Adamantan-1-ol

Suppliers

Names

[ CAS No. ]:
768-95-6

[ Name ]:
Adamantan-1-ol

[Synonym ]:
MFCD00074729
Tricyclo[3.3.1.1(3,7)]decan-1-ol
1-Hydroxyadamantane
Tricyclo[3.3.1.1]decan-1-ol
adamantanol
1-adamantyl alcohol
adamantan-1-ol
1-Adamantol
adamantyl alcohol
EINECS 212-202-8
1-Adamantanol
adamantanemonool
hydroxyadamantane

Chemical & Physical Properties

[ Density]:
1.2±0.1 g/cm3

[ Boiling Point ]:
245.8±8.0 °C at 760 mmHg

[ Melting Point ]:
247 °C (subl.)(lit.)

[ Molecular Formula ]:
C₁₀H₁₆O

[ Molecular Weight ]:
152.233

[ Flash Point ]:
101.1±10.9 °C

[ Exact Mass ]:
152.120117

[ PSA ]:
20.23000

[ LogP ]:
2.16

[ Vapour Pressure ]:
0.0±1.1 mmHg at 25°C

[ Index of Refraction ]:
1.581

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: AU4980000

CHEMICAL NAME :: 1-Adamantanol

CAS REGISTRY NUMBER :: 768-95-6

LAST UPDATED :: 198201

DATA ITEMS CITED :: 1

MOLECULAR FORMULA :: C10-H16-O

MOLECULAR WEIGHT :: 152.26

WISWESSER LINE NOTATION :: L66 B6/B-H/DI A B- C 1B ITJ BQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 600 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: PCJOAU Pharmaceutical Chemistry Journal (English Translation). Translation of KHFZAN. (Plenum Pub. Corp., 233 Spring St., New York, NY 10013) No.1- 1967- Volume(issue)/page/year: 10,454,1976

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Hazard Codes ]:
Xi

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S22-S24/25

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
AU4980000

[ HS Code ]:
29061900

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

1-(2-propenyloxy)tricyclo[3.3.1.13,7]decane
trimethyl(tricyclo[3.3.1.13,7]dec-1-yloxy)silane
Adamantane
1-(trifluoroacetoxy)adamantane
trifluoroacetic acid
1-adamantyl p-toluate
1-adamantyl benzyl ether
carbon monoxide
acetic acid
butane-2,3-dione

DownStream

2-(1-Adamantyl)-4-methylphenol
1-Adamantanethiol
1-Adamantyl isocyanate
N-(1-adamantyl)-2-chloroacetamide
1-Isothiocyanatoadamantane
1-adamantyl thiocyanate
adamantaneacetic acid
3-(1-adamantyl)propan-1-ol
3-Hydroxyadamantane-1-acetic acid
1-Adamantanemethylamine

Customs

[ HS Code ]: 2906199090

[ Summary ]:
2906199090. cyclanic, cyclenic or cyclotherpenic alcohols. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:5.5%. General tariff:30.0%

Articles

Bioconversion of 1-adamantanol to 1,3-adamantanediol usingStreptomycessp. SA8 oxidation system

J. Biosci. Bioeng. 109(6) , 550-3, (2010)

To efficiently produce 1,3-adamantanediol (1,3-ad(OH) 2) from 1-adamantanol (1-adOH), our stocks of culture strains and soil microorganisms were surveyed for hydroxylation activity towards 1-adOH. Amo...

Syntheses, characterization, and catalytic ability in alkane oxygenation of chloro(dimethyl sulfoxide)ruthenium(II) complexes with tris(2-pyridylmethyl)amine and its derivatives.

Inorg. Chem. 45(20) , 8342-54, (2006)

New ruthenium(II) complexes having a tetradentate ligand such as tris(2-pyridylmethyl)amine (TPA), tris[2-(5-methoxycarbonyl)pyridylmethyl]amine [5-(MeOCO)3-TPA], tris(2-quinolylmethyl)amine (TQA), or...