4-Bromophenethylamine

Names

[ Name ]:
4-Bromophenethylamine

[Synonym ]:
2-(4-bromophenyl)ethan-1-amine
Benzeneethanamine, 4-bromo-
EINECS 277-636-2
2-(4-Bromophenyl)ethanamine
4-Bromophenethylamine
MFCD00008189
2-(4-Bromophenyl)ethylamine

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
271.3±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C₈H₁₀BrN

[ Molecular Weight ]:
200.076

[ Flash Point ]:
113.1±20.4 °C

[ Exact Mass ]:
198.999649

[ PSA ]:
26.02000

[ LogP ]:
2.23

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.576

MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 2735

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
8.0

[ HS Code ]:
2921499090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

4-Bromobenzyl cyanide
Benzene,1-bromo-4-(2-nitroethenyl)-
1-(4-bromophenyl)-2-nitroethane
4-Bromobenzaldehyde
Bis-(β-nitroso-4-brom-styrol)
4-Bromostyrene

DownStream

N-[2-(4-bromophenyl)ethyl]benzenesulfonamide
N-{[2-(4-Bromophenyl)ethyl]carbamothioyl}benzamide
2-(4-Bromophenyl)-N,N-dimethylethanamine
CHEMBRDG-BB 5128501
P-BROMOPHENETHYL AMINE HYDROCHLORIDE
Ethanone, 1-(7-bromo-3,4-dihydro-2(1H)-isoquinolinyl)-2,2,2-trifluoro-
N-(4-BROMOPHENETHYL)-2,2,2-TRIFLUOROACETAMIDE
N-(4-Bromophenethyl)isobutyramide
1-(6-bromo-3,4-dihydro-2(1H)-isoquinolinyl)-2,2,2-trifluoro-Ethanone
7-Bromo-3,4-dihydro-1(2H)-isoquinolinone

Customs

[ HS Code ]: 2921499090

[ Summary ]:
2921499090 other aromatic monoamines and their derivatives; salts thereof VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:30.0%

Articles

A facile one-pot preparation of alkyl aminoaryl sulfides for the synthesis of GW7647 as an agonist of peroxisome proliferator-activated receptor alpha.

J. Org. Chem. 71 , 5781, (2006)

We have developed two simple and high yielding one-pot syntheses of alkyl aminoaryl sulfides containing a series of four-steps: in situ protection of the free amine by reaction with a Grignard reagent...

Targeted LC-MS derivatization for aldehydes and carboxylic acids with a new derivatization agent 4-APEBA.

Anal. Bioanal. Chem 397 , 665-75, (2010)

Based on the template of a recently introduced derivatization reagent for aldehydes, 4-(2-(trimethylammonio)ethoxy)benzeneaminium dibromide (4-APC), a new derivatization agent was designed with additi...

Formation of pyrazinoisoquinoline ring system by the tandem amidoalkylation and N-acyliminium ion cyclization: An efficient synthesis of Praziquantel. Kim JH, et al.

Tetrahedron 54(26) , 7395-7400, (1998)

4-Bromophenethylamine
4-Bromophenethylamine
n-boc-4-bromophenethylamine
4-Bromophenethylamine hydrobromide
4-Bromophenethylamine hydrochloride
2,5-dimethoxy-4-bromophenethylamine
methyl 2-({2-[(methoxycarbonyl)amino]-1H-1,3-benzimidazol-6-yl}carbonyl)benzenecarboxylate
2-[3-chloro-5-(trifluoromethyl)-2-pyridinyl]-6-methyl-N-phenyl-4-pyrimidinamine
2-[3-chloro-5-(trifluoromethyl)-2-pyridinyl]-N,6-dimethyl-4-pyrimidinamine
4-Methyl-1-phenyl-5-(trifluoromethyl)-1,4-dihydropyridazine
(2E)-3-[1-(benzenesulfonyl)-1H-indol-5-yl]-N-(oxan-2-yloxy)prop-2-enamide
1-[(4-Chlorophenyl)methyl]-5,5-dimethylimidazolidine
3,5,11,13-Tetramethoxy-17-oxatetracyclo[7.7.1.0^{2,7}.0^{10,15}]heptadeca-2,4,6,10(15),11,13-hexaene-4,12-diol
1-[5-Phenyl-2-(propan-2-yl)-2,3-dihydro-1,3,4-oxadiazol-3-yl]ethan-1-one
6-[(4-methylphenyl)sulfanyl]-9H-purin-2-amine
tert-butyl 4-[(9R)-9-(4-cyanophenyl)-3-(3,5-dichlorophenyl)-1-methyl-2,4-dioxo-1,3,7-triazaspiro[4.4]nonan-7-yl]benzoate

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