Biphenyl-4,4'-dicarboxylic acid

Suppliers

Names

[ CAS No. ]:
787-70-2

[ Name ]:
Biphenyl-4,4'-dicarboxylic acid

[Synonym ]:
4,4'-dicarboxybiphenyl
4,4'-DIPHENIC ACID
EINECS 212-328-3
Biphenyl-4,4'-dicarboxylicacid
P,P'-DIPHENIC ACID
4,4′-biphenyldicarboxylic acid
usafdo-69
biphenyl-4,4′-dicarboxylic acid
BIBENZOIC ACID
4,4'-DIBENZOIC ACID
biphenyl-4,4'-dicarboxylic acid
4,4'-BIBENZOIC ACID
4,4'-dicarboxybiphenylic acid
4,4'-Diphenit acid
4,4'-H2bpdc
Biphenyl-4,4'-dicarb
1,1'-biphenyl-4,4'-dicarboxylic acid
[1,1'-Biphenyl]-4,4'-dicarboxylic acid
RARECHEM AL BO 0295
4,4'-Biphenyldicarboxylic acid
4,4'-BISBENZOIC ACID
MFCD00002554

Chemical & Physical Properties

[ Density]:
1.3±0.1 g/cm3

[ Boiling Point ]:
482.5±38.0 °C at 760 mmHg

[ Melting Point ]:
>300 °C(lit.)

[ Molecular Formula ]:
C14H10O4

[ Molecular Weight ]:
242.23

[ Flash Point ]:
259.7±23.3 °C

[ Exact Mass ]:
242.057907

[ PSA ]:
74.60000

[ LogP ]:
3.52

[ Vapour Pressure ]:
0.0±1.3 mmHg at 25°C

[ Index of Refraction ]:
1.639

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
DV2975000
CHEMICAL NAME :
4,4'-Biphenyldicarboxylic acid
CAS REGISTRY NUMBER :
787-70-2
BEILSTEIN REFERENCE NO. :
0523308
LAST UPDATED :
199701
DATA ITEMS CITED :
2
MOLECULAR FORMULA :
C14-H10-O4
MOLECULAR WEIGHT :
242.24
WISWESSER LINE NOTATION :
QVR DR DVQ

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
500 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
REFERENCE :
NTIS** National Technical Information Service. (Springfield, VA 22161) Formerly U.S. Clearinghouse for Scientific & Technical Information. Volume(issue)/page/year: AD277-689

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
dust mask type N95 (US);Eyeshields;Gloves

[ Hazard Codes ]:
Xi:Irritant

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S26-S37/39

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
3

[ RTECS ]:
DV2975000

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

  • 4-Iodobenzoic acid
  • 4-Chlorobenzoic acid
  • 4-Bromobenzoic acid
  • p-Boronobenzoic acid
  • p-Xylene
  • BI-P-TOLYL
  • 4,4'-Diacetylbiphenyl
  • potassium (4-methoxycarbonylphenyl)trifluoroborate
  • carbon monoxide
  • 4,4'-Dibromobiphenyl

DownStream

  • Diethyl 4,4'-biphenyldicarboxylate
  • Biphenyl-4,4'-dicarbonyl dichloride
  • Biphenyl dimethyl dicarboxylate
  • 4,4'-Biphenyldicarbaldehyde
  • 4,4'-Biphenyldiyldimethanol
  • 4,4'-Bis(chloromethyl)biphenyl
  • 4,4'-Bis(bromomethyl)biphenyl
  • 4,4'-BISBENZHYDRAZIDE
  • 4-(4-carboxy-2-nitrophenyl)-3-nitrobenzoic acid

Articles

From small building blocks to complex molecular architecture.

Org. Lett. 8 , 1367, (2006)

[reaction: see text] We describe a synthesis of a dendrimer-like amphiphile containing a flat rigid core and 12 hydrophobic and hydrophilic arms. We employ a modular approach based on stepwise protect...


More Articles

Related Compounds

  • 2-methylbiphenyl-4,4'-dicarboxylic acid
  • 2-methoxy-biphenyl-4,4'-dicarboxylic acid
  • biphenyl-4,4'-dicarboxylic acid dichloride
  • biphenyl-4,4'-dicarboxylic acid dihydrazide
  • 2,2'-dinitrobiphenyl-4,4'-dicarboxylic acid
  • 2,2'-dimethylbiphenyl-4,4'-dicarboxylic acid
  • 2-(Bromomethyl)-6-(difluoromethyl)-3-fluoro-4-iodopyridine
  • 2-(Chloromethyl)-4-cyano-6-(difluoromethyl)-3-methylpyridine
  • 2-(Bromomethyl)-6-(difluoromethyl)-4-iodo-3-(trifluoromethyl)pyridine
  • 2-(Chloromethyl)-5-(difluoromethyl)-3-fluoro-6-iodopyridine
  • 2-(Bromomethyl)-5-(difluoromethyl)-3-(trifluoromethoxy)pyridine-6-carboxylic acid
  • 2-(Chloromethyl)-3-(difluoromethyl)-5-methoxy-4-nitropyridine
  • 2-(Bromomethyl)-6-(difluoromethyl)-5-hydroxy-3-(trifluoromethoxy)pyridine
  • 2-(Chloromethyl)-5-(difluoromethyl)-3-fluoro-4-nitropyridine
  • 3-Formylcyclobutyl 4-methylbenzenesulfonate
  • 2-(Chloromethyl)-3-(difluoromethyl)-6-iodo-4-(trifluoromethyl)pyridine