Potassium bromate

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Names

[ CAS No. ]:
7758-01-2

[ Name ]:
Potassium bromate

[Synonym ]:
EINECS 231-829-8
MFCD00011359
Potassium bromate

Chemical & Physical Properties

[ Density]:
3.27

[ Melting Point ]:
350 °C

[ Molecular Formula ]:
BrKO3

[ Molecular Weight ]:
167.001

[ Exact Mass ]:
165.866776

[ PSA ]:
57.20000

[ LogP ]:
0.48920

[ Stability ]:
Stability Strong oxidizer - contact with combustible materials may cause fire. Incompatible with combustible material, organics, reducing agents, aluminium, finely powdered metals.

[ Water Solubility ]:
70 g/L (20 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
EF8725000
CHEMICAL NAME :
Bromic acid, potassium salt
CAS REGISTRY NUMBER :
7758-01-2
LAST UPDATED :
199701
DATA ITEMS CITED :
32
MOLECULAR FORMULA :
Br-O3.K
MOLECULAR WEIGHT :
167.01

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
321 mg/kg
TOXIC EFFECTS :
Behavioral - changes in motor activity (specific assay) Lungs, Thorax, or Respiration - respiratory stimulation Nutritional and Gross Metabolic - body temperature decrease
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
50 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
289 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
177 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
4200 mg/kg/13W-C
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Gastrointestinal - tumors
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
38500 mg/kg/2Y-C
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Kidney, Ureter, Bladder - Kidney tumors
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
19635 mg/kg/2Y-C
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Kidney, Ureter, Bladder - Kidney tumors Endocrine - thyroid tumors
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
19250 mg/kg/2Y-C
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Kidney, Ureter, Bladder - Kidney tumors
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
10500 mg/kg/39W-C
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Gastrointestinal - tumors Kidney, Ureter, Bladder - Kidney tumors
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
9625 mg/kg/2Y-C
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Kidney, Ureter, Bladder - Kidney tumors Endocrine - thyroid tumors
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
9625 mg/kg/2Y-C
TOXIC EFFECTS :
Tumorigenic - Carcinogenic by RTECS criteria Kidney, Ureter, Bladder - Kidney tumors
TYPE OF TEST :
TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5460 mg/kg/2Y-C
TOXIC EFFECTS :
Tumorigenic - neoplastic by RTECS criteria Kidney, Ureter, Bladder - Kidney tumors
TYPE OF TEST :
Micronucleus test
TYPE OF TEST :
DNA damage
TYPE OF TEST :
Cytogenetic analysis
TYPE OF TEST :
Cytogenetic analysis
TYPE OF TEST :
Micronucleus test
TYPE OF TEST :
Micronucleus test

MUTATION DATA

TYPE OF TEST :
DNA damage
TEST SYSTEM :
Mammal - pig Kidney
DOSE/DURATION :
7500 umol/L
REFERENCE :
CRNGDP Carcinogenesis (London). (Oxford Univ. Press, Pinkhill House, Southfield Road, Eynsham, Oxford OX8 1JJ, UK) V.1- 1980- Volume(issue)/page/year: 16,335,1995 *** REVIEWS *** IARC Cancer Review:Animal Sufficient Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 40,207,1986 IARC Cancer Review:Human No Adequate Data IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) V.1- 1972- Volume(issue)/page/year: 40,207,1986 IARC Cancer Review:Group 2B IMSUDL IARC Monographs, Supplement. (WHO Publications Centre USA, 49 Sheridan Ave., Albany, NY 12210) No.1- 1979- Volume(issue)/page/year: 7,56,1987 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 81949 No. of Facilities: 132 (estimated) No. of Industries: 6 No. of Occupations: 9 No. of Employees: 3252 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 81949 No. of Facilities: 1458 (estimated) No. of Industries: 10 No. of Occupations: 24 No. of Employees: 26562 (estimated) No. of Female Employees: 11090 (estimated)

Safety Information

[ Symbol ]:

GHS03, GHS06, GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H271-H301-H350

[ Precautionary Statements ]:
P201-P210-P283-P301 + P310 + P330-P308 + P313-P371 + P380 + P375

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P2 (EN 143) respirator cartridges;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
T:Toxic

[ Risk Phrases ]:
R25;R45;R9

[ Safety Phrases ]:
S53-S45

[ RIDADR ]:
UN 1484 5.1/PG 2

[ WGK Germany ]:
3

[ RTECS ]:
EF8725000

[ Packaging Group ]:
II

[ Hazard Class ]:
5.1

[ HS Code ]:
2829900090

Synthetic Route

Precursor & DownStream

Precursor

  • bromine(•)
  • 2(1H)-Pyrimidinone, 4-amino-1-tetrahydro-6-(hydroxymethyl)-2-phenylfuro3,4-d-1,3-dioxol-4-yl-
  • Potassium chlorate
  • Bromine
  • Potassium carbonate
  • Bromine trifluoride
  • potassium hypobromide
  • potassium hexafluorobromate
  • Water
  • oxygen

DownStream

  • Bromine
  • oxygen
  • 2(1H)-Pyrimidinone, 4-amino-1-tetrahydro-6-(hydroxymethyl)-2-phenylfuro3,4-d-1,3-dioxol-4-yl-
  • bromine(•)
  • bromic acid
  • Sodium bromide
  • potassium hypobromide
  • Selenium dioxide
  • Selenious acid
  • Silver bromate

Customs

[ HS Code ]: 2829900090

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