perchloryl fluoride

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Names

[ CAS No. ]:
7616-94-6

[ Name ]:
perchloryl fluoride

[Synonym ]:
Chlorine oxyfluoride
TRIOXYCHLOROFLUORIDE
perchlorylfluoride
Chloryl (per-)fluoride
Chlorine fluoride oxide (ClO3F)
EINECS 231-526-0
Perchloryl fluoride ((ClO3)F)
Chlorine fluoride oxide
UN3083

Chemical & Physical Properties

[ Density]:
1.434

[ Boiling Point ]:
-46.8ºC

[ Melting Point ]:
-146ºC

[ Molecular Formula ]:
ClFO3

[ Molecular Weight ]:
102.45000

[ Exact Mass ]:
101.95200

[ PSA ]:
51.21000

[ LogP ]:
0.75330

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
SD1925000
CHEMICAL NAME :
Perchloryl fluoride
CAS REGISTRY NUMBER :
7616-94-6
LAST UPDATED :
199712
DATA ITEMS CITED :
24
MOLECULAR FORMULA :
Cl-F-O3
MOLECULAR WEIGHT :
102.45
WISWESSER LINE NOTATION :
O3 F G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
385 ppm/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PENNS* Pennsalt Chemicals Corp., Technical Div., New Products. (Philadelphia, PA)
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
630 ppm/4H
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PENNS* Pennsalt Chemicals Corp., Technical Div., New Products. (Philadelphia, PA)
TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Mammal - dog
DOSE/DURATION :
451 ppm/4H
REFERENCE :
XAWPA2 U.S. Army Chemical Warfare Laboratories. (Army Chemical Center, MD) Volume(issue)/page/year: CWL 2-10,1958 *** REVIEWS *** ACGIH TLV-STEL 25 mg/m3 (6 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-TWA 13 mg/m3 (3 ppm) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 3 ppm (14 mg/m3) DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,202,1971 OSHA PEL (Gen Indu):8H TWA 3 ppm (13.5 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 3 ppm (13.5 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 3 ppm (13.5 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 3 ppm (13.5 mg/m3) CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 3 ppm (14 mg/m3);STEL 6 ppm (28 mg/m3) JAN 1993 OEL-BELGIUM:TWA 3 ppm (13 mg/m3);STEL 6 ppm (25 mg/m3) JAN 1993 OEL-DENMARK:TWA 2 mg/m3 JAN 1993 OEL-DENMARK:TWA 3 ppm (14 mg/m3) JAN 1993 OEL-FINLAND:TWA 3 ppm (14 mg/m3);STEL 6 ppm (25 mg/m3) JAN 1993 OEL-FRANCE:TWA 3 ppm (14 mg/m3) JAN 1993 OEL-THE NETHERLANDS:TWA 3 ppm (14 mg/m3) JAN 1993 OEL-THE PHILIPPINES:TWA 3 ppm (10.5 mg/m3) JAN 1993 OEL-SWITZERLAND:TWA 3 ppm (13 mg/m3) JAN 1993 OEL-UNITED KINGDOM:TWA 3 ppm (14 mg/m3);STEL 6 ppm (28 mg/m3) JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO PERCHLORYL FLUORIDE-air:10H TWA 3 ppm;STEL 6 ppm REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

Safety Information

[ RIDADR ]:
UN 3157

[ Hazard Class ]:
2.2

Synthetic Route

Precursor & DownStream

Precursor

  • PERCHLORIC ACID
  • Antimony pentafluoride
  • Fluorine
  • Potassium chlorate
  • Chloryl fluoride
  • Fluorosulfuric acid
  • Dihyperchloric anhydride

DownStream

  • Aluminum fluoride
  • Chlorine
  • HYDROXYLAMINE NITRATE
  • hydroxylammonium fluoride
  • hydroxylammonium chlorate
  • Chlorosyl
  • chloro-fluoro-dinitromethane
  • Difluorodinitromethane
  • Fluorotrinitromethane
  • 2-(3-fluoro-2,6-dioxopiperidin-3-yl)isoindole-1,3-dione

Related Compounds

  • perchloryl hypofluorite
  • perchloryl-benzene
  • perchloryl nitrite
  • perchloryl ethaneperoxoate
  • Chromium fluoride
  • cinnamyl fluoride