TMS

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Names

[ CAS No. ]:
75-76-3

[ Name ]:
TMS

[Synonym ]:
trimethylchlorosilane
CT2050
Tetramethylsilicane
Tetramethylsilane
tetramethyl-silan
tSILICON TETRAMETHYL
Silane,tetramethyl
MFCD00008274
UNII-5YV3GII1TB
TMS
EINECS 200-899-1

Chemical & Physical Properties

[ Density]:
0.648 g/mL at 25 °C(lit.)

[ Boiling Point ]:
26-28 °C(lit.)

[ Melting Point ]:
-99 °C

[ Molecular Formula ]:
C4H12Si

[ Molecular Weight ]:
88.2248

[ Flash Point ]:
-27 °C

[ Exact Mass ]:
88.071

[ LogP ]:
3.24

[ Vapour Pressure ]:
718 mm Hg at 25 °C

[ Index of Refraction ]:
n20/D 1.358(lit.)

[ Storage condition ]:
0-6°C

[ Stability ]:
Stable. Highly flammable - readily forms explosive mixtures with air. Note the boiling point close to room temperature, the low flash point and high vapour pressure. Incompatible with oxidizing agents. Refrigerate before opening.

[ Water Solubility ]:
0.02 G/L (25 ºC)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H224

[ Precautionary Statements ]:
P210

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
F+:Highlyflammable;

[ Risk Phrases ]:
R12

[ Safety Phrases ]:
S36-S45-S33-S3/7-S16-S9

[ RIDADR ]:
UN 2810 6.1/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
I

[ Hazard Class ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Trichloro(2-chloroethyl)silane
  • lithium,chloromethyl(trimethyl)silane
  • [diphenylmanganese]
  • Tetrachlorosilane
  • 2-(Trimethylsilyl)ethanol
  • triphenylvanadium
  • tetra-n-butylammonium nitridotetrakis(trimethylsilylmethyl)ruthenium(VI)
  • diphenyliron
  • TRIMETHYLSILYLMETHYL ISOCYANIDE

DownStream

  • (Trimethylsilyl)methanol
  • Benzene,1-methyl-4-(trimethylsilyl)-
  • trimethyl-(3-methylphenyl)silane
  • 9-methyldecalin
  • Decahydronaphthalene
  • 4-Methylphthalonitrile
  • 4-methylbenzene-1,3-dicarbonitrile
  • 2-Methylterephthalonitrile
  • 5-methylbenzene-1,2,4-tricarbonitrile

Articles

Novel Dammarane-Type Triterpene Saponins from Panax ginseng Root.

Chem. Pharm. Bull. 63 , 927-34, (2015)

Four phytochemical constituents were isolated from Panax ginseng root by repeated column chromatography (CC), medium pressure liquid chromatography (MPLC), high-speed counter current chromatography (H...

Curdlan-Conjugated PLGA Nanoparticles Possess Macrophage Stimulant Activity and Drug Delivery Capabilities.

Pharm. Res. 32 , 2713-26, (2015)

There is significant interest in the application of nanoparticles to deliver immunostimulatory signals to cells. We hypothesized that curdlan (immune stimulating polymer) could be conjugated to PLGA a...

Chirality of Single-Handed Twisted Titania Tubular Nanoribbons Prepared Through Sol-gel Transcription.

Chirality 27 , 543-50, (2015)

Single-handed twisted titania tubular nanoribbons were prepared through sol-gel transcription using a pair of enantiomers. Handedness was controlled by that of the template. The obtained samples were ...


More Articles

Related Compounds

  • TMS
  • TMSI
  • TMSI
  • TMSTf
  • TMSOTf
  • TMS-CT
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