(S)-Glycidyl tosylate

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Names

[ Name ]:
(S)-Glycidyl tosylate

[Synonym ]:
(2S)-2-Oxiranylmethyl 4-methylbenzenesulfonate
T3OTJ B1OSWR D1 &&S Form
EINECS 417-210-7
[(2S)-oxiran-2-yl]methyl 4-methylbenzenesulfonate
(2S)-Glycidyl tosylate
2-Oxiranemethanol, 4-methylbenzenesulfonate, (2S)-
MFCD00064489
(2S)-Oxiran-2-ylmethyl-4-methylbenzolsulfonat
(2S)-Oxiran-2-ylmethyl 4-methylbenzenesulfonate
(S)-Glycidyl tosylate
(S)-(+)-Glycidyl tosylate

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
370.5±15.0 °C at 760 mmHg

[ Melting Point ]:
45-48ºC

[ Molecular Formula ]:
C₁₀H₁₂O₄S

[ Molecular Weight ]:
228.265

[ Flash Point ]:
177.9±20.4 °C

[ Exact Mass ]:
228.045624

[ PSA ]:
64.28000

[ LogP ]:
1.35

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.550

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: RR0510050

CHEMICAL NAME :: Oxiranemethanol, 4-methylbenzenesulfonate, (S)-

CAS REGISTRY NUMBER :: 70987-78-9

BEILSTEIN REFERENCE NO. :: 3592143

LAST UPDATED :: 199612

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: C10-H12-O4-S

MOLECULAR WEIGHT :: 228.28

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: Mutation test systems - not otherwise specified

TYPE OF TEST :: Cytogenetic analysis

MUTATION DATA

TEST SYSTEM :: Rodent - mouse

DOSE/DURATION :: 100 mg/kg

REFERENCE :: MUREAV Mutation Research. (Elsevier Science Pub. B.V., POB 211, 1000 AE Amsterdam, Netherlands) V.1- 1964- Volume(issue)/page/year: 298,197,1993

Safety Information

[ Symbol ]:

GHS05, GHS07, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H317-H318-H341-H350-H411

[ Precautionary Statements ]:
P201-P273-P280-P305 + P351 + P338-P308 + P313

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
T:Toxic

[ Risk Phrases ]:
R41;R43;R45;R51/53

[ Safety Phrases ]:
S45-S53-S61

[ RIDADR ]:
UN 3077

[ WGK Germany ]:
3

[ RTECS ]:
RR0510050

[ Hazard Class ]:
9.0

[ HS Code ]:
29109000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Tosyl chloride
(±)-Glycidol
Allyl alcohol

DownStream

1-(2,3-Dihydro-1,4-benzodioxin-2-yl)methanamine
(R)-(-)-Epichlorohydrin
(R)-(-)-1-Benzyloxy-3-(p-tosyloxy)-2-propanol
(S)-(+)-1-Benzyloxy-3-(p-tosyloxy)-2-propanol
2,3-Dihydro-1,4-benzodioxin-2-ylmethanol
Levodropropizine
phenyl glycidyl ether
(S)-N-Glycidylphthalimide
(R)-(-)-GLYCIDYL1-NAPHTHYLETHER

Customs

[ HS Code ]: 2910900090

[ Summary ]:
2910900090. epoxides, epoxyalcohols, epoxyphenols and epoxyethers, with a three-membered ring, and their halogenated, sulphonated, nitrated or nitrosated derivatives. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Henry, N. et al.

Tetrahedron Lett. 45 , 1465, (2004)

(S)-Glycidyl tosylate
(S)-Glycidyl nosylate
(S)-glycidyl 4-aminophenyl ether
(S)-glycidyl 3-methoxyphenyl ether
(S)-glycidyl nosylate
(S)-glycidyl methacrylate
1-[(2,4-dichloro-5-methylphenyl)sulfonyl]-2-methyl-1H-benzimidazole
4-Bromo-1-ethoxy-2-[(2-ethyl-4-methylimidazolyl)sulfonyl]benzene
(3aS)-1,3,3-triphenyl-3a,4,5,6-tetrahydropyrrolo[1,2-c][1,3,2]oxazaborole;1,1,1-trifluoro-N-(trifluoromethylsulfonyl)methanesulfonamide
4-(1-Methyl-1H-pyrrol-2-yl)benzonitrile
N-[2-[[2-[(2,6-Di-1-pyrrolidinyl-4-pyrimidinyl)amino]ethyl]methylamino]ethyl]-4-nitrobenzamide
N-(4-chloro-benzyl)-N-[3-(piperidine-1-carbonyl)-phenyl]-benzenesulfonamide
N-(2-aminophenyl)acrylamide
N-[1-(oxolan-2-ylmethyl)pyrazol-4-yl]prop-2-enamide
n-(1-(1h-Pyrazol-1-yl)propan-2-yl)isobutyramide
2-(2-Methoxyphenyl)-2-oxoethyl 4-(2-phenylethenesulfonamido)benzoate

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