(+)-2,2-DIMETHYL-4,5-((DIPHENYLPHOSPHINO)DIMETHYL)DIOXOLANE

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Names

[ CAS No. ]:
72656-47-4

[ Name ]:
(+)-2,2-DIMETHYL-4,5-((DIPHENYLPHOSPHINO)DIMETHYL)DIOXOLANE

[Synonym ]:
3-hydroxy-3-phenylpropionic acid ethyl ester
(R)-3-hydroxy-3-phenyl-propionic acid ethyl ester
MFCD00216720
(R)-3-hydroxy-3-phenylpropanoic acid ethyl ester
(+)-Ethyl (R)-3-hydroxy-3-phenylpropionate

Chemical & Physical Properties

[ Density]:
1.119g/cm3

[ Boiling Point ]:
315.296ºC at 760 mmHg

[ Molecular Formula ]:
C11H14O3

[ Molecular Weight ]:
194.22700

[ Flash Point ]:
132.598ºC

[ Exact Mass ]:
194.09400

[ PSA ]:
46.53000

[ LogP ]:
1.67320

[ Index of Refraction ]:
n20/D 1.510

MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Safety Phrases ]:
23-24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2918199090

Synthetic Route

Precursor & DownStream

Precursor

  • Ethyl 3-oxo-3-phenylpropanoate
  • 3-acetoxy derivative of ethyl 3-phenylpropionate
  • Benzaldehyde
  • Ethyl iodoacetate
  • (R)-3-ethoxy-3-oxo-1-phenylpropyl decanoate
  • ETHYL-3-HYDROXY-3-PHENYL PROPIONATE
  • ethyl 2-bromoacetate
  • 1-ethoxyethenoxy(trimethyl)silane
  • Cinnamic aldehyde

DownStream

  • (-)-Ethyl (S)-3-hydroxy-3-phenylpropionate
  • ETHYL-3-HYDROXY-3-PHENYL PROPIONATE
  • Benzenepropanoic acid, b-hydroxy-, butyl ester
  • methyl (3S)-3-hydroxy-3-phenylpropanoate
  • Ethyl 3-oxo-3-phenylpropanoate
  • (R)-(+)-3-HYDROXY-3-PHENYLPROPIONIC ACID
  • L-Phenylglycinol
  • METHYL (R)-3-HYDROXY-3-PHENYLPROPANOATE
  • (R)-1-PHENYL-1,3-PROPANEDIOL
  • methyl (3R)-3-hydroxy-3-phenyl-propanoate

Customs

[ HS Code ]: 2918199090

[ Summary ]:
2918199090 other carboxylic acids with alcohol function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

A. Kumar et al.

Tetrahedron Lett. 32 , 1901, (1991)

C. Greck et al.

Synlett , 475, (1993)


More Articles


Related Compounds

  • Ethyl 3-(4-bromo-3-chlorophenyl)-3-hydroxy-2,2-dimethylpropanoate
  • 3-Chloro-2-ethynylthiophene
  • 2-(5-Bromo-2-chlorophenyl)oxirane
  • Methyl 2-amino-2-(4-bromo-3-chlorophenyl)acetate
  • Ethyl 2-amino-2-(4-bromo-3-chlorophenyl)acetate
  • 8-Bromo-5-chloroisoquinolin-1(2H)-one
  • 1-(5-Bromo-2-chlorophenyl)ethane-1,2-diol
  • 1-(4-Bromo-3-chlorophenyl)ethane-1,2-diol
  • 2-(4-Bromo-3-chlorophenyl)-2-acetamidoacetic acid
  • 2-(4-Bromo-3-chlorophenyl)-2-{[(tert-butoxy)carbonyl]amino}acetic acid
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