Chloro{2,6-bis[(phenylseleno-Se)methyl]phenyl-C}palladium(II)

Names

[ CAS No. ]:
761459-93-2

[ Name ]:
Chloro{2,6-bis[(phenylseleno-Se)methyl]phenyl-C}palladium(II)

Chemical & Physical Properties

[ Melting Point ]:
162-221°C

[ Molecular Formula ]:
C₂₀H₁₉ClPdSe₂

[ Molecular Weight ]:
559.18

[ Storage condition ]:
2-8°C

Safety Information

[ Symbol ]:

GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H301 + H311 + H331-H351

[ Precautionary Statements ]:
P261-P280-P301 + P310-P311

[ Hazard Codes ]:
T

[ Risk Phrases ]:
23/24/25-40

[ Safety Phrases ]:
36/37-45

[ RIDADR ]:
UN 3283 6.1 / PGIII

[ WGK Germany ]:
3

Articles

Petasis Borono-Mannich reaction and allylation of carbonyl compounds via transient allyl boronates generated by palladium-catalyzed substitution of allyl alcohols. an efficient one-pot route to stereodefined alpha-amino acids and homoallyl alcohols.

J. Am. Chem. Soc. 129 , 13723 - 13731, (2007)

An efficient one-pot procedure was designed by integration of the pincer-complex-catalyzed borylation of allyl alcohols in the Petasis borono-Mannich reaction and in allylation of aldehydes and ketone...