Sodamide
Suppliers
Names
[ CAS No. ]:
7782-92-5
[ Name ]:
Sodamide
[Synonym ]:
Aminosodium
MFCD00011117
Sodium azanide
sodium amide,sodamide
m amide
sodium amide NaNH2,orthorhombic,I
SODAMIDE
Natriumamid
Sodiumamide
EINECS 231-971-0
Chemical & Physical Properties
[ Density]:
1.4
[ Boiling Point ]:
400 °C(lit.)
[ Melting Point ]:
210 °C(lit.)
[ Molecular Formula ]:
H2NNa
[ Molecular Weight ]:
39.012
[ Flash Point ]:
85 °F
[ Exact Mass ]:
39.008495
[ PSA ]:
26.02000
[ LogP ]:
0.10970
[ Water Solubility ]:
REACTS VERY VIOLENTLY, EVEN EXPLOSIVELY
MSDS
Safety Information
[ Symbol ]:
GHS02, GHS05, GHS09
[ Signal Word ]:
Danger
[ Hazard Statements ]:
H261-H314-H400
[ Supplemental HS ]:
Contact with water liberates toxic gas., May form explosive peroxides.
[ Precautionary Statements ]:
P231 + P232-P273-P280-P305 + P351 + P338-P310-P422
[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges
[ Hazard Codes ]:
F:Flammable;C:Corrosive;
[ Risk Phrases ]:
R14/15;R19;R34
[ Safety Phrases ]:
S26-S43-S45-S62-S7/8-S43D-S36/37/39-S27-S16
[ RIDADR ]:
UN 3129 4.3/PG 2
[ WGK Germany ]:
2
[ Packaging Group ]:
II
[ Hazard Class ]:
4.3
[ HS Code ]:
2853009090
Customs
[ HS Code ]: 2853009090
Articles
Dalton Trans. 43(46) , 17324-32, (2014)
Trivalent Eu[N(SiHMe2)2]3(THF)2 can easily be synthesized by applying a routine salt metathesis protocol (EuCl3(THF)2 and 3 equiv. of Li[N(SiHMe2)2] in n-hexane) which crystallizes isotypically to its...
Phys. Chem. Chem. Phys. 17 , 22999-3006, (2015)
We demonstrate that the ammonia decomposition reaction catalysed by sodium amide proceeds under a different mechanism to ammonia decomposition over transition metal catalysts. Isotopic variants of amm...
Org. Biomol. Chem. 9 , 2743-2750, (2011)
Stannylated allylic carbonates are suitable substrates for Pd-catalyzed allylic aminations. In DMF and with [allylPdCl](2) as catalyst the stannylated allyl amines formed can be directly coupled with ...