3-Iodoanisole

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Names

[ CAS No. ]:
766-85-8

[ Name ]:
3-Iodoanisole

[Synonym ]:
m-MeOC6H4-I
Benzene,1-iodo-3-methoxy
Anisole,m-iodo
Benzene, 1-iodo-3-methoxy-
3-Iodoanisole
m-Methoxyiodobenzene
3-Methoxyiodobenzene
1-Iodo-3-methoxybenzene
MFCD00001048
3-MeO-C6H4-I
3-Methoxyphenyl iodide
1-methoxy-3-iodobenzene
3-Iodophenyl methyl ether
m-Iodoanisole
EINECS 212-173-1

Chemical & Physical Properties

[ Density]:
1.7±0.1 g/cm3

[ Boiling Point ]:
245.2±13.0 °C at 760 mmHg

[ Molecular Formula ]:
C7H7IO

[ Molecular Weight ]:
234.034

[ Flash Point ]:
102.1±19.8 °C

[ Exact Mass ]:
233.954147

[ PSA ]:
9.23000

[ LogP ]:
2.95

[ Vapour Pressure ]:
0.0±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.592

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H319

[ Precautionary Statements ]:
P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R22;R36

[ Safety Phrases ]:
S26-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2909309090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4-Boronoanisole
  • 3-anisidine
  • 2-Bromotoluene
  • m-Bromoanisole
  • 3-methoxyphenyliodonium-(5-[2,2-dimethyl-1,3-dioxane-4,6-dione])ylide
  • (3-methoxyphenyl)(triphenyl-λ5-phosphanyl)gold
  • Anisole
  • 4-Methoxy-2-nitrobenzoic acid
  • m-nitroanisole
  • 3-Nitrophenol

DownStream

  • 3-methoxy-N,N-bis(3-methoxyphenyl)aniline
  • 4-(3-Methoxyphenyl)-1-butanol
  • 3-METHOXYPHENYLBORONIC ACID PINACOL ESTER
  • 1-Bromo-2-iodo-4-methoxybenzene
  • 3-(Trifluoromethyl)anisole
  • 1,2-BIS(3-METHOXYPHENYL)ETHANE-1,2-DIONE
  • Ethyl benzoate
  • Diethyl 4,4'-biphenyldicarboxylate
  • 1,1'-Biphenyl, 3,3'-dimethoxy-
  • ethyl 4-(3-methoxyphenyl)benzoate

Customs

[ HS Code ]: 2909309090

[ Summary ]:
2909309090 other aromatic ethers and their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:5.5% General tariff:30.0%

Articles

After-effects of lithium-mediated alumination of 3-iodoanisole: isolation of molecular salt elimination and trapped-benzyne products.

Dalton Trans. 41(6) , 1832-9, (2012)

Gaining a deeper understanding of the modus operandi of heterometallic lithium aluminate bases towards deprotonative metallation of substituted aromatic substrates, we have studied the reactions and t...


More Articles

Related Compounds

  • 3-iodoanisole
  • 4-Bromo-3-iodoanisole
  • 4-Nitro-3-iodoanisole
  • 4-amino-3-iodoanisole
  • 2-Bromo-3-iodoanisole
  • 4-chloro-3-iodoanisole
  • benzyl N-[(2-methylidenecyclopropyl)methyl]carbamate
  • benzyl N-[1-(oxolan-3-yl)prop-2-yn-1-yl]carbamate
  • benzyl N-[3-(hydroxymethyl)bicyclo[2.2.1]heptan-2-yl]carbamate
  • Tert-butyl 2-(fluoromethyl)-1,4-oxazepane-4-carboxylate
  • benzyl N-[3-(fluorosulfonyl)propyl]-N-methylcarbamate
  • Tert-butyl 3-(2-hydroxyethyl)-3-(trifluoroacetamido)azetidine-1-carboxylate
  • benzyl N-[3-hydroxy-2-(methoxymethyl)-2-methylpropyl]carbamate
  • rac-(3R,3aR,6aR)-5-(trifluoroacetyl)-hexahydro-2H-furo[2,3-c]pyrrole-3-carboxylic acid
  • 4-Methyl-5-oxo-1-(trifluoroacetyl)piperazine-2-carboxylic acid
  • 2-[2-Oxo-4-(trifluoroacetyl)piperazin-1-yl]acetic acid
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