Titanium tetrachloride

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Names

[ CAS No. ]:
7550-45-0

[ Name ]:
Titanium tetrachloride

[Synonym ]:
Titanium tetrachloride
EINECS 231-441-9
MFCD00011267

Chemical & Physical Properties

[ Density]:
1.726

[ Boiling Point ]:
135-136ºC

[ Melting Point ]:
-25ºC

[ Molecular Formula ]:
Cl4Ti

[ Molecular Weight ]:
189.679

[ Flash Point ]:
8ºC

[ Exact Mass ]:
187.823364

[ LogP ]:
2.75800

[ Vapour Pressure ]:
50 mm Hg ( 55 °C)

[ Index of Refraction ]:
1.61

[ Stability ]:
Stable. Reacts with water. Incompatible with moisture, ammonia, amines, alcohols, potassium and other chemically active metals.

[ Water Solubility ]:
H2O: soluble | reacts

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
XR1925000
CHEMICAL NAME :
Titanium chloride (TiCl4)
CAS REGISTRY NUMBER :
7550-45-0
LAST UPDATED :
199710
DATA ITEMS CITED :
7
MOLECULAR FORMULA :
Cl4-Ti
MOLECULAR WEIGHT :
189.70
WISWESSER LINE NOTATION :
TI G4

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
400 mg/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,111,1982
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
100 mg/m3/2H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982 Volume(issue)/page/year: -,111,1982 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
10 mg/m3/6H/2Y-I
TOXIC EFFECTS :
Lungs, Thorax, or Respiration - other changes Lungs, Thorax, or Respiration - changes in lung weight Related to Chronic Data - death
REFERENCE :
TXAPA9 Toxicology and Applied Pharmacology. (Academic Press, Inc., 1 E. First St., Duluth, MN 55802) V.1- 1959- Volume(issue)/page/year: 83,30,1986 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 84219 No. of Facilities: 62 (estimated) No. of Industries: 3 No. of Occupations: 9 No. of Employees: 1337 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 84219 No. of Facilities: 81 (estimated) No. of Industries: 3 No. of Occupations: 5 No. of Employees: 2107 (estimated) No. of Female Employees: 131 (estimated)

Safety Information

[ Symbol ]:

GHS05, GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314-H330-H370-H372

[ Supplemental HS ]:
Corrosive to the respiratory tract., Reacts violently with water.

[ Precautionary Statements ]:
P260-P280-P284-P305 + P351 + P338-P310

[ Target Organs ]:
Blood, Central nervous system, Liver

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable;C:Corrosive;

[ Risk Phrases ]:
R11;R14;R34;R48/20;R63;R65;R67

[ Safety Phrases ]:
S26-S36/37/39-S45-S46-S62-S7/8

[ RIDADR ]:
UN 1838/2443

[ WGK Germany ]:
2

[ RTECS ]:
XR1925000

[ Packaging Group ]:
II

[ HS Code ]:
2827399000

Precursor & DownStream

Precursor

  • Titanous chloride
  • titanium
  • Carbon tetrachloride
  • Trichlorosilane
  • titanium tetrafluoride
  • Titanium(IV) iodide
  • Phosphorus trichloride
  • Hydrochloric acid
  • Niobium(V) Chloride

DownStream

  • Terabutyl titanate
  • Silane, tetrabutoxy-
  • Titanium(4+) tetrakis(diethylazanide)
  • Bromine
  • 2,2,3,3-tetrachlorooxolane,titanium
  • Titanium(4+) chloride-cyclopentanethiol (1:4:2)
  • bis-(Mercaptocyclohexane)titanium tetrachloride
  • 2,3,4,5-tetrachloropyridine,titanium
  • tert-butyl chloride

Customs

[ HS Code ]: 2827399000

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Related Compounds

  • titanium tetrachloride
  • Titanium tetrachloride,urea complex
  • titanium tetrachloride tetrahydrofuran complex
  • BIS(MERCAPTOCYCLOHEXANE)TITANIUM TETRACHLORIDE
  • Bis(mercaptocyclopentane)titanium tetrachloride
  • Titanium tetrachloride,reaction product with magnesium ethylate