(2S)-2-Methylpiperazine

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Names

[ CAS No. ]:
75336-86-6

[ Name ]:
(2S)-2-Methylpiperazine

[Synonym ]:
MFCD00192317
(R)-2-methylpiperazine
(S)-(+)-2-Methylpiperazine
(R)-2-Methyl piperazine (L)tataric acid salt
Piperazine, 2-methyl-, (2R)-
Piperazine, 2-methyl-, (2S)-
(2S)-2-Methylpiperazine
(R)-(-)-2-Methylpiperazine
(2R)-2-Methylpiperazine
(R)-(+)-2-Methylpiperazine

Chemical & Physical Properties

[ Density]:
0.8±0.1 g/cm3

[ Boiling Point ]:
153.2±8.0 °C at 760 mmHg

[ Melting Point ]:
86-93ºC

[ Molecular Formula ]:
C5H12N2

[ Molecular Weight ]:
100.16

[ Flash Point ]:
45.1±10.2 °C

[ Exact Mass ]:
100.100044

[ PSA ]:
24.06000

[ LogP ]:
-0.68

[ Vapour Pressure ]:
3.4±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.418

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H228-H315-H319-H335

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R11;R34

[ Safety Phrases ]:
S16-S26-S36/37/39-S45

[ RIDADR ]:
UN 1325

[ WGK Germany ]:
2

[ Packaging Group ]:
III

[ Hazard Class ]:
4.1

[ HS Code ]:
2933599090

Synthetic Route

Precursor & DownStream

Precursor

  • (R)-2-HYDROXYMETHYLHEXANOICACID
  • (R)-1-BENZYL-3-METHYLPIPERAZINE
  • Z-Gly-D-Ala-OMe
  • 1-BENZYL-3-METHYL-PIPERAZINE-2,5-DIONE
  • 2,5-Piperazinedione,3-methyl-,(3R)-(9CI)
  • Ethylene glycol

DownStream

  • BMS-378806
  • (R)-1-(3-chloropyridin-2-yl)-3-methylpiperazine
  • 1-Trityl-(R)-3-methylpiperazine
  • 4-benzoyl-2-methyl-1-[(7-oxido-1h-pyrrolo[2,3-b] pyridin-3-yl)oxoacetyl]-piperazine
  • (R)-2-HYDROXYMETHYLPROPANOICACID
  • (R)-2-CHLORO-3-(2-METHYLPIPERAZIN-1-YL)PYRAZINE
  • (R)-1-BENZYL-3-METHYLPIPERAZINE
  • (R)-1-Cbz-3-methylpiperazine
  • (R)-1-Boc-3-Methylpiperazine
  • (R)-METHYL 4-(3-METHYLPIPERAZIN-1-YL)BENZOATE

Customs

[ HS Code ]: 2933599090

[ Summary ]:
2933599090. other compounds containing a pyrimidine ring (whether or not hydrogenated) or piperazine ring in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Org. Prep. Proced. Int. 22 , 761, (1990)


More Articles


Related Compounds

  • (2S)-2-Methylpiperazine
  • (2S)-2-Methylpiperazine
  • (2S)-2-Methylpiperazine dihydrochloride
  • ethyl (2S)-2-methylpiperazine-1-carboxylate
  • tert-butyl (2S)-2-methylpiperazine-1-carboxylate
  • benzyl (2S)-2-methylpiperazine-1-carboxylate,hydrochloride