cis-2,6-Dimethylpiperidine

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Names

[ CAS No. ]:
766-17-6

[ Name ]:
cis-2,6-Dimethylpiperidine

[Synonym ]:
(2S,6R)-2,6-dimethylpiperidine
(cis)-2,6-dimethylpiperidine
2,6-cis-dimethylpiperidine
4-Piperidinone,2,6-dimethyl-,cis
cis-2,6-dimethyl-piperidin-4-one
Piperidine, 2,6-dimethyl-, (2R,6S)-
cis-2,6-dimethylpiperidinone
2,6-cis-2,6-dimethylpiperidine
(2R,6S)-2,6-Dimethylpiperidine
cis-2,6-dimethyl-4-piperidone
MFCD00066304
EINECS 207-981-6

Chemical & Physical Properties

[ Density]:
0.8±0.1 g/cm3

[ Boiling Point ]:
127.1±0.0 °C at 760 mmHg

[ Melting Point ]:
-20ºC

[ Molecular Formula ]:
C7H15N

[ Molecular Weight ]:
113.201

[ Flash Point ]:
11.7±0.0 °C

[ Exact Mass ]:
113.120445

[ PSA ]:
12.03000

[ LogP ]:
1.92

[ Vapour Pressure ]:
11.3±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.417

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H315-H319-H335

[ Precautionary Statements ]:
P210-P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable;Xi:Irritant;

[ Risk Phrases ]:
R11;R36/37/38

[ Safety Phrases ]:
S16-S26

[ RIDADR ]:
UN 1993

[ WGK Germany ]:
3

[ RTECS ]:
OK5775000

[ Packaging Group ]:
II

[ Hazard Class ]:
3.1

[ HS Code ]:
2933399090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 2,6-lutidine
  • cis-2,6-Dimethylpiperidin-5-one
  • 2,6-Dimethylpyridin-4-amine
  • 1,2β,6β-Trimethylpiperidine
  • acetic acid
  • Diisopropylamine
  • Diphenylmethane

DownStream

  • 2,6-dimethyl-1-oxido-2,3,4,5-tetrahydropyridin-1-ium
  • Diisopropylamine
  • cis-1-Amino-2,6-dimethylpiperidine
  • Diphenylmethane
  • 2,6-dimethylpiperidine-1-carboximidamide
  • (2R,6S)-2,6-dimethyl-1-nitrosopiperidine
  • 2,6-bis[4-(2,6-dimethylpiperidin-1-yl)but-2-ynyl]pyrrolo[3,4-f]isoindole-1,3,5,7-tetrone
  • 3-(2,6-dimethylpiperidin-1-yl)propanehydrazide
  • 1-ethyl-2,6-dimethylpiperidine

Customs

[ HS Code ]: 2933399090

[ Summary ]:
2933399090. other compounds containing an unfused pyridine ring (whether or not hydrogenated) in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

cis-2,6-Dimethylpiperidide: a structural mimic for TMP (2,2,6,6-tetramethylpiperidide) or DA (diisopropylamide)?

Dalton Trans. (2) , 511-9, (2010)

Four novel heterobimetallic ate complexes containing cis-2,6-dimethylpiperidide (cis-DMP) have been prepared and characterised. Two contain one cis-DMP ligand, namely the bisalkyl-amido lithium, and s...

High Catalytic Activity of Chiral Amino Alcohol Ligands Anchored to Polystyrene Resins.

J. Org. Chem. 63(18) , 6309-6318, (1998)

Enantiomerically pure (2S,3S)-2,3-epoxy-3-phenylpropanol (3) has been anchored to Merrifield resins with different degrees of cross-linking and functionalization. The resulting epoxy-functionalized re...

Proton magnetic resonance studies of cyclic compounds-VI: Cis-and trans-2, 6-dimethylpiperidine and cis (2, 4), cis (4, 6), cis (2, 6)-2, 4, 6-trimethylpiperidine. Booth HJ< et al.

Tetrahedron 24(1) , 279-87, (1968)


More Articles

Related Compounds

  • 1-AMINO-CIS-2,6-DIMETHYLPIPERIDINE
  • 1-benzyl-cis-2,6-dimethylpiperidine
  • 1-benzyl-cis-2,6-dimethylpiperidine
  • cis-2,6-dimethylpiperidine-1-carboxaldehyde
  • cis-2,6-dimethylpiperidine-2,6-dicarboxylic acid dimethyl ester-1-oxyl radical
  • cis-2,6-dimethyl-4-({4-[(E)-2-(tetramethyl-1,3,2-dioxaborolan-2-yl)ethenyl]phenyl}methyl)morpholine
  • tert-butyl N-[2-chloro-6-(propan-2-yl)pyridin-3-yl]carbamate
  • (1RS,2SR,4RS&,5SR&)-4,5-dihydroxy-2-(2,2,2-trifluoroacetamido)cyclohexane-1-carboxylic acid
  • 3,3-Dimethoxy-1-(2,2,2-trifluoroacetamido)cyclobutane-1-carboxylic acid
  • benzyl N-(3-hydroxyphenyl)-N-(propan-2-yl)carbamate
  • 4,5-Dimethyl-2-{[(prop-2-en-1-yloxy)carbonyl]amino}benzoic acid
  • 2,4-Dimethyl-5-{[(prop-2-en-1-yloxy)carbonyl]amino}benzoic acid
  • 2,4-Dimethyl-6-{[(prop-2-en-1-yloxy)carbonyl]amino}benzoic acid
  • 3,5-Dimethyl-2-{[(prop-2-en-1-yloxy)carbonyl]amino}benzoic acid
  • tert-butyl N-(3-cyano-4-methoxypyridin-2-yl)carbamate
  • 2-(1-Acetylpiperidin-4-yl)pyrimidine-5-carboxylic acid
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