benzyl 2,2,2-trifluoroethyl sulfide

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Names

[ CAS No. ]:
77745-03-0

[ Name ]:
benzyl 2,2,2-trifluoroethyl sulfide

[Synonym ]:
benzyl trifluoroethyl thioether
Benzyl 2,2,2-trifluoroethyl sulfide
2,2,2-trifluoroethylthiomethylbenzene
MFCD00191786

Chemical & Physical Properties

[ Density]:
1.222 g/mL at 25ºC(lit.)

[ Boiling Point ]:
45-46ºC20 mm Hg(lit.)

[ Melting Point ]:
74ºC

[ Molecular Formula ]:
C9H9F3S

[ Molecular Weight ]:
206.22800

[ Flash Point ]:
50 °F

[ Exact Mass ]:
206.03800

[ PSA ]:
25.30000

[ LogP ]:
3.48210

[ Index of Refraction ]:
n20/D 1.490(lit.)

MSDS

Safety Information

[ Symbol ]:

GHS02

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225

[ Precautionary Statements ]:
P210

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
F

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
9-16

[ RIDADR ]:
UN 1993 3/PG 2

[ WGK Germany ]:
3

[ Packaging Group ]:
II

[ Hazard Class ]:
3.1

[ HS Code ]:
2930909090

Synthetic Route

Precursor & DownStream

Precursor

  • 2,2,2-trifluoroethyl tosylate
  • benzylthiol
  • 1-chloro-1,1,2-trifluoro-ethane
  • 2,2,2-TRIFLUOROETHYL METHANESULFONATE

DownStream

  • (Benzylsulfonyl)acetic acid
  • 2,2,2-Trifluoroethanesulfonyl chloride
  • Benzyl chloride
  • 2,2,2-TRIFLUOROETHANETHIOL
  • (1,1-dichloro-2,2,2-trifluoroethyl) thiohypochlorite

Customs

[ HS Code ]: 2930909090

[ Summary ]:
2930909090. other organo-sulphur compounds. VAT:17.0%. Tax rebate rate:13.0%. . MFN tariff:6.5%. General tariff:30.0%

Articles

Synthesis of 2, 2, 2-trifluoroethanesulfonic acid. Bunyagidj C, et al.

J. Org. Chem. 46(16) , 3335-36, (1981)

Yaws CL.

The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals 2nd ed.,, (2015), 234


More Articles


Related Compounds

  • benzyl 2,2,2-trifluoroethyl sulfonate
  • benzyl 2,2,2-trifluoroethyl carbonate
  • 4-(1,1-dichloro2,2,2-trifluoro-ethylthio)methylbenzene
  • 2,2,2-trifluoroethoxymethylbenzene
  • Benzyl [bis(2,2,2-trifluoroethyl)phosphono]acetate
  • benzyl 2,2,2-trichloroethyl diisopropylphosphoramidite