Trimethylsilyl cyanide
Suppliers
Names
[ CAS No. ]:
7677-24-9
[ Name ]:
Trimethylsilyl cyanide
[Synonym ]:
Trimethylsilyl cyanide
trimethylsilylformonitrile
EINECS 231-657-3
Silanecarbonitrile, 1,1,1-trimethyl-
Trimethylsilanecarbonitrile
MFCD00001765
Silanecarbonitrile, trimethyl-
TRIMETHYLSILYLCYANIDE
Chemical & Physical Properties
[ Density]:
0.8±0.1 g/cm3
[ Boiling Point ]:
118.5±0.0 °C at 760 mmHg
[ Melting Point ]:
8-11 °C(lit.)
[ Molecular Formula ]:
C4H9NSi
[ Molecular Weight ]:
99.206
[ Flash Point ]:
1.1±0.0 °C
[ Exact Mass ]:
99.050423
[ PSA ]:
23.79000
[ LogP ]:
1.00
[ Vapour Pressure ]:
16.6±0.2 mmHg at 25°C
[ Index of Refraction ]:
1.388
[ Storage condition ]:
0-6°C
[ Water Solubility ]:
reacts
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS06
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H225-H300 + H310 + H330
[ Supplemental HS ]:
Contact with water liberates toxic gas.
[ Precautionary Statements ]:
P210-P260-P264-P280-P284-P301 + P310
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter
[ Hazard Codes ]:
F:Flammable
[ Risk Phrases ]:
R11;R26/27/28;R29;R50/53
[ Safety Phrases ]:
S16-S36/37/39-S45-S61-S28A-S26
[ RIDADR ]:
UN 3384 6.1/PG 1
[ WGK Germany ]:
3
[ Packaging Group ]:
II
[ Hazard Class ]:
6.1
[ HS Code ]:
29310095
Precursor & DownStream
Precursor
DownStream
Customs
[ HS Code ]: 2931900090
[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%
Articles
Angew. Chem. Int. Ed. Engl. 46(44) , 8468-70, (2007)
Org. Biomol. Chem. 10(46) , 9271-7, (2012)
KF-mediated nucleophilic activation of TMSCN as a functional isonitrile equivalent establishes an efficient and chemoselective Ugi-type multicomponent reaction of a heterocyclic amidine and aldehyde w...
Dalton Trans. 44(4) , 1942-7, (2014)
Three scandium metal-organic frameworks (Sc-MOFs), [Sc(pydc)(Hpydc)(H2O)]·H2O (1), [Sc2(pydc)3(H2O)4]·5H2O (2) and [Sc(pydc)(H2O)(NO3)] (3) with similar Sc2(pydc)2 building unit were prepared by using...