(+)-alpha-Pinene

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Names

[ CAS No. ]:
7785-70-8

[ Name ]:
(+)-alpha-Pinene

[Synonym ]:
2,6,6-Trimethyl-bicyclo[3.1.1]hept-2-ene
(±)-2-Pinene
2,6,6-Trimethylbicyclo[3.1.1]hept-2-ene
(1R,5R)-4,6,6-trimethylbicyclo[3.1.1]hept-3-ene
(1R)-(+)-alpha-Pinene
Bicyclo[3.1.1]hept-2-ene, 2,6,6-trimethyl-
Pinene
EINECS 232-087-8
MFCD00001346
(+)-alpha-pinene
α-Pinene

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
157.9±7.0 °C at 760 mmHg

[ Melting Point ]:
-62ºC

[ Molecular Formula ]:
C10H16

[ Molecular Weight ]:
136.234

[ Flash Point ]:
32.2±0.0 °C

[ Exact Mass ]:
136.125198

[ LogP ]:
4.37

[ Vapour Pressure ]:
3.5±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.479

[ Storage condition ]:
2-8°C

MSDS

Safety Information

[ Symbol ]:

GHS02, GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H226-H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;Faceshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R10;R36/37/38

[ Safety Phrases ]:
S16-S23

[ RIDADR ]:
UN 2368 3/PG 3

[ WGK Germany ]:
3

[ RTECS ]:
DT7000000

[ Packaging Group ]:
III

[ Hazard Class ]:
3.0

[ HS Code ]:
2902199090

Synthetic Route

Precursor & DownStream

Precursor

  • Bis(2,6,6-trimethylbicyclo[3.1.1]hept-3-yl)borane
  • [(1R,2S,3R,5R)-2,6,6-Trimethylbicyclo[3.1.1]hept-3-yl]borane
  • isopinocampheyl boron dichloride
  • (-)-isopinocamphyl tosylate
  • (-)-Isopinocampheol
  • Benzaldehyde
  • (4aR,8aR)-1-((1R,2S,3R,5R)-2,6,6-trimethylbicyclo[3.1.1]heptan-3-yl)decahydrobenzo[b]borinine
  • ch3cho

DownStream

  • p-cymene
  • (-)-camphene
  • (S)-(-)-Limonene
  • cyclene
  • β-pinene
  • 6,6-dimethyl4-methylidenebicyclo[3.1.1]hept-2-ene
  • norbornane, 7,7-dimethyl-2-methylene
  • (6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)methyl acetate
  • Bornyl acetate

Customs

[ HS Code ]: 2902199090

[ Summary ]:
2902199090 other cyclanes, cyclenes and cyclotherpenes。Supervision conditions:None。VAT:17.0%。Tax rebate rate:9.0%。MFN tariff:2.0%。General tariff:30.0%

Articles

Aldrichimica Acta 13 , 13, (1980)

J. Org. Chem. 59 , 2365, (1994)

Aldrichimica Acta 20 , 24, (1987)


More Articles


Related Compounds

  • (+/-)-ALPHA-(2,3-DIMETHOXY-PHENYL)-1-[2-(4-FLUOROPHENYL)ETHYL]-4-PIPERIDINE-METHANOL
  • (+-)-alpha-Cyclohexyl-alpha-phenyl-1-pyrrolidinepropanol hydrochloride
  • (+/-)-ALPHA-AMINO-3-HYDROXY-5-METHYLISOXAZOLE-4-PROPIONICACIDHYDROBROMIDE
  • (+)-alpha-amorphene
  • (+/-)-ALPHA-DAMASCONE
  • (+)-alpha-curcumene
  • 1-(4-chloro-2-(trifluoromethyl)benzyl)-1H-indazole-5-carbaldehyde
  • 3-(4-Bromo-3,5-dimethylphenyl)piperidine
  • Methyl 2-(1-aminocyclopropyl)propanoate
  • N-(4-formyl-3,5-dimethyl-phenyl)-acetamide
  • Methyl 3-amino-2-cyclopropylpropanoate
  • 1-Naphthalenamine, N-(2-bromo-4-chlorophenyl)-1,2,3,4-tetrahydro-
  • Methyl 2-(aminomethyl)-3,3-dimethylbutanoate
  • Methyl 2-amino-2-cyclopentylpropanoate
  • (2S,3S,4R,5R)-2,3,4,5,6,7-Hexahydroxyheptanal
  • 3-Amino-cycloheptanecarboxylic acid methyl ester
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