(+)-Camphene

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Names

[ CAS No. ]:
79-92-5

[ Name ]:
(+)-Camphene

[Synonym ]:
(+)-Camphene
2-tert-butylpropenal
3,3-dimethyl-2-methylenebutanal
Bicyclo(2.2.1)heptane, 2,2-dimethyl-3-methylene-, (1R,4S)-
(1R,4S)-2,2-Dimethyl-3-methylenebicyclo[2.2.1]heptane
EINECS 201-234-8
Bicyclo[2.2.1]heptane, 2,2-dimethyl-3-methylene-, (1R,4S)-
Camphene, (1R,4S)-(+)-
Camphene
2-tert-butyl-acrylaldehyde
3,3-dimethyl-2-methylenenorbornane
2,2-dimethyl-3-methylene-norbornane
2,2-dimethyl-3-methylidenebicyclo<2.2.1>heptane
3,3-DIMETHYL-2-METHYLENE-BUTYRALDEHYDE
2-tert-Butyl-acrylaldehyd
2-tert-butylacrolein
MFCD00066603

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
158.6±7.0 °C at 760 mmHg

[ Melting Point ]:
48-52 °C(lit.)

[ Molecular Formula ]:
C₁₀H₁₆

[ Molecular Weight ]:
136.234

[ Flash Point ]:
36.7±0.0 °C

[ Exact Mass ]:
136.125198

[ LogP ]:
4.37

[ Vapour Pressure ]:
3.4±0.1 mmHg at 25°C

[ Index of Refraction ]:
1.484

[ Water Solubility ]:
practically insoluble

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: EX1055000

CHEMICAL NAME :: Camphene

CAS REGISTRY NUMBER :: 79-92-5

LAST UPDATED :: 199712

DATA ITEMS CITED :: 8

MOLECULAR FORMULA :: C10-H16

MOLECULAR WEIGHT :: 136.26

WISWESSER LINE NOTATION :: L55 A CYTJ CU1 D1 D1

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Oral

SPECIES OBSERVED :: Rodent - rat

DOSE/DURATION :: >5 gm/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD - Lethal dose

ROUTE OF EXPOSURE :: Intraperitoneal

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: >500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

TYPE OF TEST :: LD50 - Lethal dose, 50 percent kill

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - rabbit

DOSE/DURATION :: >2500 mg/kg

TOXIC EFFECTS :: Details of toxic effects not reported other than lethal dose value

MUTATION DATA

TYPE OF TEST :: Body fluid assay

TEST SYSTEM :: Rodent - rat Bacteria - Salmonella typhimurium

DOSE/DURATION :: 2500 mg/kg

REFERENCE :: NUCADQ Nutrition and Cancer. (Franklin Institute Press, POB 2266, Phildelphia, PA 19103) V.1- 1978- Volume(issue)/page/year: 1,10,1979 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - M4188 No. of Facilities: 25 (estimated) No. of Industries: 1 No. of Occupations: 4 No. of Employees: 2675 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - M4188 No. of Facilities: 6181 (estimated) No. of Industries: 81 No. of Occupations: 83 No. of Employees: 114605 (estimated) No. of Female Employees: 29452 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS07, GHS09

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H228-H319-H410

[ Precautionary Statements ]:
P210-P273-P305 + P351 + P338-P501

[ Personal Protective Equipment ]:
Eyeshields;full-face particle respirator type N100 (US);Gloves;respirator cartridge type N100 (US);type P1 (EN143) respirator filter;type P3 (EN 143) respirator cartridges

[ Hazard Codes ]:
F

[ Risk Phrases ]:
R10

[ Safety Phrases ]:
S16-S33

[ RIDADR ]:
UN 1325 4.1/PG 2

[ WGK Germany ]:
2

[ RTECS ]:
EX1055000

[ Packaging Group ]:
III

[ Hazard Class ]:
4.1

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Cumene
(S)-verbenone
o-Cymene
camphenilone
2-exo-6-exo-5,5,6-trimethylbicyclo[2.2.1]heptan-2-ol
camphene hydrate
borneol
3,3-dimethyl-2-(nitromethylidene)bicyclo[2.2.1]heptane
Carbon tetrachloride
Carbon dioxide

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