Tributyl citrate

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Names

[ CAS No. ]:
77-94-1

[ Name ]:
Tributyl citrate

[Synonym ]:
1,2,3-Propanetricarboxylic acid, 2-hydroxy-, tributyl ester
Tri-n-butyl citrate
Citric acid tri-n-butyl ester
EINECS 201-071-2
MFCD00027217
Citric acid, tributyl ester (8CI)
Tributyl citrate
tributyl 2-hydroxypropane-1,2,3-tricarboxylate

Chemical & Physical Properties

[ Density]:
1.1±0.1 g/cm3

[ Boiling Point ]:
389.8±9.0 °C at 760 mmHg

[ Melting Point ]:
≥300 °C(lit.)

[ Molecular Formula ]:
C18H32O7

[ Molecular Weight ]:
360.45

[ Flash Point ]:
120.7±12.2 °C

[ Exact Mass ]:
360.214813

[ PSA ]:
99.13000

[ LogP ]:
4.68

[ Vapour Pressure ]:
0.0±2.0 mmHg at 25°C

[ Index of Refraction ]:
1.465

[ Water Solubility ]:
insoluble

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TZ8608000
CHEMICAL NAME :
1,2,3-Propanetricarboxylic acid, 2-hydroxy-, tributyl ester
CAS REGISTRY NUMBER :
77-94-1
BEILSTEIN REFERENCE NO. :
1806072
LAST UPDATED :
199701
DATA ITEMS CITED :
3
MOLECULAR FORMULA :
C18-H32-O7

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
2900 mg/kg
TOXIC EFFECTS :
Behavioral - somnolence (general depressed activity) Vascular - other changes
REFERENCE :
JPMSAE Journal of Pharmaceutical Sciences. (American Pharmaceutical Assoc., 2215 Constitution Ave., NW, Washington, DC 20037) V.50- 1961- Volume(issue)/page/year: 53,774,1964 ** OTHER MULTIPLE DOSE TOXICITY DATA **
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
8120 mg/kg/14D-I
TOXIC EFFECTS :
Nutritional and Gross Metabolic - weight loss or decreased weight gain
REFERENCE :
JPMSAE Journal of Pharmaceutical Sciences. (American Pharmaceutical Assoc., 2215 Constitution Ave., NW, Washington, DC 20037) V.50- 1961- Volume(issue)/page/year: 53,774,1964

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves

[ Hazard Codes ]:
T: Toxic;

[ Risk Phrases ]:
R25

[ Safety Phrases ]:
S26-S36/37/39-S45-S24/25

[ RIDADR ]:
UN 2811 6.1/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
TZ8608000

[ HS Code ]:
2918150000

Synthetic Route

Precursor & DownStream

Precursor

  • Citric Acid
  • Butanol
  • Glyoxylic acid
  • Sulfuric acid

DownStream

  • Tributyl citrate acetate
  • 1,2,3-Propanetricarboxylic acid, 2-hydroxy-, trihexyl ester

Customs

[ HS Code ]: 2918150000

[ Summary ]:
2918150000. other salts and esters of citric acid. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:4ABXY(export license,certificate of inspection for goods inward,certificate of inspection for goods outwardexport license(processing trade),export license(border small volume trade)). MFN tariff:6.5%. General tariff:30.0%

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