N-Methylacetamide

Suppliers

Names

[ CAS No. ]:
79-16-3

[ Name ]:
N-Methylacetamide

[Synonym ]:
Acetamide, N-methyl-
Acetamide,methyl
N-Monomethylacetamide
N-Methyl acetamide
Acetylmethylamine
Acetamide,N-methyl
N-acetyl-methylamine
EINECS 201-182-6
N-Acetylmethylamine
N-Methyl-acetamide
Monomethylacetamide
N-Methylacetamide
MFCD00008683
Methylacetamide

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
125.0±23.0 °C at 760 mmHg

[ Melting Point ]:
26-28 °C(lit.)

[ Molecular Formula ]:
C3H7NO

[ Molecular Weight ]:
73.094

[ Flash Point ]:
46.2±11.9 °C

[ Exact Mass ]:
73.052765

[ PSA ]:
29.10000

[ LogP ]:
-0.09

[ Vapour Pressure ]:
5.8±0.5 mmHg at 25°C

[ Index of Refraction ]:
1.410

[ Stability ]:
Stable. Combustible. Incompatible with strong oxidizing agents.

[ Water Solubility ]:
soluble

MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :
AC5960000
CHEMICAL NAME :
Acetamide, N-methyl-
CAS REGISTRY NUMBER :
79-16-3
LAST UPDATED :
199710
DATA ITEMS CITED :
23
MOLECULAR FORMULA :
C3-H7-N-O
MOLECULAR WEIGHT :
73.11
WISWESSER LINE NOTATION :
1VM1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
5 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
2750 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Subcutaneous
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3600 mg/kg
TOXIC EFFECTS :
Gastrointestinal - other changes Liver - other changes Endocrine - other changes
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Unreported
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
3200 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intraperitoneal
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
4380 mg/kg
TOXIC EFFECTS :
Nutritional and Gross Metabolic - weight loss or decreased weight gain Nutritional and Gross Metabolic - body temperature decrease
TYPE OF TEST :
LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - mouse
DOSE/DURATION :
4015 mg/kg
TOXIC EFFECTS :
Nutritional and Gross Metabolic - weight loss or decreased weight gain Nutritional and Gross Metabolic - body temperature decrease
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Rodent - rabbit
DOSE/DURATION :
16940 mg/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE :
Intravenous
SPECIES OBSERVED :
Bird - chicken
DOSE/DURATION :
14 gm/kg
TOXIC EFFECTS :
Details of toxic effects not reported other than lethal dose value
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
SPECIES OBSERVED :
Rodent - rat
DOSE/DURATION :
90 gm/kg/90D-C
TOXIC EFFECTS :
Kidney, Ureter, Bladder - changes in tubules (including acute renal failure, acute tubular necrosis) Blood - changes in bone marrow (not otherwise specified) Nutritional and Gross Metabolic - weight loss or decreased weight gain
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
2 gm/kg
SEX/DURATION :
female 7 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Administration onto the skin
DOSE :
1200 mg/kg
SEX/DURATION :
female 10-11 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetal death
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Intraperitoneal
DOSE :
2 gm/kg
SEX/DURATION :
female 15-16 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus) Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
3250 mg/kg
SEX/DURATION :
female 6-18 day(s) after conception
TOXIC EFFECTS :
Reproductive - Specific Developmental Abnormalities - craniofacial (including nose and tongue) Reproductive - Specific Developmental Abnormalities - body wall Reproductive - Specific Developmental Abnormalities - musculoskeletal system
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
3250 mg/kg
SEX/DURATION :
female 6-18 day(s) after conception
TOXIC EFFECTS :
Reproductive - Effects on Embryo or Fetus - fetotoxicity (except death, e.g., stunted fetus)
TYPE OF TEST :
TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE :
Oral
DOSE :
130 mg/kg
SEX/DURATION :
female 6-18 day(s) after conception
TOXIC EFFECTS :
Reproductive - Fertility - post-implantation mortality (e.g. dead and/or resorbed implants per total number of implants)
TYPE OF TEST :
DNA inhibition

MUTATION DATA

TYPE OF TEST :
Sister chromatid exchange
TEST SYSTEM :
Rodent - hamster Ovary
DOSE/DURATION :
10 gm/L
REFERENCE :
APHGAO Acta Pharmaceutica Hungarica. (Kultura, POB 149, H-1389 Budapest, Hungary) 1953- Adopts V.24 in 1955. Volume(issue)/page/year: 56,97,1986 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - X4317 No. of Facilities: 17 (estimated) No. of Industries: 1 No. of Occupations: 1 No. of Employees: 851 (estimated) No. of Female Employees: 187 (estimated)

Safety Information

[ Symbol ]:

GHS08

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H360D

[ Precautionary Statements ]:
P201-P308 + P313

[ Personal Protective Equipment ]:
Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
T:Toxic;

[ Risk Phrases ]:
R61

[ Safety Phrases ]:
S53-S45

[ RIDADR ]:
NONH for all modes of transport

[ WGK Germany ]:
2

[ RTECS ]:
AC5960000

[ HS Code ]:
2942000000

Synthetic Route

Precursor & DownStream

Precursor

  • acetic acid
  • methylamine
  • Propan-2-one oxime
  • 2-N,3-N-dimethylbutane-2,3-diimine
  • Acetone
  • carbon monoxide
  • Trimethylamine
  • N-bromo-N-methylacetamide
  • 1-(Methylamino)ethanethione

DownStream

  • 2-Fluoropyridine
  • N-Methyl-N-vinylacetamide
  • 5-AMINO-3-(2-FURYL)ISOXAZOLE-4-CARBONITRILE
  • 2-methylamino-5-nitropyridine
  • 2-[(2-carbonochloridoylphenyl)disulfanyl]benzoyl chloride
  • N-methyl-N-triethylsilylacetamide
  • N-(2-oxopropyl)carbamoyl chloride
  • n-benzylacetamide
  • Acetamide

Customs

[ HS Code ]: 2942000000

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Related Compounds

  • N-methylacetamide
  • N-methylacetamide-d
  • N-methylacetamide-d3
  • N-Methylacetamide-d6
  • N-Methylacetamide-d7
  • N-methylacetamide anion
  • 3-Methyl-3-[5-(trifluoromethyl)furan-2-yl]butan-1-amine
  • (2R)-4-(5-fluoro-2-methoxy-4-methylphenyl)butan-2-amine
  • 1-{4,8-Diazaspiro[2.6]nonan-4-yl}ethan-1-one
  • N-(3-methylbutan-2-yl)-4,8-diazaspiro[2.6]nonane-4-carboxamide
  • 4-(Propane-1-sulfonyl)-4,8-diazaspiro[2.6]nonane
  • 2-fluoro-4-({[3-methyl-1-(propan-2-yl)-1H-pyrazol-4-yl]amino}methyl)phenol
  • 7-methyl-7-[(thiophen-3-yl)methyl]-4H,5H,6H,7H-thieno[2,3-c]pyridine
  • 6-Ethyl-7-methyl-2-(pentan-2-yl)-[1,2,4]triazolo[1,5-a]pyridin-5-ol
  • 5-Bromo-6-methyl-3-[3-(propan-2-yl)phenyl]-3,4-dihydropyrimidin-4-one
  • 7-Propyl-[1,2,4]triazolo[1,5-a]pyridin-5-ol
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