methyl dichlorosilane

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Names

[ CAS No. ]:
75-54-7

[ Name ]:
methyl dichlorosilane

[Synonym ]:
Methyldichlorosilan
methyl dichlorosilane
monomethyldichlorosilane
dichloromethyl-silan
CM8750
Dichloro(methyl)silane
Silane,methyldichloro
Silane, dichloromethyl-
Silane,dichloromethyl
Methyl-dichlorsilan
METHYLSILICON DICHLORIDE
methyldichlorosilae
METHYLDICHLOROSILANE
MFCD00000494
EINECS 200-877-1

Chemical & Physical Properties

[ Density]:
1.105 g/mL at 25 °C(lit.)

[ Boiling Point ]:
38.4±9.0 °C at 760 mmHg

[ Melting Point ]:
-93 °C

[ Molecular Formula ]:
CH4Cl2Si

[ Molecular Weight ]:
115.034

[ Flash Point ]:
-32.2±0.0 °C

[ Exact Mass ]:
113.945930

[ LogP ]:
3.77

[ Vapour density ]:
4 (vs air)

[ Vapour Pressure ]:
468.2±0.1 mmHg at 25°C

[ Index of Refraction ]:
n20/D 1.398(lit.)

[ Water Solubility ]:
DECOMPOSES

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
VV3500000
CHEMICAL NAME :
Silane, dichloromethyl-
CAS REGISTRY NUMBER :
75-54-7
BEILSTEIN REFERENCE NO. :
1071194
LAST UPDATED :
199709
DATA ITEMS CITED :
6
MOLECULAR FORMULA :
C-H4-Cl2-Si
MOLECULAR WEIGHT :
115.04
WISWESSER LINE NOTATION :
G-SI-HG1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1218,1986
TYPE OF TEST :
Standard Draize test
ROUTE OF EXPOSURE :
Administration into the eye
SPECIES OBSERVED :
Rodent - rabbit
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1218,1986 ** ACUTE TOXICITY DATA **
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2830 uL/kg
TOXIC EFFECTS :
Sense Organs and Special Senses (Eye) - lacrimation Lungs, Thorax, or Respiration - other changes Gastrointestinal - other changes
REFERENCE :
ATDAEI Acute Toxicity Data. Journal of the American College of Toxicology, Part B. (Mary Ann Liebert, Inc., 1651 Third Ave., New York, NY 10128) V.1- 1990- Volume(issue)/page/year: 12,572,1993
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
300 ppm/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85JCAE "Prehled Prumyslove Toxikologie; Organicke Latky," Marhold, J., Prague, Czechoslovakia, Avicenum, 1986 Volume(issue)/page/year: -,1218,1986 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X3236 No. of Facilities: 10 (estimated) No. of Industries: 2 No. of Occupations: 5 No. of Employees: 371 (estimated) No. of Female Employees: 34 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS05, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H261-H301 + H331-H314

[ Supplemental HS ]:
Corrosive to the respiratory tract., Reacts violently with water.

[ Precautionary Statements ]:
P210-P231 + P232-P261-P280-P301 + P310-P422

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
F:Flammable;C:Corrosive;

[ Risk Phrases ]:
R11;R14/15;R34;R37

[ Safety Phrases ]:
S16-S26-S36/37/39-S43-S45-S7/8-S30

[ RIDADR ]:
UN 1242 4.3/PG 1

[ WGK Germany ]:
1

[ RTECS ]:
VV3500000

[ Packaging Group ]:
I

[ Hazard Class ]:
4.3

Synthetic Route

Precursor & DownStream

Precursor

  • Methyltrichlorosilane
  • 1,2-dichloro-tetramethyldisilane
  • Chloromethane
  • Silicon
  • Trichloro(chloromethyl)silane
  • methane
  • Chlorodimethylsilane
  • Dichlorodimethylsilane
  • methylsilane
  • Hexamethyldisilane

DownStream

  • methyl(dipentyl)silane
  • Di-n-Hexyl(methyl)silane
  • 3-[Dichloro(methyl)silyl]propanenitrile
  • 1h,1h,2h,2h-perfluorodecylmethyldichlorosilane
  • Methyl[bis(2-methyl-2-propanyl)]silane
  • ethane-1,2-diylbis(dichloromethylsilane)
  • Dichloro(methyl)vinylsilane
  • 1,4-Butanediylbis[dichloro(methyl)silane]
  • Dichloro(cyclohexyl)methylsilane

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Related Compounds

  • Ethyl methyl dichlorosilane
  • ethoxy methyl dichlorosilane
  • 2-Cyanoethyl methyl dichlorosilane
  • NORBORNENYL ETHYL METHYL DICHLOROSILANE
  • 3,3-Dimethylbutyl Methyl Dichlorosilane
  • chloromethylpropyl methyl dichlorosilane
  • 4-(1-Cyclohexen-1-yl)-3-(1-hydroxyethyl)-1H-2-benzopyran-1-one
  • 4-(2-Amino-5-pyrimidinyl)-3-(1-bromoethyl)-1H-2-benzopyran-1-one
  • 4-phenyl-1H-isochromene-3-carbaldehyde
  • 1-Piperidineethanamine, I(2)-methyl-N-(2-methyl-6-nitrophenyl)-
  • 6-[(1-Methylethyl)-2-propen-1-ylamino]-3-pyridinecarbonitrile
  • 3-(1-Bromoethyl)-4-[5-(4,4,5,5-tetramethyl-1,3-dioxolan-2-yl)-2-thienyl]-1H-2-benzopyran-1-one
  • 4-chloro-1H-isochromene-3-carbaldehyde
  • Methyl 2-(3-(tert-butoxycarbonylamino)but-1-ynyl)benzoate
  • N,1-bis(tetrahydro-2H-pyran-2-yl)-3-(trifluoromethyl)-1H-pyrazolo[3,4-d]pyrimidin-4-amine
  • 3-(1-Bromoethyl)-7-methyl-4-phenyl-1H-2-benzopyran-1-one
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