N-p-Tosylazetidine

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Names

[ CAS No. ]:
7730-45-2

[ Name ]:
N-p-Tosylazetidine

[Synonym ]:
MFCD00022359
Azetidine, 1-[(4-methylphenyl)sulfonyl]-
p-toluenesulfonylazetidine
Azetidine, 1-(p-tolylsulfonyl)-
1-[(4-Methylphenyl)sulfonyl]azetidine
Azetidine, 1- (p-tolylsulfonyl)-
N-p-Tosylazetidine
1-Tosylazetidine

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
337.6±35.0 °C at 760 mmHg

[ Melting Point ]:
119-122ºC(lit.)

[ Molecular Formula ]:
C10H13NO2S

[ Molecular Weight ]:
211.281

[ Flash Point ]:
158.0±25.9 °C

[ Exact Mass ]:
211.066696

[ PSA ]:
45.76000

[ LogP ]:
1.68

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.591

MSDS

Click to get detail MSDS

Safety Information

[ Personal Protective Equipment ]:
Eyeshields;Gloves;type N95 (US);type P1 (EN143) respirator filter

[ Safety Phrases ]:
22-24/25

[ RIDADR ]:
NONH for all modes of transport

[ HS Code ]:
2933990090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • Pentafluorobenzaldehyde
  • N-(3-bromopropyl)-4-methylbenzenesulfonamide
  • 3-(4-methylphenylsulfonamido)propyl 2-(phenylethynyl)-benzoate
  • Azetidine
  • 4-methyl-N-[3-(4-methylphenyl)sulfonyloxypropyl]benzenesulfonamide
  • 4-methyl-N-(3-(phenylselanyl)propyl)benzenesulfonamide
  • 4-Toluenesulfonamide
  • 1,3-Dibromopropane
  • 1,3-Bis(tosyloxy)propane
  • 4-methylbenzensulphonamide potassium salt

DownStream

  • Azetidine
  • 3-CHLOROPROPYLAMINE
  • 3-Aminopropan-1-ol

Customs

[ HS Code ]: 2933990090

[ Summary ]:
2933990090. heterocyclic compounds with nitrogen hetero-atom(s) only. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Ag(I)-catalyzed regioselective ring-opening of N-tosylaziridine and N-tosylazetidine with S-, O-, and N-nucleophiles and tethered dinucleophiles.

J. Org. Chem. 76(5) , 1475-8, (2011)

[Ag(COD)(2)]PF(6) catalyzes the ring-opening of N-tosylaziridines and -azetidines with alcohols, amines, thiols, and related tethered 1,2-ethane dinucleophiles. Initial rate studies and DFT-based eval...


More Articles

Related Compounds

  • N-(p-methoxyphenyl)-2,2,6,6-tetrachlorocyclohexaneimine
  • N-[p-(9-Acridinylamino)phenyl]ethanesulfonamide
  • N-(p-tolyl)methanesulfonimidomorpholide
  • N-p-Methoxybenzylthieno[3,2-d][1,3]oxazine-2,4-dione
  • N-p-toluenesulfonylpyrrole-3,4-dimethanol
  • N-p-Tosyl-N-n-butylcarbaminsaeureaethylester
  • 3-Amino-3-(4-chloro-3-methoxyphenyl)propan-1-ol
  • 3-Amino-1-(4-chloro-3-methoxyphenyl)propan-1-ol
  • 4,7-Dimethoxy-1H-indole-2-carbaldehyde
  • 4-(Phenylmethyl)-2-morpholineacetyl chloride
  • 1-[2-(Propan-2-yl)phenyl]cyclopentan-1-amine
  • 1-(1,3-Benzothiazol-6-yl)cyclopropanecarbaldehyde
  • 4-{[1,2,4]Triazolo[4,3-b]pyridazin-3-yl}piperidine hydrochloride
  • 1-(2-formylphenyl)-1H-pyrazole-4-carboxylic acid
  • 6-(Pyridin-3-yl)pyridazine-4-carboxylic acid
  • {4-[(4-Chlorophenyl)methoxy]-2-methylphenyl}boronic acid
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