3-Bromo-7-azaindole

Names

[ CAS No. ]:
74420-15-8

[ Name ]:
3-Bromo-7-azaindole

[Synonym ]:
MFCD02179276
3-Bromo-1H-pyrrolo[2,3-b]pyridine
1H-Pyrrolo[2,3-b]pyridine, 3-bromo-

Chemical & Physical Properties

[ Density]:
1.8±0.1 g/cm3

[ Boiling Point ]:
336.4ºC at 760 mmHg

[ Melting Point ]:
185-189ºC

[ Molecular Formula ]:
C₇H₅BrN₂

[ Molecular Weight ]:
197.03

[ Flash Point ]:
157.3ºC

[ Exact Mass ]:
195.963608

[ PSA ]:
28.68000

[ LogP ]:
2.80

[ Index of Refraction ]:
1.728

MSDS

Safety Information

[ Symbol ]:

GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301-H315-H318-H335

[ Precautionary Statements ]:
P261-P280-P301 + P310-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
R22;R37/38;R41

[ Safety Phrases ]:
26-36/37/39

[ RIDADR ]:
UN 2811

[ HS Code ]:
2933990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

3-Bromo-1-(triisopropylsilyl)-1H-pyrrolo[2,3-b]pyridine
3-bromo-1-(4-methylbenzenesulfonyl)-1H-pyrrolo[2,3-b]pyridine
1H-Pyrrolo[2,3-b]pyridine, 3-bromo-1-[(1,1-dimethylethyl)dimethylsilyl]-
1-BENZYL-3-BROMO-7-AZAINDOLE
3-Bromo-1-(phenylsulfonyl)-1H-pyrrolo[2,3-b]pyridine
3-Bromo-1-methyl-1H-pyrrolo[2,3-b]pyridine
tert-butyl 3-bromo-1H-pyrrolo[2,3-b]pyridine-1-carboxylate
(1-Tosyl-1H-pyrrolo[2,3-b]pyridin-3-yl)boronic acid
1-(Phenylsulfonyl)-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyrrolo[2,3-b]pyridine
1H-Pyrrolo[2,3-b]pyridin-3-amin

Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Highly and Broad-Spectrum In Vitro Antitumor Active cis-Dichloridoplatinum(II) Complexes with 7-Azaindoles.

PLoS ONE 10 , e0136338, (2015)

The cis-[PtCl2(naza)2] complexes (1-3) containing monosubstituted 7-azaindole halogeno-derivatives (naza), showed significantly higher activity than cisplatin towards ovarian carcinoma A2780, its cisp...

J. Am. Chem. Soc. 78 , 1247, (1956)

4-Amino-3-bromo-7-azaindole
5-Amino-3-Bromo-7-azaindole
1-BENZYL-3-BROMO-7-AZAINDOLE
3-Bromo-7-azaindole-5-carbaldehyde
3-bromo-7-azaindole-4-carbaldehyde
3-bromo-7-azaindole-5-carboxylic acid
N-(5-((4-fluorobenzyl)sulfonyl)-1,3,4-thiadiazol-2-yl)-2-(4-methoxyphenyl)acetamide
(Z)-ethyl 2-((2-((6-bromo-4H-benzo[d][1,3]dioxin-8-yl)methylene)-3-oxo-2,3-dihydrobenzofuran-6-yl)oxy)acetate
5,11-Dibenzyl-8-sulfanylidenespiro[3,5,7,11-tetrazatricyclo[7.3.1.02,7]tridec-2-ene-13,1'-cyclopentane]-1,9-dicarbonitrile
(2E)-2-[(5-methoxy-1-methyl-1H-indol-3-yl)methylidene]-7-methyl-3-oxo-2,3-dihydro-1-benzofuran-6-yl 2-fluorobenzoate
2',3',9',10'-tetrahydrospiro(cyclohexane-1,8'-cyclopenta[c]pyrano[3,2-g]chromene)-4'(1'H)-thione
2-(Benzo[d]furan-2-ylmethylene)-6-hydroxy-4-methyl-7-(piperidylmethyl)benzo[b] furan-3-one
1-(Tetrazolo[1,5-a]pyridin-7-yl)ethanone
2-[4-(4-fluorophenyl)piperazin-1-yl]-N-(4-methyl-5-oxo-5,6,7,8-tetrahydroquinazolin-2-yl)acetamide
(2Z)-2-(1,3-benzodioxol-5-ylmethylidene)-3-oxo-2,3-dihydro-1-benzofuran-6-yl 4-fluorobenzoate
N-(2-methoxybenzyl)-1-[3-(trifluoromethyl)[1,2,4]triazolo[4,3-b]pyridazin-6-yl]piperidine-4-carboxamide

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