1-Bromoadamantane

Suppliers

Names

[ CAS No. ]:
768-90-1

[ Name ]:
1-Bromoadamantane

[Synonym ]:
1-Bromtricyclo[3.3.1.1]decan
Tricyclo[3.3.1.1]decane, 1-bromo-
EINECS 212-200-7
1-bromoadmantance
1-Bromoadamantane
Adamantane, 1-bromo-
11-BROMOADAMANTANE
1-ADAMANTYL BROMIDE
MFCD00074721
Adamantane,1-bromo
3-Bromoadamantane
1-BroMoadaMantan
adamantyl bromide
RARECHEM AQ TC 1019

Chemical & Physical Properties

[ Density]:
1.4±0.1 g/cm3

[ Boiling Point ]:
240.5±9.0 °C at 760 mmHg

[ Melting Point ]:
116-118 °C(lit.)

[ Molecular Formula ]:
C₁₀H₁₅Br

[ Molecular Weight ]:
215.13

[ Flash Point ]:
96.4±8.4 °C

[ Exact Mass ]:
214.035706

[ LogP ]:
4.03

[ Vapour Pressure ]:
0.1±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.587

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xn: Harmful;

[ Risk Phrases ]:
R20/21/22

[ Safety Phrases ]:
S22-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
29035990

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Adamantan-1-ol
1-Chloroadamantane
Adamantane
1-Fluoroadamantane
adamantanecarbonyl chloride
N.N-Dibrom-1-adamantanamin
4-(1-adamantyl)benzene-1,3-diol
6-(hydroxymethyl)tridecan-7-yl heptanoate
N-Chlor-N-aethyl-1-adamantanamin
Tetrabutylammonium bromide

DownStream

2-(1-Adamantyl)-4-methylphenol
1-Adamantanethiol
4-Methoxyquinoline
7-(1-Adamantyl)-7,8-dihydro-4-methoxychinolin
6-(1-Adamantyl)-5,6-dihydro-4-methoxychinolin
2-(1-Adamantyl)-4-methoxychinolin
1-Adamantyl isocyanate
N-Methyl-1-adamantanamine
1-Bromo-3,5,7-Trimethyladamantane

Customs

[ HS Code ]: 2903890090

[ Summary ]:
2903890090. halogenated derivatives of cyclanic, cyclenic or cyclotherpenic hydrocarbons. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Experimental (NMR) and Computational (MD) Studies on the Inclusion Complexes of 1-Bromoadamantane with alpha-, beta-, and gamma-Cyclodextrin.

J. Org. Chem. 61(20) , 7012-7017, (1996)

The inclusion complexes between the most commonly used cyclodextrins (alpha-, beta-, and gamma-CD) and 1-bromoadamantane were prepared and studied experimentally by NMR methods and by molecular dynami...

Thin-film composite materials as a dielectric layer for flexible metal-insulator-metal capacitors.

ChemSusChem 3(9) , 1051-6, (2010)

A new organic-organic nanoscale composite thin-film (NCTF) dielectric has been synthesized by solution deposition of 1-bromoadamantane and triblock copolymer (Pluronic P123, BASF, EO20-PO70-EO20), in ...

Alkylation of ß-diketones through their co (II), co (III) and zn (II) complexes. 1-Bromoadamantane as alkylating agent. Gonzalez A, et al.

Tetrahedron Lett. 26(31) , 3735-3738, (1985)