N-(tert-Butyldimethylsilyl)-N-methyl-trifluoroacetamide

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Names

[ Name ]:
N-(tert-Butyldimethylsilyl)-N-methyl-trifluoroacetamide

[Synonym ]:
N-methyl-N-(tert-butyldimethylsilyl)trifluoroacetamide
Acetamide, N-[(1,1-dimethylethyl)dimethylsilyl]-2,2,2-trifluoro-N-methyl-
N-[tert-Butyl(dimethyl)silyl]-2,2,2-trifluoro-N-methylacetamide
N-[Dimethyl(2-methyl-2-propanyl)silyl]-2,2,2-trifluoro-N-methylacetamide
N-(tert-Butyldimethylsilyl)-N-methyl-trifluoroacetamide
MFCD00009671
FXFFCN1&-SI-1&1&X1&1&1
Acetamide, N-((1,1-dimethylethyl)dimethylsilyl)-2,2,2-trifluoro-N-methyl-
N-methyl-N-(t-butyldimethylsilyl)-trifluoroacetamide

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
182.6±35.0 °C at 760 mmHg

[ Molecular Formula ]:
C₉H₁₈F₃NOSi

[ Molecular Weight ]:
241.326

[ Flash Point ]:
64.2±25.9 °C

[ Exact Mass ]:
241.110977

[ PSA ]:
20.31000

[ LogP ]:
3.32

[ Vapour Pressure ]:
0.8±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.400

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
decomposes

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R10;R36/37/38

[ Safety Phrases ]:
S26-S36-S16

[ RIDADR ]:
UN 1993 3/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

N-Methyltrifluoroacetamide
tert-Butyldimethylsilyl chloride

DownStream

Articles

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J. Sci. Food Agric. 95(5) , 1094-102, (2015)

The cladodes of Opuntia ficus-indica (prickly pear cactus) have a low protein content; for use as a balanced feed, supplementation with other protein sources is therefore desirable. We investigated pr...

Matrix solid-phase dispersion of polybrominated diphenyl ethers and their hydroxylated and methoxylated analogues in lettuce, carrot and soil.

J. Chromatogr. A. 1360 , 57-65, (2014)

In the present work, a novel analytical method for the simultaneous determination of ten polybrominated diphenyl ethers (PBDEs), eight methoxylated PBDEs (MeO-PBDEs) and seven hydroxylated PBDEs (OH-P...

Determination of low levels of benzodiazepines and their metabolites in urine by hollow-fiber liquid-phase microextraction (LPME) and gas chromatography-mass spectrometry (GC-MS).

J. Chromatogr. B. Analyt. Technol. Biomed. Life Sci. 975 , 24-33, (2014)

In this study, it is shown a method for the determination of benzodiazepines and their main metabolites in urine samples by hollow-fiber liquid-phase microextraction (LPME) in the three-phase mode. In...