Methyl bromopyruvate

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Names

[ CAS No. ]:
7425-63-0

[ Name ]:
Methyl bromopyruvate

[Synonym ]:
Methyl 3-bromo-2-oxopropanoate
Propanoic acid, 3-bromo-2-oxo-, methyl ester
MFCD01862963
Methyl bromopyruvate

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
186.8±23.0 °C at 760 mmHg

[ Molecular Formula ]:
C4H5BrO3

[ Molecular Weight ]:
180.985

[ Flash Point ]:
66.8±22.6 °C

[ Exact Mass ]:
179.942200

[ PSA ]:
43.37000

[ LogP ]:
0.21

[ Vapour Pressure ]:
0.7±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.468

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
UN 3334

[ WGK Germany ]:
3

[ HS Code ]:
2918300090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methanol
  • 3-Bromopyruvic acid
  • Methyl pyruvate
  • (−)-Methyl L-lactate

DownStream

  • 2(1H)-Quinoxalinone,3-(bromomethyl)-
  • Methyl 2-aminooxazole-4-carboxylate
  • Methyl 2-aminothiazole-4-carboxylate
  • methyl 2-oxo-3-(triphenyl-λ5-phosphanylidene)propanoate
  • IMidazo[1,2-a]pyridine-2-carboxylic acid, 8-(trifluoromethyl)-, Methyl ester
  • methyl 8-chloroimidazo[1,2-a]pyrazine-2-carboxylate
  • Methyl 2-phenyl-1,3-thiazole-4-carboxylate
  • Methyl imidazo[1,2-a]pyrazine-2-carboxylate
  • Methyl 2-methylthiazole-4-carboxylate

Customs

[ HS Code ]: 2918300090

[ Summary ]:
2918300090 other carboxylic acids with aldehyde or ketone function but without other oxygen function, their anhydrides, halides, peroxides, peroxyacids and their derivatives。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:6.5%。General tariff:30.0%

Articles

Variable involvement of the perivascular retinal tissue in carbonic anhydrase inhibitor induced relaxation of porcine retinal arterioles in vitro.

Invest. Ophthalmol. Vis. Sci. 48(10) , 4688-93, (2007)

Inhibition of carbonic anhydrase in the eye is an important treatment modality for reducing the intraocular pressure in glaucoma. However, evidence suggests that carbonic anhydrase inhibition also exe...

Protecting-group-free total synthesis of (+/-)-subincanadine F.

J. Org. Chem. 74(19) , 7533-5, (2009)

With chemoselective Dieckmann condensation as the key step, the protective-group-free total synthesis of (+/-)-subincanadine F was accomplished in 7 steps from the commercially available tryptamine in...

Further degradation products of cephalosporin C. Isolation and synthesis of 2-(4-amino-4-carboxybutyl)thiazole-4-carboxylic acid.

Biochem. J. 75(2) , 216, (1960)


More Articles

Related Compounds

  • 3-Bromo-2-oxobutanoic acid
  • methyl 3-azido-2-methylidenehexanoate
  • methyl 3-azido-4-methyl-2-methylidenehexanoate
  • methyl 4-bromo-5-hydroxyhexanoate
  • methyl (3S)-3-hydroxy-5-methylhexanoate
  • methyl 6-(2-hydroxyethoxy)hexanoate
  • 4-((Cyclohexylamino)methyl)benzoic acid hydrochloride
  • ethyl (1S,3R,4S)-4-(tert-butoxycarbonylamino)-3-fluoro-cyclohexanecarboxylate
  • 1-[(2,4-Dichlorophenyl)methyl]-N-(1,1-dimethylethyl)-2-methyl-1H-indole-3-methanamine
  • 2-Methoxy-6-(pyrazol-1-yl)-benzonitrile
  • 1H-3-Benzazepin-7-ol, 8-chloro-2,3,4,5-tetrahydro-5-(3-iodophenyl)-3-methyl-, (S)-
  • 2-[(4-bromo-2-pyridinyl)methylamino]-N-methylAcetamide
  • (4-Methyl-tetrahydro-furan-2-yl)-methanol
  • methyl 2,6-bis(tetramethyl-1,3,2-dioxaborolan-2-yl)-1H-indole-4-carboxylate
  • N-(1-cyanocyclopentyl)-2-[4-(4-fluorobenzenesulfonyl)-1,4-diazepan-1-yl]acetamide
  • 4,5,6,7-Tetrahydrobenzo[d]isoxazole-3-carbaldehyde