5-Bromopyrimidin-2-amine

Names

[ Name ]:
5-Bromopyrimidin-2-amine

[Synonym ]:
5-Bromo-2-pyrimidinamine
2-Pyrimidinamine, 5-bromo-
MFCD00012341
2-Amino-5-bromopyrimidine
5-Brompyrimidin-2-amin
5-Bromopyrimidin-2-amine

Chemical & Physical Properties

[ Density]:
1.8±0.1 g/cm3

[ Boiling Point ]:
340.7±34.0 °C at 760 mmHg

[ Melting Point ]:
241-243 °C(lit.)

[ Molecular Formula ]:
C₄H₄BrN₃

[ Molecular Weight ]:
173.999

[ Flash Point ]:
159.9±25.7 °C

[ Exact Mass ]:
172.958847

[ PSA ]:
51.80000

[ LogP ]:
0.78

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.649

[ Storage condition ]:
Refrigerator (+4°C)

[ Water Solubility ]:
Insoluble

MSDS

Safety Information

[ Symbol ]:

GHS07, GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H302-H319-H400

[ Precautionary Statements ]:
P273-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Faceshields;Gloves

[ Hazard Codes ]:
Xn:Harmful

[ Risk Phrases ]:
R22;R36;R50/53

[ Safety Phrases ]:
S26-S60-S61

[ RIDADR ]:
UN 3077 9/PG 3

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
9.0

[ HS Code ]:
29335995

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

2-Aminopyrimidine
2-Pyrimidinamine,1-oxide
Ammonia
5-Bromo-2-chloropyrimidine

DownStream

6-Bromo-2-methylimidazo[1,2-a]pyrimidine
5-Bromo-2-chloropyrimidine
2,5-Dibromopyrimidine
5-Bromo-N-methylpyrimidin-2-amine
5-Bromo-N,N-dimethylpyrimidin-2-amine
Methyl 2-Aminopyrimidine-5-carboxylate
2-Aminopyrimidine-5-boronic acid Pinacol ester
5-Bromo-2-hydroxypyrimidine
2-Aminopyrimidine-5-boronic acid
5-BROMO-2-(2,5-DIMETHYL-1H-PYRROL-1-YL)PYRIMIDINE

Customs

[ HS Code ]: 2933599090

[ Summary ]:
2933599090. other compounds containing a pyrimidine ring (whether or not hydrogenated) or piperazine ring in the structure. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:20.0%

Articles

Synthesis of pyridine, pyrimidine and pyridinone C-nucleoside phosphoramidites for probing cytosine function in RNA.

J. Org. Chem. 74(21) , 8021-30, (2009)

In the structures of the HDV ribozyme a cytosine nucleobase resides at the active site poised to participate directly in catalysis. Defining the functional role of the nucleobase requires nucleoside a...

J. Chem. Educ. 62 , 905, (1985)

Structure of 2-amino-5-bromopyrimidine. Watton HLL, et al.

Acta Crystallogr. C 44(10) , 1857-58, (1988)

N-BENZYL-5-BROMOPYRIMIDIN-2-AMINE
N,N-dibenzyl-5-bromopyrimidin-2-amine
N-(1-benzylpiperidin-4-yl)-5-bromopyrimidin-2-amine
n-(3-(1h-imidazol-1-yl)propyl)-5-bromopyrimidin-2-amine
N-[bis(aziridin-1-yl)phosphoryl]-5-bromopyrimidin-2-amine
(5-BROMOPYRIMIDIN-2-YL)PHENYLAMINE
{(R)-2-[(S)-2-(4-Amino-benzylcarbamoyl)-pyrrolidin-1-yl]-1-benzyl-2-oxo-ethyl}-carbamic acid tert-butyl ester
2,6-Dimethoxy-3-bromotetrahydropyran
2-(2,3-dihydro-1H-inden-1-yl)prop-2-enoic Acid
Trimethoxybiphenyl
Ethyl 4-oxo-4-(pyridin-4-ylamino)butanoate
N-allyl-4-bromo-2-chloroaniline
(31S,6aR,9aR)-6a-Ethyloctahydro-4H-pyrrolo[3,2,1-ij]quinoline-2,9-dione
(R)-alpha-(t-Butyldimethylsilyloxy)-alpha-phenylacetaldehyde
Di(propan-2-yl)-bis(prop-2-enyl)silane
1-[2-(Prop-2-yn-1-yloxy)ethyl]piperidine

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