[2-(Chloromethoxy)ethyl](trimethyl)silane

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Names

[ CAS No. ]:
76513-69-4

[ Name ]:
[2-(Chloromethoxy)ethyl](trimethyl)silane

[Synonym ]:
EINECS 278-483-4
2-(chloromethoxy)ethyl-trimethylsilane
Silane, [2-(chloromethoxy)ethyl]trimethyl-
MFCD00009919
[2-(Chloromethoxy)ethyl](trimethyl)silane
SEMCl
2-(Trimethylsilyl)ethoxymethylchloride

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
182.1±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C6H15ClOSi

[ Molecular Weight ]:
166.721

[ Flash Point ]:
46.7±0.0 °C

[ Exact Mass ]:
166.058075

[ PSA ]:
9.23000

[ LogP ]:
2.23

[ Vapour Pressure ]:
1.1±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.413

[ Storage condition ]:
−20°C

[ Water Solubility ]:
decomposes

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H226-H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R10;R34

[ Safety Phrases ]:
S26-S28-S36/37/39-S45-S16

[ RIDADR ]:
UN 2920 8/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3.2

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Formaldehyde
  • 2-(Trimethylsilyl)ethanol

DownStream

  • 1-(2-trimethylsilylethoxymethyl)imidazole-2-carbonitrile
  • 5-methyl-6-phenylsulfanyl-1-(2-trimethylsilylethoxymethyl)pyrimidine-2,4-dione
  • INCB032304
  • 4-chloro-7-((2-(trimethylsilyl)ethoxy)methyl)-7H-pyrrolo[2,3-d]pyrimidine
  • 2-[(6-chloropurin-9-yl)methoxy]ethyl-trimethylsilane
  • Dimethylprotoporphyrin IX dimethyl ester
  • Ethyl 4-methoxy-1-{[2-(trimethylsilyl)ethoxy]methyl}-1H-pyrrolo[2 ,3-b]pyridine-2-carboxylate
  • 2-(trimethylsilyl)ethoxymethyltriphenylphosphonium chloride
  • 1-((2-(Trimethylsilyl)Ethoxy)Methyl)-1H-Pyrazole

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Biomimetically inspired total synthesis and structure activity relationships of 1-O-methyllateriflorone. 6 pi electrocyclizations in organic synthesis.

J. Am. Chem. Soc. 126 , 5493-5501, (2004)

The total synthesis of 1-O-methyllateriflorone (2) is described. The construction of the cage-like domain of the molecule involved a biomimetic Claisen/Diels-Alder cascade, whereas the novel spiroxala...

Tetrahedron Lett. 47 , 5909, (2006)

Tetrahedron Lett. 36 , 1683, (1995)


More Articles

Related Compounds

  • 2-(Chloromethoxy)ethyl acetate
  • 2-Ethyl-1-trimethylsilyloxyhexene
  • [2-(4-chloro-3-fluorophenoxy)ethyl]trimethyl-silane
  • {2-[2,5-Dimethoxy-4-((R)-1-phenyl-allyl)-phenoxy]-ethyl}-trimethyl-silane
  • [2-(8-Benzenesulfonyl-1,4-dioxa-spiro[4.5]dec-9-en-7-yl)-ethyl]-trimethyl-silane
  • [2-(8-Benzenesulfonyl-1,4-dioxa-spiro[4.5]dec-8-en-7-yl)-ethyl]-trimethyl-silane
  • Methyl 3-hydroxy-3-(2-hydroxy-4,5-dimethylphenyl)propanoate
  • 2-Azido-4-(3-fluorophenoxy)butan-1-ol
  • Tert-butyl 3-(3-methoxy-2-methylphenyl)piperazine-1-carboxylate
  • 2-[2-(3-Fluorophenoxy)ethyl]-2-methyloxirane
  • (2R)-2-(2-methoxy-5-nitrophenyl)oxirane
  • (1-ethyl-3,4-dihydro-2H-quinolin-8-yl)boronic acid
  • (9H-fluoren-9-yl)methyl 4-{3-amino-5-[(tert-butoxy)carbonyl]phenyl}piperazine-1-carboxylate
  • N-(2,3,4,5-tetrahydro-1-benzoxepin-4-yl)but-2-ynamide
  • 3-Formyl-5-[2-(trimethylsilyl)ethynyl]benzoic acid
  • N-(2,6-dimethylpyridin-3-yl)-N-(3-methoxy-2,2-dimethylpropyl)prop-2-enamide
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