2-Amino-4-methyl-6-methoxypyrimidine

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Names

[ CAS No. ]:
7749-47-5

[ Name ]:
2-Amino-4-methyl-6-methoxypyrimidine

[Synonym ]:
MFCD00059768
4-methoxy-6-methylpyrimidin-2-amine

Chemical & Physical Properties

[ Density]:
1.174 g/cm3

[ Boiling Point ]:
328.2ºC at 760 mmHg

[ Melting Point ]:
156-158 °C(lit.)

[ Molecular Formula ]:
C6H9N3O

[ Molecular Weight ]:
139.15500

[ Flash Point ]:
152.3ºC

[ Exact Mass ]:
139.07500

[ PSA ]:
61.03000

[ LogP ]:
0.95700

[ Index of Refraction ]:
1.557

[ Storage condition ]:
2-8°C

MSDS

Click to get detail MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xn:Harmful;

[ Risk Phrases ]:
R21/22;R36/37/38

[ Safety Phrases ]:
S26-S36-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ HS Code ]:
2933599090

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4-Chloro-6-methyl-2-pyrimidinamine
  • Sodium Methylate
  • Ethyl bromopyruvate
  • Methanol

DownStream

  • 2-Chloro-4-methoxy-6-methylpyrimidine
  • methyl N-(4-methoxy-6-methylpyrimidin-2-yl)carbamate

Customs

[ HS Code ]: 2933599090

[ Summary ]:
2933599090. other compounds containing a pyrimidine ring (whether or not hydrogenated) or piperazine ring in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Stepwise charge transfer complexation of some pyrimidines with sigma-acceptor iodine involving a new unconventional acceptor.

Spectrochim. Acta. A. Mol. Biomol. Spectrosc. 68(3) , 605-11, (2007)

Interactions of some pyrimidine derivatives, 4-amino-2,6-dimethylpyrimidine, kyanmethin, (4AP), 2-amino-4,6-dimethylpyrimidine (2AP), 2-aminopyrimidine (AP), 2-amino-4-methylpyrimidine (AMP), 2-amino-...

Hydrogen bonding in 2-amino-4-methoxy-6-methylpyrimidine, 2-benzylamino-4-benzyloxy-6-methylpyrimidine and 4-benzylamino-2,6-bis(benzyloxy)pyrimidine: pi-stacked chains of fused R22(8) rings, and centrosymmetric R22(8) dimers.

Acta Crystallogr. C 59(Pt 1) , o9-13, (2003)

Molecules of 2-amino-4-methoxy-6-methylpyrimidine, C(6)H(9)N(3)O, (I), lie on mirror planes in space group Pnma and are linked by two N-H...N hydrogen bonds [H...N = 2.26 and 2.34 A, N...N = 3.136 (2)...

Facile synthesis of Baylis-Hillman adducts bearing the carbamate or amide functional group at the secondary position. Lee KY, et al.

Bull. Korean Chem. Soc. 25 , 1966-68, (2004)


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