6-tetrazaphosphorine-6-ox...

Reactions between pyrrole and orthoesters: preparation of tri-(pyrrol-2-yl) alkanes. Reese CB and Yan H.

Tetrahedron Lett. 43(32) , 5545-47, (2001)

Incidence and avoidance of stereospecific 1, 2-ethylthio group migration during the synthesis of ethyl 1-thio-a-l-rhamnopyranoside 2, 3-orthoester. Auzanneau F-I and Bundle DR.

Carbohydr. Res. 212 , 13-24, (1991)


More Articles

Related Compounds

  • Trimethyl Allyloxysilane
  • trimethyl-[3-(2-methyl-1,3-dioxolan-2-yl)propyl]azanium,iodide
  • trimethyl(1-octoxyethenoxy)silane
  • trimethyl(1,3,3,5-tetrachloropentyl)silane
  • trimethyl(2,4,4-trimethylpent-2-en-3-yloxy)silane
  • trimethyl(1,3,3-trichlorobutyl)silane
  • Tert-butyl 3-(propylamino)piperidine-1-carboxylate
  • N-[4-[[4-(4-ethoxyphenyl)-1-piperazinyl]carbonyl]phenyl]-8-quinolinesulfonamide
  • N-[4-[[4-[4-(diethylamino)phenyl]-1-piperazinyl]carbonyl]phenyl]-8-quinolinesulfonamide
  • N-[4-[[4-(2-ethylphenyl)-1-piperazinyl]carbonyl]phenyl]-8-quinolinesulfonamide
  • N-[4-[[4-[3-(1-methylethoxy)phenyl]-1-piperazinyl]carbonyl]phenyl]-8-quinolinesulfonamide
  • 7-Hydroxy-1-methyl-2,3-dihydroimidazo[1,2-C]pyrimidin-5(1H)-one
  • 4-Bromo-1,3-dihydro-3-methyl-1-[[2-(trimethylsilyl)ethoxy]methyl]-2H-benzimidazol-2-one
  • 2H-Benzimidazol-2-one, 1,3-dihydro-1-methyl-7-(1-pyrrolidinylcarbonyl)-
  • 1,3-Dihydro-7-hydroxy-1-methyl-2h-benzimidazol-2-one
  • Methyl 4-((tert-butoxycarbonyl)(methyl)amino)thiophene-3-carboxylate
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