2-[(Trimethylsilyl)methyl]-2-propen-1-yl acetate

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Names

[ CAS No. ]:
72047-94-0

[ Name ]:
2-[(Trimethylsilyl)methyl]-2-propen-1-yl acetate

[Synonym ]:
2-[(Trimethylsilyl)methyl]prop-2-en-1-yl acetate
2-(trimethylsilylmethyl)prop-2-enyl acetate
2-Propen-1-ol, 2-[(trimethylsilyl)methyl]-, acetate
2-[(Trimethylsilyl)methyl]-2-propen-1-yl acetate
2-Propen-1-ol, 2-(trimethylsilyl)methyl-, acetate
MFCD00075170

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
228.3±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₉H₁₈O₂Si

[ Molecular Weight ]:
186.324

[ Flash Point ]:
71.1±0.0 °C

[ Exact Mass ]:
186.107605

[ PSA ]:
26.30000

[ LogP ]:
3.10

[ Vapour Pressure ]:
0.1±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.423

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R14;R36/37/38

[ Safety Phrases ]:
26-36/37/39-37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Articles

[3+ 2] Cycloaddition of Trimethylenemethane and its Synthetic Equivalents. Yamago S and Nakamura E.

Org. React. , (2004)

2-Methyl-2-propen-1-yl acetate
2-[(Trimethylsilyl)methyl]-2-propen-1-ol
chlorodimethyl(2-methyl-2-propen-1-yl)silane
Benzene,[(2-methyl-2-propen-1-yl)oxy]-
1-(2-methyl-2-propen-1-yl)-5-oxoproline
Tributyl(2-methyl-2-propen-1-yl)stannane
[1-(Ethanesulfonyl)-2-methylpyrrolidin-2-yl]methanamine
2-(1-Methylpyrrolidin-3-yl)-6-oxo-1,6-dihydropyrimidine-5-carboxylic acid
6-Cyano-5-(difluoromethyl)-2-(trifluoromethyl)nicotinic acid
2-(Aminomethyl)-3-(difluoromethyl)-5-hydroxy-6-methylpyridine
2-(Difluoromethyl)-5-nitro-3-(trifluoromethyl)pyridine-4-methanol
4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
(6-(4-(Trifluoromethyl)cyclohex-1-enyl)pyrimidin-4-yl)methanamine
Ethyl 2-(3-methoxypiperidin-4-yl)acetate
2-(Bromomethyl)-6-(difluoromethyl)-4-(trifluoromethyl)pyridine-3-sulfonyl chloride
(4-(5-(1-ethyl-1H-pyrazol-5-yl)-1,2,4-oxadiazol-3-yl)piperidin-1-yl)(3-fluoro-4-methoxyphenyl)methanone