phosphorus trifluoride

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Names

[ CAS No. ]:
7783-55-3

[ Name ]:
phosphorus trifluoride

[Synonym ]:
trifluorophosphane
phosphorus trfluoride
TL 75
Phosphorus fluoride
phosphorus(III) fluoride
Trifluorophosphine
phosphorous trifluoride
Phosphorous fluoride
EINECS 232-008-7
Trifluorophosphin

Chemical & Physical Properties

[ Density]:
3.907g/l

[ Boiling Point ]:
-95 ºC

[ Melting Point ]:
-90--88 ºC

[ Molecular Formula ]:
F3P

[ Molecular Weight ]:
87.96900

[ Flash Point ]:
-101.5°C

[ Exact Mass ]:
87.96900

[ PSA ]:
13.59000

[ LogP ]:
2.12180

[ Appearance of Characters ]:
Gas,Colorless

[ Water Solubility ]:
Slightly soluble (1.1 g/L) (25 ºC)

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
TH3850000
CHEMICAL NAME :
Phosphorus fluoride
CAS REGISTRY NUMBER :
7783-55-3
LAST UPDATED :
199712
DATA ITEMS CITED :
27
MOLECULAR FORMULA :
F3-P
MOLECULAR WEIGHT :
87.97
WISWESSER LINE NOTATION :
P F3

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE :
Inhalation
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
1900 mg/m3/10M
REFERENCE :
NDRC** National Defense Research Committee, Office of Scientific Research and Development, Progress Report. Volume(issue)/page/year: NDCrc-132,JUN1942 *** REVIEWS *** ACGIH TLV-TWA 2.5 mg(F)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 ACGIH TLV-Not classifiable as a human carcinogen DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: TLV/BEI,1997 *** U.S. STANDARDS AND REGULATIONS *** MSHA STANDARD-air:TWA 2.5 mg(F)/m3 DTLVS* The Threshold Limit Values (TLVs) and Biological Exposure Indices (BEIs) booklet issues by American Conference of Governmental Industrial Hygienists (ACGIH), Cincinnati, OH, 1996 Volume(issue)/page/year: 3,116,1971 OSHA PEL (Gen Indu):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1910.1000,1994 OSHA PEL (Construc):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1926.55,1994 OSHA PEL (Shipyard):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 29,1915.1000,1993 OSHA PEL (Fed Cont):8H TWA 2.5 mg(F)/m3 CFRGBR Code of Federal Regulations. (U.S. Government Printing Office, Supt. of Documents, Washington, DC 20402) Volume(issue)/page/year: 41,50-204.50,1994 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:TWA 2.5 mg(F)/m3 JAN 1993 OEL-BELGIUM:TWA 2.5 mg(F)/m3 JAN 1993 OEL-DENMARK:TWA 2.5 mg(F)/m3 JAN 1993 OEL-FINLAND:TWA 2.5 mg(F)/m3 JAN 1993 OEL-FRANCE:TWA 2.5 mg(F)/m3 JAN 1993 OEL-GERMANY:TWA 2.5 mg(F)/m3 JAN 1993 OEL-HUNGARY:TWA 1 mg(F)/m3;STEL 2 mg(F)/m3 JAN 1993 OEL-THE NETHERLANDS:TWA 2.5 mg(F)/m3 JAN 1993 OEL-THE PHILIPPINES:TWA 2.5 mg(F)/m3 JAN 1993 OEL-POLAND:TWA 1 mg(F)/m3 JAN 1993 OEL-SWEDEN:TWA 2 mg(F)/m3 JAN 1993 OEL-SWITZERLAND:TWA 1.8 ppm (1.5 mg(F)/m3);STEL 9.0 ppm JAN 1993 OEL-THAILAND:TWA 2.5 mg(F)/m3 JAN 1993 OEL-TURKEY:TWA 2.5 mg(F)/m3 JAN 1993 OEL-UNITED KINGDOM:TWA 2.5 mg(F)/m3 JAN 1993 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGIH TLV *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH RECOMMENDED EXPOSURE LEVEL (REL) : NIOSH REL TO FLUORIDES, INORGANIC-air:10H TWA 2.5 mg(F)/m3 REFERENCE : NIOSH* National Institute for Occupational Safety and Health, U.S. Dept. of Health, Education, and Welfare, Reports and Memoranda. Volume(issue)/page/year: DHHS #92-100,1992

Safety Information

[ Hazard Codes ]:
T

[ Risk Phrases ]:
R14;R32;R34

[ Safety Phrases ]:
S9;S38;S45

[ RIDADR ]:
UN 3308

[ RTECS ]:
TH3850000

[ Hazard Class ]:
2.3

Synthetic Route

Precursor & DownStream

Precursor

  • Trifluorostibine
  • Phosphorus trichloride
  • Phosphorus tribromide
  • Phosphoryl fluoride
  • chlorodifluorophosphane
  • arsenic trifluoride
  • Tetrakis(trifluormethyl)phosphinigsaeureanhydrid
  • Phosphorus pentachloride
  • bromo(difluoro)phosphane
  • dibromofluorophosphane

DownStream

  • Phosphine
  • Phosphorus trichloride
  • fluoro-hydroxy-oxophosphanium
  • cyclooctasulfur
  • Phosphorus pentafluoride
  • Tetrafluoroethylene
  • Carbon tetrafluoride
  • Silicon tetrafluoride
  • TETRAKIS(TRIFLUOROPHOSPHINE)NICKEL (0)
  • sulfur(+2) tetrahydride cation tetrafluoride

Related Compounds

  • PHOSPHORUS TRIFLUORIDE
  • phosphorus trifluoride-borane
  • Borane(3).phosphorus trifluoride
  • Chromium,hexakis(phosphorus trifluoride)
  • Palladium tetrakis(phosphorus trifluoride)
  • Molybdenum,hexakis(phosphorus trifluoride)