sulfometuron-methyl [ANSI]

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Names

[ CAS No. ]:
74222-97-2

[ Name ]:
sulfometuron-methyl [ANSI]

[Synonym ]:
methyl 2-{[(4,6-dimethylpyrimidin-2-yl)carbamoyl]sulfamoyl}benzoate
sulfometuron-methyl
DPX T5648
Sulfometuron methyl ester
methyl 2-(4,6-dimethylpyrimidin-2-ylcarbamoylsulfamoyl)benzoate
Methyl 2-{[(4,6-dimethyl-2-pyrimidinyl)carbamoyl]sulfamoyl}benzoate
methyl 2-[(4,6-dimethylpyrimidin-2-yl)carbamoylsulfamoyl]benzoate
Benzoic acid, 2-[[[[(4,6-dimethyl-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]-, methyl ester
methyl 2-[3-(4,6-dimethylpyrimidin-2-yl)ureidosulfonyl]benzoate
sulfometuron-methyl [ANSI]
T6N CNJ BMVMSWR BVO1& D1 F1
methyl 2-[[[[(4,6-dimethyl-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]benzoate
EINECS 277-780-6
2-[[[[(4,6-Dimethyl-2-pyrimidinyl)amino]carbonyl]amino]sulfonyl]benzoic Acid Methyl Ester
MFCD00128060
N-[(4,6-Dimethylpyrimidin-2-yl)aminocarbonyl]-2-methoxycarbonylbenzenesulfonamide

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Melting Point ]:
203-205°C

[ Molecular Formula ]:
C15H16N4O5S

[ Molecular Weight ]:
364.376

[ Exact Mass ]:
364.084137

[ PSA ]:
135.73000

[ LogP ]:
2.18

[ Index of Refraction ]:
1.601

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DG9096550
CHEMICAL NAME :
Benzoic acid, o-((3-(4,6-dimethyl-2-pyrimidinyl)ureido)sulfonyl)-, methyl ester
CAS REGISTRY NUMBER :
74222-97-2
BEILSTEIN REFERENCE NO. :
0965602
LAST UPDATED :
199712
DATA ITEMS CITED :
8
MOLECULAR FORMULA :
C15-H16-N4-O5-S
MOLECULAR WEIGHT :
364.41

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
DUPON* E.I. Dupont de Nemours and Company, Technical Sheet. (1007 Market St., Wilmington, DE 19898) Volume(issue)/page/year: AG-361 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
DUPON* E.I. Dupont de Nemours and Company, Technical Sheet. (1007 Market St., Wilmington, DE 19898) Volume(issue)/page/year: AG-361
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>5 gm/m3/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
DUPON* E.I. Dupont de Nemours and Company, Technical Sheet. (1007 Market St., Wilmington, DE 19898) Volume(issue)/page/year: AG-361
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
DUPON* E.I. Dupont de Nemours and Company, Technical Sheet. (1007 Market St., Wilmington, DE 19898) Volume(issue)/page/year: AG-361
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Bird - duck
DOSE/DURATION :
>5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,774,1991 *** REVIEWS *** ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 5 mg/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** EPA FIFRA 1988 PESTICIDE SUBJECT TO REGISTRATION OR RE-REGISTRATION FEREAC Federal Register. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) V.1- 1936- Volume(issue)/page/year: 54,7740,1989

Safety Information

[ Symbol ]:

GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H400

[ Precautionary Statements ]:
P273

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Hazard Codes ]:
N

[ Risk Phrases ]:
R50

[ Safety Phrases ]:
S61

[ RIDADR ]:
UN3077 9/PG 3

[ RTECS ]:
DG9096550

[ Hazard Class ]:
9.0

Synthetic Route

Precursor & DownStream

Precursor

  • 2-Amino-4,6-dimethylpyrimidine
  • methyl 2-chlorosulfonylbenzoate
  • Methyl 2-[(oxomethylene)sulfamoyl]benzoate

DownStream

  • sulfometuron

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Related Compounds

  • Bensulfuron-methyl [ANSI, WSSA]
  • tribenuron-methyl [ANSI]
  • N-[(4,6-dimethoxypyrimidin-2-yl)aminocarbonyl]-2-methoxycarbonylbenzenesulfonamide
  • furophanate
  • Cyclopropanecarboxylicacid, 2,2-dimethyl-3-(2-methyl-1-propen-1-yl)-, (2,4-dimethylphenyl)methylester
  • Lactofen
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • 2-(1-Bromo-2-oxopropyl)-6-(trifluoromethylthio)phenol
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • Pentyl 3-formyl-1h-indole-6-carboxylate
  • Methyl 3-[[(2-nitro-5-phenoxyphenyl)amino]methyl]benzoate
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • tert-Butyl 3-(3-chloro-4-(methoxycarbonyl)phenyl)-1,4-diazepane-1-carboxylate
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide