Allyl(triphenyl)stannane

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Names

[ CAS No. ]:
76-63-1

[ Name ]:
Allyl(triphenyl)stannane

[Synonym ]:
MFCD00048162
Allyl(triphenyl)stannane
Stannane, triphenyl-2-propen-1-yl-
triphenyl(prop-2-enyl)stannane
EINECS 200-975-4

Chemical & Physical Properties

[ Density]:
1,07 g/cm3

[ Boiling Point ]:
421.4±38.0 °C at 760 mmHg

[ Melting Point ]:
71-74 °C(lit.)

[ Molecular Formula ]:
C₂₁H₂₀Sn

[ Molecular Weight ]:
391.094

[ Flash Point ]:
211.8±13.9 °C

[ Exact Mass ]:
392.058685

[ LogP ]:
9.57

[ Vapour Pressure ]:
0.0±1.0 mmHg at 25°C

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: WH6705000

CHEMICAL NAME :: Stannane, allyltriphenyl-

CAS REGISTRY NUMBER :: 76-63-1

BEILSTEIN REFERENCE NO. :: 3612762

LAST UPDATED :: 199712

DATA ITEMS CITED :: 24

MOLECULAR FORMULA :: C21-H20-Sn

MOLECULAR WEIGHT :: 391.10

WISWESSER LINE NOTATION :: 1U2-SN-R&R&R

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intravenous

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 100 mg/kg

REFERENCE :: CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#02200 *** REVIEWS *** ACGIH TLV-TWA 0.1 mg(Sn)/m3;STEL 0.2 mg/m3 (skin) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 0.1 mg(Sn)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,258,1971 OSHA PEL (Gen Indu):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 0.1 mg(Sn)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-BELGIUM:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-DENMARK:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-FINLAND:TWA 0.1 mg(Sn)/m3;STEL 0.3 mg(Sn)/m3;Skin JAN 1993 OEL-FRANCE:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3 JAN 1993 OEL-GERMANY:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-HUNGARY:STEL 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-THE NETHERLANDS:TWA 0.1 mg(Sn)/m3;Skin JAN 1993 OEL-THE PHILIPPINES:TWA 0.1 mg(Sn)/m3 JAN 1993 OEL-SWEDEN:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3;Skin JAN 1993 OEL-SWITZERLAND:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3;Skin JAN 1993 OEL-THAILAND:TWA 0.1 mg(Sn)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 0.1 mg(Sn)/m3;STEL 0.2 mg(Sn)/m3;Skin JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO ORGANOTIN COMPOUND-air:10H TWA 0.1 mg(Sn)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

Safety Information

[ Symbol ]:

GHS06, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H311 + H331-H410

[ Precautionary Statements ]:
P261-P273-P280-P301 + P310 + P330-P302 + P352 + P312-P304 + P340 + P312

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
T,N

[ Risk Phrases ]:
23/24/25-50/53

[ Safety Phrases ]:
S26-S27-S28-S45-S60-S61

[ RIDADR ]:
UN 3146 6.1/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
WH6705000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

Articles

J. Am. Chem. Soc. 103 , 1969, (1981)

Allyl(triphenyl)phosphonium bromide
Allyl(triphenyl)silane
Allyl(triphenyl)phosphonium chloride
diphenylphosphoryloxy(triphenyl)stannane
mesityl-triphenyl stannane
chloro-triphenyl-stannane; diphenylphosphorylbenzene
3,5-dibromo-N,N-diphenylaniline
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5-Tert-butyl-2-(propan-2-YL)phenol
1-(2-(5,5,8,8-Tetramethyl-5,6,7,8-tetrahydronaphthalen-2-yl)pyridin-4-yl)piperidin-4-amine
5-(4-((4-Bromothiazol-2-yl)oxy)piperidin-1-yl)-3-isopropyl-1,2,4-oxadiazole
1-[2-(4-Fluoro-phenyl)-thiazol-4-yl]-ethanone
Acetamide, N-(3-fluorophenyl)-2-[[[[4-(2-phenyldiazenyl)phenyl]amino]carbonyl]amino]-
2-(Pyrimidin-5-yl)butanoic acid
1-(2-(4-Isopropoxy-3-isopropylphenyl)pyrimidin-4-yl)piperidin-4-amine
(5-(4-(3-(Tert-butyl)-4-isopropoxyphenyl)pyrimidin-2-yl)pyridin-2-yl)methanamine

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