2-(Trimethylsilyl)thiazole

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Names

[ CAS No. ]:
79265-30-8

[ Name ]:
2-(Trimethylsilyl)thiazole

[Synonym ]:
2-(Trimethylsilyl)thiazole
2-(Trimethylsilyl)-1,3-thiazole
trimethyl(1,3-thiazol-2-yl)silane
MFCD00066274
2-trimethylsilyl-1,3-thiazole
Thiazole, 2-(trimethylsilyl)-

Chemical & Physical Properties

[ Density]:
1.0±0.1 g/cm3

[ Boiling Point ]:
174.7±0.0 °C at 760 mmHg

[ Molecular Formula ]:
C6H11NSSi

[ Molecular Weight ]:
157.309

[ Flash Point ]:
57.2±0.0 °C

[ Exact Mass ]:
157.038147

[ PSA ]:
41.13000

[ LogP ]:
2.09

[ Vapour Pressure ]:
1.6±0.3 mmHg at 25°C

[ Index of Refraction ]:
1.487

[ Storage condition ]:
2-8°C

[ Water Solubility ]:
IMMISCIBLE

MSDS

Safety Information

[ Symbol ]:

GHS07

[ Signal Word ]:
Warning

[ Hazard Statements ]:
H315-H319-H335

[ Precautionary Statements ]:
P261-P305 + P351 + P338

[ Personal Protective Equipment ]:
Eyeshields;full-face respirator (US);Gloves;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter

[ Hazard Codes ]:
Xi:Irritant;

[ Risk Phrases ]:
R36/37/38

[ Safety Phrases ]:
S23-S24/25-S26

[ RIDADR ]:
1993

[ WGK Germany ]:
3

[ Packaging Group ]:
III

[ Hazard Class ]:
3

[ HS Code ]:
2934100090

Synthetic Route

Precursor & DownStream

Precursor

  • Thiazole
  • Chlorotrimethylsilane
  • 2-Bromothiazole
  • lithium,2H-1,3-thiazol-2-ide

DownStream

  • 5-Bromothiazole
  • 5-BROMO-2-IODOTHIAZOLE
  • 2-THIAZOLYL-2-THIENYL KETONE
  • 2-Bromo-1-thiazol-2-yl-ethanone
  • Thiazole
  • Ethyl 2-chlorothiazole-5-carboxylate
  • ethyl 2-iodothiazole-5-carboxylate
  • 2,5-BISTRIMETHYLSILANYLTHIAZOLE
  • Thiazole-5-boronic acid pinacol ester
  • 2-(Tributylstannyl)-1,3-thiazole

Customs

[ HS Code ]: 2934100090

[ Summary ]:
2934100090 other compounds containing an unfused thiazole ring (whether or not hydrogenated) in the structure VAT:17.0% Tax rebate rate:9.0% Supervision conditions:none MFN tariff:6.5% General tariff:20.0%

Articles

A. Dondoni et al.

J. Org. Chem. 58 , 3196, (1993)

A. Dondoni, P. Merino

Organic Synth. 72 , 21, (1995)

Synthesis , 181, (1995)


More Articles


Related Compounds

  • 2-(trimethylsilyl)thiazole-5-carbaldehyde
  • 4-(TRIBUTYLSTANNYL)-2-(TRIMETHYLSILYL)THIAZOLE
  • 5-(tributylstannyl)-2-(trimethylsilyl)thiazole
  • 2-trimethylsilyl-1,3-thiazole-4-carbaldehyde
  • 2-(((trimethylsilyl)oxy)methyl)benzo[d]thiazole
  • 2-(trimethylsilyl)benzothiazole