Zinc bromide

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Names

[ CAS No. ]:
7699-45-8

[ Name ]:
Zinc bromide

[Synonym ]:
MFCD00011294
Zinc dibromide
EINECS 231-718-4

Chemical & Physical Properties

[ Density]:
4.22

[ Boiling Point ]:
697ºC

[ Melting Point ]:
394ºC

[ Molecular Formula ]:
Br2Zn

[ Molecular Weight ]:
225.217

[ Flash Point ]:
650°C

[ Exact Mass ]:
221.765808

[ LogP ]:
1.68870

[ Index of Refraction ]:
1.5452

[ Storage condition ]:
APPROX >0°C

[ Stability ]:
Stable. Forms explosive mixtures with sodium and potassium. Protect from moisture.

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
ZH1150000
CHEMICAL NAME :
Zinc bromide
CAS REGISTRY NUMBER :
7699-45-8
LAST UPDATED :
199701
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
Br2-Zn
MOLECULAR WEIGHT :
225.19
WISWESSER LINE NOTATION :
.ZN..E2

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

MUTATION DATA

TYPE OF TEST :
Cytogenetic analysis
TEST SYSTEM :
Rodent - rat Ascites tumor
DOSE/DURATION :
800 mg/kg
REFERENCE :
GANNA2 Gann. Japanese Journal of Cancer Research. (Tokyo, Japan) V.1-75, 1907-84. For publisher information, see JJCREP. Volume(issue)/page/year: 54,155,1963 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83367 No. of Facilities: 22 (estimated) No. of Industries: 2 No. of Occupations: 1 No. of Employees: 68 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83367 No. of Facilities: 221 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 442 (estimated) No. of Female Employees: 221 (estimated)

Safety Information

[ Symbol ]:

GHS05, GHS07, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H314-H317-H411

[ Precautionary Statements ]:
P273-P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R34;R50

[ Safety Phrases ]:
S26-S29-S36/37/39-S45-S61

[ RIDADR ]:
UN 3260

[ WGK Germany ]:
3

[ RTECS ]:
ZH1150000

[ Packaging Group ]:
II

[ Hazard Class ]:
8

Articles

Asymmetric Rh-catalyzed intermolecular hydroacylation of 1,5-hexadiene with salicylaldehyde.

Chem. Pharm. Bull. 57(10) , 1158-60, (2009)

Asymmetric intermolecular hydroacylation between salicylaldehyde (1) and 1,5-hexadiene (2) using a combination of [RhCl(C(8)H(14))(2)](2) (0.10 eq), (S)-BINAP (0.10 eq), and ZnBr(2) (0.20 eq) afforded...

Palladium-catalyzed cross-coupling of cyclopropylmagnesium bromide with aryl bromides mediated by zinc halide additives.

J. Org. Chem. 75(19) , 6677-80, (2010)

The key Pd-catalyzed cross-coupling of aryl bromides or triflates and cyclopropylmagnesium bromide in the presence of substoichiometric amounts of zinc bromide produces cyclopropyl arenes in good to e...

Synthesis of tri- or tetrasubstituted pyrimidine derivatives through the [5+1] annulation of enamidines with either N,N-dimethylformamide dialkyl acetals or orthoesters and their application in a ring transformation of pyrimidines to pyrido[2,3-d]pyrimidin-5-one derivatives.

Chemistry 17(34) , 9385-94, (2011)

The [5+1] annulation of enamidines, which were prepared from functionalized silanes, organolithium compounds and two nitriles, with N,N-dimethylformamide dialkyl acetals as the C1 unit is described, l...


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Related Compounds

  • zinc bromide
  • ethylzinc bromide
  • methylzinc bromide
  • Benzylzinc bromide
  • thienylzinc bromide
  • benzyl zinc bromide
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