Trimethylsilyl cyanide

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Names

[ CAS No. ]:
7677-24-9

[ Name ]:
Trimethylsilyl cyanide

[Synonym ]:
Trimethylsilyl cyanide
trimethylsilylformonitrile
EINECS 231-657-3
Silanecarbonitrile, 1,1,1-trimethyl-
Trimethylsilanecarbonitrile
MFCD00001765
Silanecarbonitrile, trimethyl-
TRIMETHYLSILYLCYANIDE

Chemical & Physical Properties

[ Density]:
0.8±0.1 g/cm3

[ Boiling Point ]:
118.5±0.0 °C at 760 mmHg

[ Melting Point ]:
8-11 °C(lit.)

[ Molecular Formula ]:
C4H9NSi

[ Molecular Weight ]:
99.206

[ Flash Point ]:
1.1±0.0 °C

[ Exact Mass ]:
99.050423

[ PSA ]:
23.79000

[ LogP ]:
1.00

[ Vapour Pressure ]:
16.6±0.2 mmHg at 25°C

[ Index of Refraction ]:
1.388

[ Storage condition ]:
0-6°C

[ Water Solubility ]:
reacts

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS06

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H300 + H310 + H330

[ Supplemental HS ]:
Contact with water liberates toxic gas.

[ Precautionary Statements ]:
P210-P260-P264-P280-P284-P301 + P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F:Flammable

[ Risk Phrases ]:
R11;R26/27/28;R29;R50/53

[ Safety Phrases ]:
S16-S36/37/39-S45-S61-S28A-S26

[ RIDADR ]:
UN 3384 6.1/PG 1

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
6.1

[ HS Code ]:
29310095

Precursor & DownStream

Precursor

  • Chlorotrimethylsilane
  • POTASSIUM CYANIDE
  • Sodium cyanide
  • Bis(trimethylsilyl) sulfate
  • benzyl thiocyanate
  • (Trifluoromethyl)trimethylsilane
  • Thiocyanic acid, octylester
  • Phenyl thiocyanate
  • Benzyl selenocyanate
  • phenylselenocyanate

DownStream

  • 3-hydroxy-1-[(2-methylpropan-2-yl)oxycarbonyl]pyrrolidine-3-carboxylic acid
  • 2-methyl-2-trimethylsilyloxyheptanenitrile
  • (2-Bromo-4-methylphenyl)acetonitrile
  • (R)-2-HYDROXY-2-CYCLOHEXYLACETONITRILE
  • 3,6-dihydro-2h-pyran-4-carbonitrile
  • 2-(cyclohexylamino)acetonitrile
  • phenylselenocyanate
  • Diphenyldiselenide
  • Cyclohexanecarbonitrile,1-(methylamino)-

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Asymmetric activation of tropos 2,2'-biphenol with cinchonine generates an effective catalyst for the asymmetric strecker reaction of N-tosyl-protected aldimines and ketoimines.

Angew. Chem. Int. Ed. Engl. 46(44) , 8468-70, (2007)

A chemoselective Ugi-type reaction in water using TMSCN as a functional isonitrile equivalent: generation of heteroaromatic molecular diversity.

Org. Biomol. Chem. 10(46) , 9271-7, (2012)

KF-mediated nucleophilic activation of TMSCN as a functional isonitrile equivalent establishes an efficient and chemoselective Ugi-type multicomponent reaction of a heterocyclic amidine and aldehyde w...

Sc₂(pydc)₂ unit based 1D, 2D and 3D metal-organic frameworks as heterogeneous Lewis acid catalysts for cyanosilylation.

Dalton Trans. 44(4) , 1942-7, (2014)

Three scandium metal-organic frameworks (Sc-MOFs), [Sc(pydc)(Hpydc)(H2O)]·H2O (1), [Sc2(pydc)3(H2O)4]·5H2O (2) and [Sc(pydc)(H2O)(NO3)] (3) with similar Sc2(pydc)2 building unit were prepared by using...


More Articles

Related Compounds

  • trimethylsilyl cyanide
  • Trimethylsilyl cyanide-13C,15N
  • Trimethylsilyl propiolate
  • trimethylsilyl methyl(3-trimethylsiloxy-3,3-dicyanopropyl)phosphinate
  • trimethylsilyl N-(2-methylphenyl)carbamate
  • Trimethylsilyl 2-iodoethyl ether
  • 2-(Methyl(pyrimidin-2-yl)amino)cyclopentan-1-ol
  • Ethyl 2-(1-(benzo[d]oxazol-2-yl)pyrrolidine-2-carboxamido)-4-methylthiazole-5-carboxylate
  • 4-(thiazol-2-yloxy)-N-(thiazolo[3,2-b][1,2,4]triazol-6-ylmethyl)benzamide
  • 4-methoxy-1-methyl-5-(pyrrolidine-1-carbonyl)pyridin-2(1H)-one
  • (4-((1H-imidazol-1-yl)methyl)phenyl)(3-(quinoxalin-2-yloxy)pyrrolidin-1-yl)methanone
  • 2-({1-[3-(Trifluoromethoxy)benzoyl]pyrrolidin-3-yl}oxy)quinoxaline
  • (3-(2H-1,2,3-triazol-2-yl)azetidin-1-yl)(cyclopropyl)methanone
  • 2-[1-(thiophene-3-carbonyl)azetidin-3-yl]-2H-1,2,3-triazole
  • (3-(2H-1,2,3-triazol-2-yl)azetidin-1-yl)(benzofuran-2-yl)methanone
  • 2-[1-(2H-1,3-benzodioxole-5-carbonyl)azetidin-3-yl]-2H-1,2,3-triazole
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