Bismuth(III) chloride oxide

Names

[ Name ]:
Bismuth(III) chloride oxide

[Synonym ]:
BISMUTH OXYBROMIDE
bismuth oxobromide
bismuth(III) oxide chloride
EINECS 232-122-7
Plearlglo UVR
MFCD00010895
bismuth(III) oxide bromide
Bismuth(III) oxychloride
Wismut(III)-oxybromid

Chemical & Physical Properties

[ Density]:
7.72 g/mL at 25 °C(lit.)

[ Melting Point ]:
melts at low red heat

[ Molecular Formula ]:
BiClO

[ Molecular Weight ]:
260.43300

[ Exact Mass ]:
259.94400

[ PSA ]:
17.07000

[ LogP ]:
0.57070

[ Index of Refraction ]:
2.15

[ Water Solubility ]:
Soluble in HCl, HNO3. Insoluble in water, alcohol.

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: EB2700000

CHEMICAL NAME :: Bismuth chloride oxide

CAS REGISTRY NUMBER :: 7787-59-9

LAST UPDATED :: 199701

DATA ITEMS CITED :: 4

MOLECULAR FORMULA :: Bi-Cl-O

MOLECULAR WEIGHT :: 260.43

WISWESSER LINE NOTATION :: BI O G

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: 22 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

REFERENCE :: FCTXAV Food and Cosmetics Toxicology. (London, UK) V.1-19, 1963-81. For publisher information, see FCTOD7. Volume(issue)/page/year: 13,543,1975 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 82927 No. of Facilities: 153 (estimated) No. of Industries: 2 No. of Occupations: 8 No. of Employees: 4832 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 82927 No. of Facilities: 1374 (estimated) No. of Industries: 4 No. of Occupations: 7 No. of Employees: 16115 (estimated) No. of Female Employees: 6096 (estimated)

Safety Information

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S36

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
2

[ RTECS ]:
EB2700000

[ HS Code ]:
2827499000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

Hydrochloric acid
Bismuth trioxide
Bismuth(III)chloride
Water
nitrogen dioxide
Chlorine

DownStream

Bismuth trioxide
Bismuth
Bismuth(III)chloride
Bismuthine, triiodo-
Bismuth(III) Fluoride
Chlorine

Customs

[ HS Code ]: 2827499000

Articles

Mineralization and toxicity reduction of textile dye neutral red in aqueous phase using BiOCl photocatalysis.

J. Photochem. Photobiol. B, Biol. 116 , 48-55, (2012)

The BiOCl catalyst was prepared by hydrolysis method. The compound was extensively characterized by XRD, SEM, TEM, UV-vis measurements and BET surface area. The prepared material had average pore diam...

[Main problems of occupational hygiene in the production of bismuth and its compounds].

Gig. Tr. Prof. Zabol. (6) , 16-21, (1986)

Photodegradation of Rhodamine B over unexcited semiconductor compounds of BiOCl and BiOBr.

J. Colloid. Interface Sci. , (2012)

This study reported, for the first time systematically, photodegradation of Rhodamine B (RhB) in aqueous solution over BiOCl and BiOBr semiconductors. Under visible light irradiation (λ>400 nm, λ>420 ...

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