Pyraclofos

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Names

[ CAS No. ]:
77458-01-6

[ Name ]:
Pyraclofos

[Synonym ]:
Pyraclofos [ISO]
starlet
(Ξ)-{O-[1-(4-chlorophenyl)-1H-pyrazol-4-yl] O-ethyl S-propyl phosphorothioate}
O-ethyl-O-[1-(4-chlorophenyl)pyrazol-4-yl]-S-n-propyl phosphorothiolate
Boltage
Phosphorothioic acid,O-(1-(4-chlorophenyl)-1H-pyrazol-4-yl) O-ethyl S-propyl ester
1-(4-chlorophenyl)-4-(ethoxy-propylsulfanylphosphoryl)oxypyrazole
(RS)-[O-1-(4-chlorophenyl)pyrazol-4-yl O-ethyl S-propyl phosphorothioate]
1-(4-chlorophenyl)-4-[ethoxy(propylsulfanyl)phosphoryl]oxypyrazole
MFCD00274600
Boltage Gra
(RS)-O-1-(4-chlorophenyl)pyrazol-4-yl O-ethyl S-propyl phosphorothioate
Voltage
O-[1-(4-chlorophenyl)-1H-pyrazol-4-yl] O-ethyl S-propyl phosphorothioate
O-[1-(4-chlorophenyl)pyrazol-4-yl]-O-ethyl-S-n-propyl phosphorothioate
TIA 230
Pyraclofos
O-(1-(4-chlorophenyl)-1H-pyrazol-4-yl) O-ethyl S-propyl phosphorothioate

Chemical & Physical Properties

[ Density]:
1.271 g/cm3 (28 C)

[ Boiling Point ]:
454ºC

[ Molecular Formula ]:
C14H18ClN2O3PS

[ Molecular Weight ]:
360.79600

[ Exact Mass ]:
360.04600

[ PSA ]:
88.46000

[ LogP ]:
5.19230

[ Index of Refraction ]:
1.595

[ Storage condition ]:
0-6°C

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TE8346000
CHEMICAL NAME :
Phosphorothioic acid, O-(1-(4-chlorophenyl)-1H-pyrazol-4-yl) O-ethyl S-propyl ester, (+-)-
CAS REGISTRY NUMBER :
77458-01-6
LAST UPDATED :
199706
DATA ITEMS CITED :
4
MOLECULAR FORMULA :
C14-H18-Cl-N2-O3-P-S
MOLECULAR WEIGHT :
360.82

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
237 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,732,1991
TYPE OF TEST :
LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
1460 mg/m3
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,732,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Administration onto the skin
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
>2 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,732,1991
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
420 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
PEMNDP Pesticide Manual. (The British Crop Protection Council, 20 Bridport Rd., Thornton Heath CR4 7QG, UK) V.1- 1968- Volume(issue)/page/year: 9,732,1991

Safety Information

[ Hazard Codes ]:
Xi: Irritant;

[ Risk Phrases ]:
R22

[ RIDADR ]:
3018

[ RTECS ]:
TE8346000

[ Packaging Group ]:
III

[ Hazard Class ]:
6.1(b)

[ HS Code ]:
2933199011

Synthetic Route

Precursor & DownStream

Precursor

  • O-[1-(4-chlorophenyl)pyrazol-4-yl]-O,O-diethyl phosphite
  • Propyl disulfide
  • 1-(4-Chlorophenyl)-1H-pyrazol-4-ol
  • 1-[chloro(ethoxy)phosphoryl]sulfanylpropane
  • 1-Bromopropane

DownStream

Customs

[ HS Code ]: 2933199011

[ Summary ]:
2933199011 2-methoxy-6-pentylcyclohexa-2,5-diene-1,4-dione。supervision conditions:s(import or export registration certificate for pesticides)。VAT:17.0%。tax rebate rate:9.0%。MFN tarrif:6.5%。general tariff:20.0%


Related Compounds

  • N-(3-(2-oxopyrrolidin-1-yl)propyl)-2-((tetrahydrothiophen-3-yl)oxy)isonicotinamide
  • 5-((4-(4-(5-(Trifluoromethyl)pyridin-2-yl)piperazin-1-yl)piperidin-1-yl)methyl)thiophene-2-carbonitrile
  • N-(3-bromophenyl)-2-((tetrahydrothiophen-3-yl)oxy)isonicotinamide
  • 1-(1-((2,3-Dihydrobenzo[b][1,4]dioxin-2-yl)methyl)piperidin-4-yl)-4-(5-(trifluoromethyl)pyridin-2-yl)piperazine
  • 3-(4-(4-(5-(trifluoromethyl)pyridin-2-yl)piperazin-1-yl)piperidin-1-yl)dihydrofuran-2(3H)-one
  • N-(2-carbamoylphenyl)-2-((tetrahydrothiophen-3-yl)oxy)isonicotinamide
  • N-(4-sulfamoylphenyl)-2-((tetrahydrothiophen-3-yl)oxy)isonicotinamide
  • methyl N-{[1-(2-methoxyethyl)-4,6-dimethyl-2-oxo-1,2-dihydropyridin-3-yl]carbonyl}glycinate
  • N-(pyrimidin-2-yl)-2-((tetrahydrothiophen-3-yl)oxy)isonicotinamide
  • N-(1-benzylpiperidin-4-yl)-2-((tetrahydrothiophen-3-yl)oxy)isonicotinamide
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