Triphenylmethyl Chloride

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Names

[ CAS No. ]:
76-83-5

[ Name ]:
Triphenylmethyl Chloride

[Synonym ]:
TrCl
MFCD00000813
Chlorotriphenylmethane
[chloro-di(phenyl)methyl]benzene
Benzene, 1,1',1''- (chloromethylidyne)tris-
1,1',1"-(chloromethanetriyl)tribenzene
Triphenylmethyl chloride
4-05-00-02497 (Beilstein Handbook Reference)
trityl chloride
1,1',1''-(Chloromethanetriyl)tribenzene
Benzene, 1,1',1''-(chloromethylidyne)tris-
EINECS 200-986-4
Trt-Cl

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
230-235 ºC (20 mmHg)

[ Melting Point ]:
110-113 ºC

[ Molecular Formula ]:
C19H15Cl

[ Molecular Weight ]:
278.775

[ Flash Point ]:
177.9±12.0 °C

[ Exact Mass ]:
278.086243

[ LogP ]:
5.57

[ Vapour Pressure ]:
0.0±0.8 mmHg at 25°C

[ Index of Refraction ]:
1.608

[ Storage condition ]:
Store under Nitrogen

[ Water Solubility ]:
chloroform: 0.1 g/mL, clear

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
PA6450000
CHEMICAL NAME :
Methane, chlorotriphenyl-
CAS REGISTRY NUMBER :
76-83-5
BEILSTEIN REFERENCE NO. :
0397363
LAST UPDATED :
199709
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C19-H15-Cl

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
180 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) Volume(issue)/page/year: NX#04021

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R14;R34;R50/53

[ Safety Phrases ]:
S26-S36/37/39-S45-S61

[ RIDADR ]:
UN 3261 8/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
PA6450000

[ Packaging Group ]:
III

[ Hazard Class ]:
8

[ HS Code ]:
29036990

Synthetic Route

Precursor & DownStream

Precursor

  • Tritanol
  • Triphenylmethane
  • (chlorosulfanyl-diphenyl-methyl)benzene
  • Azido Tributyltin
  • Carbon tetrachloride
  • benzene
  • Methoxytriphenylmethane
  • triphenylmethane hydrodisulfide
  • 2,3-DIMETHYL-1,3-BUTADIENE
  • phenyl-trityl-diazene

DownStream

  • Tr-PEG2-OH
  • n-tritylhydrazide
  • Tetrakis(4-bromophenyl)methane
  • (5-METHYL-1-TRITYL-1H-IMIDAZOL-4-YL)METHANOL
  • [R-(Z)]-4-Hydroxy-N,N,N-triMethyl-9-oxo-7-[(triphenylmethoxy)Methyl]-3,5,8-trioxa-4-phosphahexacos-17-en-1-aminium 4-Oxide Inner Salt
  • Boc-His(Trt)-OH
  • 1-Trityl-1H-imidazole-4-carbaldehyde
  • Triphenylmethylium tetrafluoroborate
  • H-His(Trt)-OH

Customs

[ HS Code ]: 2903999090

[ Summary ]:
2903999090 halogenated derivatives of aromatic hydrocarbons VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

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To elucidate the comparative susceptibility of newborn rats to chemicals, newborn and young animals were administered six industrial chemicals by gavage from postnatal days (PND) 4 to 21, and for 28 d...


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Related Compounds

  • triphenylmethyl chloride
  • triphenylmethyl chloride
  • triphenyl(trityl)phosphanium,chloride
  • 4-(Dimethylamino)-1-tritylpyridinium chloride
  • triphenylmethyl iodide
  • triphenylmethyl 4-oxopentanoate