Aluminium bromide

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Names

[ CAS No. ]:
7727-15-3

[ Name ]:
Aluminium bromide

[Synonym ]:
Aluminium bromide
tribromoalumane
Aluminium tribromide
Aluminum tribromide
MFCD00003421
AlBr3
ALUMINUM BROMIDE
tribromoaluminium
EINECS 231-779-7

Chemical & Physical Properties

[ Density]:
3.205 g/mL at 25 °C(lit.)

[ Boiling Point ]:
265 °C

[ Melting Point ]:
94-98 °C(lit.)

[ Molecular Formula ]:
AlBr3

[ Molecular Weight ]:
266.694

[ Flash Point ]:
268°C subl.

[ Exact Mass ]:
263.736542

[ LogP ]:
2.53680

[ Vapour Pressure ]:
1 mm Hg ( 81.3 °C)

[ Stability ]:
Stable, but reacts violently with water. Incompatible with aqueous solutions, alcohols, acids.

[ Water Solubility ]:
decomposes

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
BD0350000
CHEMICAL NAME :
Aluminum bromide
CAS REGISTRY NUMBER :
7727-15-3
LAST UPDATED :
199712
DATA ITEMS CITED :
17
MOLECULAR FORMULA :
Al-Br3
MOLECULAR WEIGHT :
266.71
WISWESSER LINE NOTATION :
.AL..E3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1598 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PHTOEH Pharmacology and Toxicology (Copenhagen). (Munksgaard International Pub., POB 2148, DK-1016 Copenhagen K, Denmark) V.60- 1987- Volume(issue)/page/year: 60,280,1987
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
815 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PHTOEH Pharmacology and Toxicology (Copenhagen). (Munksgaard International Pub., POB 2148, DK-1016 Copenhagen K, Denmark) V.60- 1987- Volume(issue)/page/year: 60,280,1987
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1623 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PHTOEH Pharmacology and Toxicology (Copenhagen). (Munksgaard International Pub., POB 2148, DK-1016 Copenhagen K, Denmark) V.60- 1987- Volume(issue)/page/year: 60,280,1987
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1068 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PHTOEH Pharmacology and Toxicology (Copenhagen). (Munksgaard International Pub., POB 2148, DK-1016 Copenhagen K, Denmark) V.60- 1987- Volume(issue)/page/year: 60,280,1987 *** REVIEWS *** ACGIH TLV-TWA 2 mg(Al)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-BELGIUM:TWA 2 mg(Al)/m3 JAN 1993 OEL-DENMARK:TWA 2 mg(Al)/m3 JAN 1993 OEL-FRANCE:TWA 2 mg(Al)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 2 mg(Al)/m3 JAN 1993 OEL-RUSSIA:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWEDEN:TWA 2 mg(Al)/m3 JAN 1993 OEL-SWITZERLAND:TWA 2 mg(Al)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 2 mg(Al)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV

Safety Information

[ Symbol ]:

GHS05, GHS07

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H302-H314

[ Supplemental HS ]:
Reacts violently with water.

[ Precautionary Statements ]:
P280-P305 + P351 + P338-P310

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
C:Corrosive

[ Risk Phrases ]:
R22;R34

[ Safety Phrases ]:
S9-S16-S26-S29-S36/37/39-S43-S45-S60-S61-S62-S28-S27

[ RIDADR ]:
UN 3264 8/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
BD0350000

[ Packaging Group ]:
II

[ Hazard Class ]:
8

[ HS Code ]:
28275900

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Aluminum Powder
  • allyl bromide
  • dialuminum,oxygen(2-),hydrate
  • Bromine
  • diphenylaluminum chloride
  • 1,2-Dibromoethane
  • bromine(•)
  • Aluminumnitratenonahydrate
  • Tin(IV) Bromide

DownStream

  • bromo-bis(2,2-dimethylpropyl)alumane
  • 2,4,6-Trimethylbromobenzene
  • 4-bromo-2,3,5,6-tetrafluoropyridine
  • Thionyl dibromide
  • 3,4,5,6-Tetrabromo-o-cresol
  • 3-Pyridinecarboxamide,4-methyl-
  • 1-Bromopentane
  • 2-CHLORO-2-METHYLBUTANE
  • Isobutane Residual Solvent Standard
  • 2-Bromo-3-methylbutane

Customs

[ HS Code ]: 28275900

Related Compounds

  • Aluminium bromide
  • Aluminium bromide hexahydrate
  • aluminium tris(diisopropylnaphthalenesulphonate)
  • Aluminium silicon
  • Aluminium hydroxide acetate hydrate
  • aluminium-catechin complex
  • Methyl 2-[[2-(diethylamino)acetyl]amino]-4-methyl-5-thiazolecarboxylate
  • Ethyl 6-[3-[(4-chlorophenyl)methyl]-1-azetidinyl]-4-quinolinecarboxylate
  • 2-(1,2-Dihydroxyethyl)benzene-1,3,5-triol
  • 5-Chloro-1H-1,2,4-triazole-3-carboxylic acid 2-(aminocarbonyl)hydrazide
  • 1-(Methyl-d3)-6-oxopyridine-3-carboxylic acid
  • 2-(6-Chloropyridin-2-yl)propanal
  • 7-Azadispiro[3.0.5^{5}.1^{4}]undecane-6,9-dione
  • 3-Pyrrolidinecarboxylic acid, 4-(1-methyl-1H-pyrrol-3-yl)-, ethyl ester
  • Methylamino-peg2-acid hydrochloride salt
  • 3-(oxiran-2-yl)-3,4-dihydro-2H-1-benzopyran
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