Chlorodimethylphenylsilane

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Names

[ CAS No. ]:
768-33-2

[ Name ]:
Chlorodimethylphenylsilane

[Synonym ]:
chloro-dimethyl-phenylsilane
EINECS 212-193-0
Benzene, (chlorodimethylsilyl)-
Chloro(dimethyl)phenylsilane
MFCD00000499
Chlorodimethylphenylsilane
Phenyl dimethylchlorosilane
Silane, chlorodimethylphenyl-

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
196.0±9.0 °C at 760 mmHg

[ Melting Point ]:
<0ºC

[ Molecular Formula ]:
C₈H₁₁ClSi

[ Molecular Weight ]:
170.711

[ Flash Point ]:
61.7±0.0 °C

[ Exact Mass ]:
170.031860

[ LogP ]:
3.93

[ Vapour Pressure ]:
0.6±0.4 mmHg at 25°C

[ Index of Refraction ]:
1.495

[ Water Solubility ]:
MAY DECOMPOSE

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS05

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H314

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive;

[ Risk Phrases ]:
R34

[ Safety Phrases ]:
S26-S36/37/39-S45

[ RIDADR ]:
UN 2987 8/PG 2

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Dimethylphenylsilane
Bromobenzene
Dichlorodimethylsilane
ALLYL CHLORIDE
Ethoxy(dimethyl)phenylsilane
1,1,2,2-Tetramethyl-1,2-diphenyldisilane
dimethyl-phenyl-(trimethylgermyl)-Silane
1,2-dichloro-tetramethyldisilane
Benzoyl chloride
(E)-1-dimethyl(phenyl)silyl-4-phenylbut-1-ene

DownStream

1,1,2,2-Tetramethyl-1,2-diphenyldisilane
bis[[dimethyl(phenyl)silyl]-dimethylsilyl]-dimethylsilane
rac-4-phenyloctan-2-one
4-[dimethyl(phenyl)silyl]-4-phenylbutan-2-one
Dimethylphenylfluorosilane
1,3-Diphenyltetramethyldisilazane
Methylbenzylalcohol
(1-but-1-ynylcyclohexa-2,4-dien-1-yl)-dimethylsilane
(4-methoxyphenyl)-dimethyl-phenylsilane
ethynyl-dimethyl-phenylsilane

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

Preparation and use of enantioenriched allenylsilanes for the stereoselective synthesis of homopropargylic ethers.

Org. Lett. 9 , 2689, (2007)

A convenient procedure for the synthesis of highly enantioenriched allenylsilanes by Johnson orthoester Claisen rearrangement of 1-silyl propargylic alcohols is described. Allenylsilanes are then used...

[Preparation of phenyl treated packing materials for high-performance liquid chromatography: evaluation by retention behaviour of carbamazepine and diphenylhydantoin].

Yakugaku Zasshi 112(6) , 409-13, (1992)

The retention behavior and selectivity of 30 kinds of phenyl-modified porous glasses and silicas, prepared from solutions of phenyldimethylchlorosilane, diphenylmethylchlorosilane or triphenylchlorosi...