1-(tert-Butyldimethylsilyloxy)-1-methoxyethene

Names

[ CAS No. ]:
77086-38-5

[ Name ]:
1-(tert-Butyldimethylsilyloxy)-1-methoxyethene

[Synonym ]:
MFCD02683524
TBS-methoxyethene

Chemical & Physical Properties

[ Density]:
0.863 g/mL at 25ºC(lit.)

[ Boiling Point ]:
62ºC9 mm Hg(lit.)

[ Molecular Formula ]:
C9H20O2Si

[ Molecular Weight ]:
188.33900

[ Flash Point ]:
125 °F

[ Exact Mass ]:
188.12300

[ PSA ]:
18.46000

[ LogP ]:
3.12580

[ Index of Refraction ]:
n20/D 1.429(lit.)

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F+

[ Risk Phrases ]:
10

[ RIDADR ]:
UN 1993 3/PG 3

[ Hazard Class ]:
3.0

[ HS Code ]:
2931900090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Methyl acetate
  • tert-Butyldimethylsilyl chloride

DownStream

  • tert-butyl-dimethyl-(6-methylcyclohexen-1-yl)oxysilane
  • 1-TERT-BUTYLDIMETHYLSILYLOXY-2-METHYL-1-CYCLOHEXENE
  • METHYL (R)-3-HYDROXY-3-PHENYLPROPANOATE
  • methyl (3S)-3-hydroxy-3-phenylpropanoate
  • 2-(tert-butyldimethylsilyloxy)cyclohexa&
  • 4-Phenylazetidin-2-on
  • 1-O-ethyl 5-O-methyl 2-acetyl-3,3-dimethylpentanedioate
  • Methyl (3S)-3-Boc-amino-3-phenylpropionate
  • R-3-tert-Butoxycarbonylamino-3-phenyl-propionic acid
  • METHYL 3-(2-HYDROXYPHENYL)PROPIONATE

Customs

[ HS Code ]: 2931900090

[ Summary ]:
2931900090. other organo-inorganic compounds. VAT:17.0%. Tax rebate rate:13.0%. Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward). MFN tariff:6.5%. General tariff:30.0%

Articles

New indenyl phosphinooxazoline complexes of iron and their catalytic activity in the Mukaiyama aldol reaction. Lenze M, et al.

Tetrahedron Lett. 51(21) , 2855-2858, (2010)

Recent developments in the syntheses of the epothilones and related analogues. Watkins EB, et al.

European J. Org. Chem. 18 , 4071-4084, (2006)

Enantioselective addition of ketene silyl acetals to nitrones catalyzed by chiral titanium complexes. Synthesis of optically active ß-amino acids. Murahashi SI, et al.

J. Am. Chem. Soc. 124(12) , 2888-2889, (2002)


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