CHLOROMETHYL PHENYL SULFOXIDE

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Names

[ CAS No. ]:
7205-94-9

[ Name ]:
CHLOROMETHYL PHENYL SULFOXIDE

[Synonym ]:
dl-chloromethyl phenyl sulfoxide
chloromethyl-phenyl-sulfoxid
(chloromethylsulfinyl)benzene
chloromethyl phenyl sulfoxide
chloromethanesulfinyl-benzene
((Chloromethyl)sulphinyl)benzene
chloro(phenylsulfinyl)methane
chloromethyl phenyl sulphoxide

Chemical & Physical Properties

[ Density]:
1.35 g/cm3

[ Boiling Point ]:
109-111ºC0.01 mm Hg

[ Melting Point ]:
33-35ºC

[ Molecular Formula ]:
C7H7ClOS

[ Molecular Weight ]:
174.64800

[ Flash Point ]:
100ºC

[ Exact Mass ]:
173.99100

[ PSA ]:
36.28000

[ LogP ]:
2.85620

[ Index of Refraction ]:
1.618

[ Storage condition ]:
−20°C

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Safety Phrases ]:
S22-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • chloromethylthiobenzene
  • methyl phenyl sulfoxide
  • Thioanisole
  • diazomethane
  • Benzenesulfinic chloride
  • Diethyl ether

DownStream

  • Cyclohexanol, 1-[chloro(phenylsulfinyl)methyl]-
  • 2-(benzenesulfinyl)-1-oxaspiro[2.5]octane
  • 1-chloroethylsulfinylbenzene
  • Benzene,[(1-chloro-1-methylethyl)sulfinyl]-
  • methyl phenyl sulfoxide
  • chloromethylthiobenzene
  • CHLOROMETHYL PHENYL SULFONE
  • 1-phenyl-1-pentyn-3-ol

Articles

Development of new synthetic methods with aryl 1-chlorovinyl sulfoxides.

Chem. Rec. 3(6) , 329-41, (2004)

Aryl 1-chlorovinyl sulfoxides were easily synthesized from ketones and aldehydes with aryl chloromethyl sulfoxide in three-steps with high overall yields. Low-temperature treatment of the aryl 1-chlor...

M. Hojo et al.

Synthesis , 789, (1977)

K.M. Moore, J. Wemple

J. Org. Chem. 43 , 2713, (1978)


More Articles

Related Compounds

  • lithio α-chloromethyl phenyl sulfoxide
  • chloromethyl phenyl carbonate
  • CHLOROMETHYL PHENYL SULFONE
  • chloromethyl(phenyl)silane
  • chloromethyl(phenyl)germane
  • chloromethyl(phenyl)phosphinic methyl(phenyl)amide
  • 2-{1-[(Benzyloxy)carbonyl]pyrrolidin-3-yl}-2-hydroxyacetic acid
  • 1-([2,3'-Bifuran]-5-ylmethyl)-3-(2-(trifluoromethyl)phenyl)urea
  • Methyl (2-hydroxy-2-(5-(thiophen-3-yl)furan-2-yl)ethyl)carbamate
  • N-(2-hydroxy-2-(5-(thiophen-3-yl)furan-2-yl)ethyl)-2,5-dimethylfuran-3-carboxamide
  • N-(2-hydroxy-2-(5-(thiophen-3-yl)furan-2-yl)ethyl)-2-phenoxyacetamide
  • 2-(4-fluorophenyl)-N-(2-hydroxy-2-(5-(thiophen-3-yl)furan-2-yl)ethyl)acetamide
  • 2-(2,5-dioxopyrrolidin-1-yl)-N-(2-hydroxy-2-(5-(thiophen-3-yl)furan-2-yl)ethyl)acetamide
  • N'-[(E)-3-[3-[3,5-Bis(trifluoromethyl)phenyl]-1,2,4-triazol-1-yl]prop-2-enoyl]-2,2-dimethylpropanehydrazide
  • N-(2-hydroxy-2-(5-(thiophen-3-yl)furan-2-yl)ethyl)-2-phenylbutanamide
  • 5-(2-chloro-3,4-dimethoxyphenyl)-2H-1,2,3,4-tetrazole hydrochloride
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